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Title
Japanese: 
English:Visible-light-induced Synthesis of a Variety of Trifluoromethylated Alkenes from Potassium Vinyltrifluoroborates by Photoredox Catalysis 
Author
Japanese: 安祐輔, 小池隆司, 穐田宗隆.  
English: Yusuke Yasu, Takashi Koike, MUNETAKA AKITA.  
Language English 
Journal/Book name
Japanese: 
English:Chemical Communications 
Volume, Number, Page Vol. 49        Page 2037–2039
Published date Jan. 22, 2013 
Publisher
Japanese: 
English: 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1039/c3cc39235j
Abstract A facile synthesis of trifluoromethylated alkenes by the radicalmediated trifluoromethylation of vinyltrifluoroborates has been developed. Togni’s reagent serves as a CF3 radical precursor in the presence of the photoredox catalyst [Ru(bpy)3](PF6)2 under visible light irradiation. This new photocatalytic protocol can be applicable to a wide variety of vinylborates containing electronically diverse substituents and hetero-aromatics.

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