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タイトル
和文:One-pot gram-scale rapid synthesis of MN4 complexes with 14-membered ring macrocyclic ligand as a precursor for carbon-based ORR and CO2RR catalysts 
英文:One-pot gram-scale rapid synthesis of MN4 complexes with 14-membered ring macrocyclic ligand as a precursor for carbon-based ORR and CO2RR catalysts 
著者
和文: Mana Ogawa, Sayaka Usami, Ryo Takahama, Kazuko Iwamoto, Tomomi Nabeta, Shin Kawashima, Ryoichi Kojima, Junya Ohyama, Teruaki Hayakawa, Yuta Nabae, Makoto Moriya.  
英文: Mana Ogawa, Sayaka Usami, Ryo Takahama, Kazuko Iwamoto, Tomomi Nabeta, Shin Kawashima, Ryoichi Kojima, Junya Ohyama, Teruaki Hayakawa, Yuta Nabae, Makoto Moriya.  
言語 English 
掲載誌/書名
和文:Dalton Transactions 
英文:Dalton Transactions 
巻, 号, ページ Vol. 53    No. 10    pp. 4426-4431
出版年月 2024年1月 
出版者
和文:The Royal Society of Chemistry 
英文:The Royal Society of Chemistry 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
公式リンク http://dx.doi.org/10.1039/D3DT04129H
 
DOI https://doi.org/10.1039/D3DT04129H
アブストラクト Herein, CoN4, CuN4, and NiN4 complexes with a 14-membered ring hexaazamacrocycle ligand H2HAM were synthesised as precursors for ORR and CO2RR catalysts via a one-pot, gram-scale synthesis procedure, which involved microwave heating for only 10 min. Detailed structures of the obtained 14MR-MN4 complex were revealed by single-crystal X-ray diffraction measurements.

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