論文

• M. Hatano, M. Terada, K. Mikami. Highly Enantioselective Palladium-Catalyzed Ene-type Cyclization of 1,6-Enyne, Angew. Chem. Int. Ed., Vol. 40, No. 1, pp. 249-253, 2001.
• K. Mikami, M. Terada, T. Korenaga, Y. Matsumoto, M. Ueki, R. Angelaud. Asymmetric Activation, Angew. Chem. Int. Ed., Vol. 39, No. 20, pp. 3532-3556, 2000.
• K. Mikami, T. Korenaga, M. Terada, T. Ohkuma, T. Pham, R. Noyori. Conformationally Flexible Biphenylphosphine Ligands for Ru-Catalyzed Enantioselective Hydrogenation, Angew. Chem. Int. Ed., Vol. 38, No. 4, pp. 495-497, 1999.
• T. Okano, K. Nakagawa, N. Kubodera, A. Isaka, A. Osawa, M. Terada, K. Mikami. Catalytic Asymmetric Syntheses and Biological Activities of a Series of Singly Dehydroxylated 19-Nor-1alfa,25-dihydroxyvitamin D3 A-ring Analogs in Cancer Cell Differentiation and Apoptosis, Chem. Biol., Vol. 7, No. 3, pp. 173-184, 2000.
• K. Mikami, Y. Koizumi, A. Osawa, M. Terada, H. Takayama, K. Nakagawa, T. Okano. BINOL-Ti-Catalyzed Carbonyl-Ene Cyclization by Tuning the 6-Br-Ligand for the Synthesis of 2-Methyl-19-nor-22-oxa Vitamin D Analogue with Significant Differentiation Activity, Synlett, No. 12, pp. 1899-1902, 2000.
• K. Mikami, T. Yajima, J. Kojima, M. Terada, S. Kawauchi, H. Shirasaki, K. Okuyama, Y. Suzuki, I. Kobayashi, Y. Takanishi, H. Takezoe. Diastereomer Liquid Crystalline CF3 Molecules: Conformational Probe for (Anti)ferroelectricity and Spontaneous Resolution of the Racemates, , , Mol. Cryst. Liq. Cryst., Vol. 346, pp. 41-49, 2000.
• M. Terada, Y. Matsumoto, Y. Nakamura, K. Mikami. Molecular Assembly of BINOL-Ti Complexes into Active mu3-Oxo Titanium Complex as the Efficient Chiral Lewis Acid Catalyst, Inorg. Chim. Acta, Vol. 296, pp. 267-272, 1999.
• I. Kobayashi, Y. Suzuki, T. Yajima, S. Kawauchi, T. Imase, M. Terada, K. Mikami. Effects of Conformation of Diastereomer Liquid Crystals on The Preference of Antiferroelectricty , Mol. Cryst. Liq. Cryst. Sci. Technol. Sect. A, Vol. 328, pp. 131-137, 1999.
• K. Ding, Y. Wang, H. Yun, J. Liu, Y. Wu, M. Terada, Y. Okubo, K. Mikami. Highly Efficient and Practical Optical Resolution of 2-Amino-2'-hydroxy-1,1'-binaphthyl by Molecular Complexation with N-Benzylcinchonidium Chloride: A Direct Transformation to Binaphthyl Amino Phosphine, Chem. Eur. J., Vol. 5, No. 6, pp. 1734-1737, 1999.
• Y. Takanishi, H. Takezoe, I. Kobayashi, Y. Suzuki, T. Yajima, M. Terada, K. Mikami. Spontaneous Chiral Resolution in a Fluid Smectic Phase of a Racemic Diastereomer , Angew. Chem. Int. Ed., Vol. 38, pp. 2354-2357, 1999.
• K. Mikami, T. Yajima, N. Siree, M. Terada, Y. Suzuki, I. Kobayashi, Y. Takanishi, H. Takezoe. Tandem (Domino) and Two-Directional Asymmetric Catalysis of Carbonyl-Ene Reaction with Fluoral: Fluoral-Ene Approach to Modeling of Inter-Smectic Layer Interaction of Antiferroelectric Liquid Crystals, Synlett, No. 12, pp. 1895-1898, 1999.
• T. Volk, T. Korenaga, S. Matsukawa, M. Terada, K. Mikami. Asymmetric Activation of Chiral BINOL-Zirconium Catalysts: Effect of a Product-Like Activator, Chirality, Vol. 10, pp. 717-721, 1998.
• K. Mikami, M. Terada, Y. Matsumoto, M. Tanaka, Y. Nakamura. Efficient Preparation of Binaphthol-Derived Active mu3-Oxo Titanium Catalyst by Using Hydrated Na-Zeolites (Molecular Sieves), Microporous Mesoporous Mater., Vol. 21, pp. 461-466, 1998.
