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タイトル
和文:Synthesis and structural characterization of BINOL-modified chiral polyoxometalates. 
英文:Synthesis and structural characterization of BINOL-modified chiral polyoxometalates. 
著者
和文: Ryo Ishimoto, Keigo Kamata, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka. Mizuno.  
英文: Ryo Ishimoto, Keigo Kamata, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka. Mizuno.  
言語 English 
掲載誌/書名
和文:Dalton Transactions 
英文:Dalton Transactions 
巻, 号, ページ Vol. 44    No. 24    pp. 10947-10951
出版年月 2015年 
出版者
和文:Royal Society of Chemistry 
英文:Royal Society of Chemistry 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1039/C5DT01338K
アブストラクト Chiral ligand-modified polyoxometalates (POMs), (Bu4N)4[ﾎｳ-SiTi2W10O36(ﾎｼ-OH)2(ﾎｼ-BINOLate)], were successfully synthesized by the introduction of (R)- or (S)-BINOL into the dititanium-substituted tungstosilicate POM in an org. medium and characterized by x-ray crystallog., spectroscopy, and elemental analyses. These BINOL-modified POMs were stable in the soln. state and showed catalytic activity for asym. oxidn. of thioanisole. [on SciFinder(R)]

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