Home >

news Help

Publication Information


Title
Japanese:Rhodium-catalyzed [2+2+2] cycloaddition for the synthesis of substituted pyridines, pyridones, and thiopyranimines. 
English:Rhodium-catalyzed [2+2+2] cycloaddition for the synthesis of substituted pyridines, pyridones, and thiopyranimines. 
Author
Japanese: Ken. Tanaka.  
English: Ken. Tanaka.  
Language English 
Journal/Book name
Japanese:Heterocycles 
English:Heterocycles 
Volume, Number, Page Vol. 85    No. 5    pp. 1017-1043
Published date 2012 
Publisher
Japanese:Japan Institute of Heterocyclic Chemistry 
English:Japan Institute of Heterocyclic Chemistry 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.3987/REV-12-729
Abstract A review. The transition-metal-catalyzed [2+2+2] cycloaddn. of alkynes with nitriles is a useful and atom-economical method for the synthesis of substituted pyridines. The use of isocyanates and isothiocyanates in place of nitriles affords substituted pyridones and thiopyranimines, resp. This review comprehensively covered the [2+2+2] cycloaddn. reactions catalyzed by rhodium complexes for the synthesis of substituted pyridines, pyridones, and thiopyranimines. Asym. variants of these rhodium-catalyzed [2+2+2] cycloaddn. reactions are also described. [on SciFinder(R)]

©2007 Tokyo Institute of Technology All rights reserved.