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Title
Japanese: 
English:Switching of the Conformational Flexibility of a Diazacyclooctane-Containing Ladder Polymer by Coordination and Elimination of a Lewis Acid 
Author
Japanese: 石割 文崇, 大淵 萌々子, 井上 恵希, Y. Sei, 福島 孝典.  
English: F. Ishiwari, M. Ofuchi, K. Inoue, Y. Sei, T. Fukushima.  
Language English 
Journal/Book name
Japanese: 
English:Polymer Chemistry 
Volume, Number, Page Vol. 11        Page 236–240
Published date Aug. 28, 2019 
Publisher
Japanese: 
English: 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
Official URL https://pubs.rsc.org/en/content/articlelanding/2020/PY/C9PY01104H#!divAbstract
 
DOI https://doi.org/10.1039/C9PY01104H
Abstract A recently developed diazacyclooctane-containing ladder polymer, which represents the first example of a ladder polymer with a large degree of conformational freedom, undergoes coordination and elimination of a Lewis acid (BPh2Cl), leading to reversible switching of the conformational flexibility of the polymer backbone. By taking advantage of this behaviour, it may be possible to control the bulk properties of the ladder polymer.

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