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Title
Japanese: 
English:Direct formation of single crystalline molecular clusters with disulfide bonding from thiol-containing triptycene derivatives 
Author
Japanese: 福井 智也, 斎藤 陸, 富 文聡, S. Kubo, A. Shishido, 福島 孝典.  
English: T. Fukui, R. Saitou, F. Tomi, S. Kubo, A. Shishido, T. Fukushima.  
Language English 
Journal/Book name
Japanese: 
English: 
Volume, Number, Page Volume 53    Issue 4    upae052
Published date Mar. 14, 2024 
Publisher
Japanese: 
English: 
Conference name
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Conference site
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English: 
Official URL https://academic.oup.com/chemlett/article/53/4/upae052/7628954?login=true
 
DOI https://doi.org/10.1093/chemle/upae052
Abstract When a DMF solution of 1,8,13-trimercaptotriptycene is allowed to stand under an inert atmosphere, a single crystalline molecular cluster with disulfide bonding results. Likewise, several thiol-containing triptycene derivatives yield single crystalline disulfide-containing clusters with different structural patterns. One of these clusters featuring a densely arranged tetrapod-like disulfide moiety exhibits a particularly high refractive index of 1.75, much higher than that of the others, although the sulfur contents of these clusters are comparable.

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