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Title
Japanese:Rhodium-Catalyzed Three-Component Cross-Addition of Silylacetylenes, Alkynyl Esters, and Electron-Deficient Alkenes or Isocyanates. 
English:Rhodium-Catalyzed Three-Component Cross-Addition of Silylacetylenes, Alkynyl Esters, and Electron-Deficient Alkenes or Isocyanates. 
Author
Japanese: Yuki Hoshino, Yu Shibata, 田中健.  
English: Yuki Hoshino, Yu Shibata, Ken Tanaka.  
Language English 
Journal/Book name
Japanese:Angewandte Chemie, International Edition 
English:Angewandte Chemie, International Edition 
Volume, Number, Page Vol. 51    No. 37    pp. 9407-9411
Published date Aug. 2012 
Publisher
Japanese:Wiley-VCH Verlag GmbH & Co. KGaA 
English:Wiley-VCH Verlag GmbH & Co. KGaA 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1002/anie.201204646
Abstract Authors have developed an unprecedented rhodium-catalyzed chemo-, regio-, and stereoselective three-component cross-addn. of a silylacetylene, alkynyl ester, and electron-deficient alkene, thereby leading to substituted 1,3-dienes. In addn., the analogous and unprecedented three-component cross-addn. involving isocyanates in place of electron-deficient alkenes has also been developed. Future work will focus on further exploitation of the catalytic three-component cross-addn. reactions by using the cationic rhodium(I) complexes as catalysts. [on SciFinder(R)]

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