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Title
Japanese:One-pot gram-scale rapid synthesis of MN4 complexes with 14-membered ring macrocyclic ligand as a precursor for carbon-based ORR and CO2RR catalysts 
English:One-pot gram-scale rapid synthesis of MN4 complexes with 14-membered ring macrocyclic ligand as a precursor for carbon-based ORR and CO2RR catalysts 
Author
Japanese: Mana Ogawa, Sayaka Usami, Ryo Takahama, Kazuko Iwamoto, Tomomi Nabeta, Shin Kawashima, Ryoichi Kojima, Junya Ohyama, Teruaki Hayakawa, Yuta Nabae, Makoto Moriya.  
English: Mana Ogawa, Sayaka Usami, Ryo Takahama, Kazuko Iwamoto, Tomomi Nabeta, Shin Kawashima, Ryoichi Kojima, Junya Ohyama, Teruaki Hayakawa, Yuta Nabae, Makoto Moriya.  
Language English 
Journal/Book name
Japanese:Dalton Transactions 
English:Dalton Transactions 
Volume, Number, Page Vol. 53    No. 10    pp. 4426-4431
Published date Jan. 2024 
Publisher
Japanese:The Royal Society of Chemistry 
English:The Royal Society of Chemistry 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
Official URL http://dx.doi.org/10.1039/D3DT04129H
 
DOI https://doi.org/10.1039/D3DT04129H
Abstract Herein, CoN4, CuN4, and NiN4 complexes with a 14-membered ring hexaazamacrocycle ligand H2HAM were synthesised as precursors for ORR and CO2RR catalysts via a one-pot, gram-scale synthesis procedure, which involved microwave heating for only 10 min. Detailed structures of the obtained 14MR-MN4 complex were revealed by single-crystal X-ray diffraction measurements.

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