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Title
Japanese:Cationic Rhodium(I)-dppf Complex-Catalyzed Olefin Isomerization/Propargyl Claisen Rearrangement/Carbonyl Migration Cascade. 
English:Cationic Rhodium(I)-dppf Complex-Catalyzed Olefin Isomerization/Propargyl Claisen Rearrangement/Carbonyl Migration Cascade. 
Author
Japanese: 田中健, Eri Okazaki, Yu. Shibata.  
English: Ken Tanaka, Eri Okazaki, Yu. Shibata.  
Language English 
Journal/Book name
Japanese:Journal of the American Chemical Society 
English:Journal of the American Chemical Society 
Volume, Number, Page Vol. 131    No. 31    pp. 10822-10823
Published date 2009 
Publisher
Japanese:American Chemical Society 
English:American Chemical Society 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1021/ja9038449
Abstract That a cationic rhodium(I)-dppf complex catalyzes isomerizations of allyl propargyl ethers to allenic aldehydes in good yields from room temp. to 40ﾂｰ was reported. On the other hand, carbonyl migration reactions from allenic aldehydes further proceed to give dienals in good yields at 80ﾂｰ. [on SciFinder(R)]

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