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Title
Japanese: 
English:Skeletal rearrangement of a boron-containing annulenic molecule into a macrocycle bridged by an electronically stabilized boron cation 
Author
Japanese: 村田 幸優, C. Özen, S. Maeda, 福島 孝典, 庄子 良晃.  
English: Y. Murata, C. Özen, S. Maeda, T. Fukushima, Y. Shoji.  
Language English 
Journal/Book name
Japanese: 
English:Chemical Communications 
Volume, Number, Page Vol. 59    Issue 91    Page 13635-13638
Published date Oct. 24, 2023 
Publisher
Japanese: 
English: 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
Official URL https://pubs.rsc.org/en/content/articlelanding/2023/cc/d3cc04830f#!divAbstract
 
DOI https://doi.org/10.1039/D3CC04830F
Abstract An annulenic molecule containing a three-coordinate chloroborane moiety, which exhibits a borane-olefin proximity effect, undergoes a skeletal rearrangement upon chloride abstraction, to generate a three-dimensional macrocyclic molecule featuring a borocenium (η5-cyclopentadienyl–B+–R) structure.

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