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Title
Japanese:Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions. 
English:Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions. 
Author
Japanese: Yuji Takahama, 柴田祐, Ken Tanaka.  
English: Yuji Takahama, Yu Shibata, Ken Tanaka.  
Language English 
Journal/Book name
Japanese:Chemistry - A European Journal 
English:Chemistry - A European Journal 
Volume, Number, Page Vol. 21        pp. 9053-9056
Published date May 11, 2015 
Publisher
Japanese:Wiley-VCH Verlag GmbH & Co. KGaA 
English:Wiley-VCH Verlag GmbH & Co. KGaA 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1002/chem.201501232
Abstract The oxidative olefination of sp2 C[n.63743]H bonds of anilides with both activated and unactivated alkenes using an (electron-deficient η5-cyclopentadienyl)rhodium(III) complex is reported. In contrast to reactions using this electron-deficient rhodium(III) catalyst, [Cp*RhCl2]2 showed no activity against olefination with unactivated alkenes. In addn., the deuterium kinetic isotope effect (DKIE) study revealed that the C[n.63743]H bond cleavage step is thought to be the turnover-limiting step. [on SciFinder(R)]

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