• K. Nakagawa, N. Tsugawa, K. Mikami, M. Terada, A. Osawa, K. Ozono, N. Kubodera, T. Okano. Singly Dehydroxylated A-Ring Analogues of 19-Nor-1alfa,25-dihydroxyvitamin D3 and 19-Nor-22-oxa-1alfa,25-dihydroxyvitamin D3: Novel Vitamin D3 Analogues with Potent Transcriptional Activity but Extremely Low Affinity for Vitamin D Receptor, Biol. Pharm. Bull., Vol. 21, No. 12, pp. 1300-1305, 1998.
• MASAHIRO TERADA. The effect of Counter Cations in Zeolites on the Efficient Preparation of the Binaphthol-Titanium Complex., J. Mol. Catal. A, Vol. 132, pp. 165-169, 1998.
• MASAHIRO TERADA. Asymmetric Activation of Racemic Catalysts, J. Synth. Org. Chem., Jpn, Vol. 56, No. 11, pp. 975-986, 1998.
• MASAHIRO TERADA. Asymmetric Activation of Racemic Ruthenium(II) complexcs for Enantioselectire Hyolrogenation, J. Am. Chem. Soc., Vol. 120, No. 5, pp. 1086-1087, 1998.
• I. Kobayashi, Y. Suzuki, T. Yajima, S. Kawauchi, M. Terada, K. Mikami. Diastereomer Effects on Antiferroelectricity and Ferroelectricity of the Newly Synthesized Liquid Crystals, Molecular Crystals and Liquid Crystals, Vol. 303, pp. 165-170, 1997.
• Terada, Y. Matsumoto, M. Tanaka, Y. Nakamura, K. Mikami. Anomalous Role of Molecular Sieves 4A in the Preparation of a Binaphthol-derived Active mu3-oxo Titanium Catalyst., Chem. Commun, No. 3, pp. 281-282, 1997.
• MASAHIRO TERADA. Direct Transition from SmA to antiferroelectric, erroelectric or Unknown Phases of Diastereomeric Liquid-crystalline Molecules With Varirg Enantiomeric Purities, Chem. Commun, No. 1, pp. 57-58, 1997.
• K. Mikami, S. Matsukawa, T. Volk, M. Terada. Self-Assembly of Several Components into a Highly Enantioselective Ti Catalyst for Carbonyl-Ene Reaction, Angew. Chem., Int. Ed. Engl., Vol. 36, pp. 2768-2771, 1997.
• MASAHIRO TERADA. Asymmetric Catalysis of Carbonyl-Ene and Aldol Reactions with Fluoral by Chiral Binaphthol-Derived Titanium Complex, Tetrahedron, Vol. 52, No. 1, pp. 85-98, 1996.
• MASAHIRO TERADA. Diaster eotopic Phenomena for the Appearance of SmCA Phase in α-Trifluoromethyl-β-methyl Substituted Liguid-Crystalline Molecules., Chem. Lett., pp. 861-862, 1996.
• MASAHIRO TERADA. Periselective and Erantioselective Carbonyl-Ene Reaction of Isoprene with Fluoroalkyl Glyoxylate Catalyzed by Modified Binaphthol-Titanium Complex:Asymmetric Catalytic Synthesis of Enantiomerically Pure Ipsdienol, J.Chem.Soc.Chem.Commun, No. 23, pp. 2391-2392, 1995.
• MASAHIRO TERADA. Asymmetric Catalysis of (Hetero) Diels-Alder Cycloadditions by a Modified Binaphthol-Derived Titanium Comliex, SynLett, No. 9, pp. 967-968, 1995.
• MASAHIRO TERADA. Double Asymmetric Synthesis by Asymmetric Catalytic Carbonyl-Ene Type Reaction with Chiral Ene Components:Asymmetric Catalytic Synthesis of Aspartyl Dipeptids Sweetener, Synlett, No. 5, pp. 411-415, 1995.
• MASAHIRO TERADA. Binaphthol-derived Titanium μ-Oxo Complex : A New Type of Asymmetric Catalysts for Carbonyl-Ene Reaction., J. Chem. Soc. , Chem. Commun., No. 10, pp. 833-834, 1994.
• MASAHIRO TERADA. Diastereoselective and Enantioselective Glyoxylate-Ene Reaction Catalyzed by A New Class of Binaphthol-derived Titanium Complex., Tetrahedron Lett., Vol. 35, No. 36, pp. 6693-6696, 1994.
• MASAHIRO TERADA. An Europium (III) Complex As an Efficient Catalyst for the Michael Reaction of α, β-Enones with Ketene Silyl Acetals : LIS-NMR Analysis for the Transition State Through Complexation between Europium (III) Catalyst and Enones., Inorg. Chim. Acta., Vol. 222, No. 1-2, pp. 377-380, 1994.
• MASAHIRO TERADA. Asymmetric Catalysis of Diels-Alder Cycloadditions by an MS-free Binaphthol-titanium Complex : Dramatic Effect of MS, Linear vs Positive Nonlinear Relationship, and Synthetic Applications., J. Am Chem. Soc., Vol. 116, No. 7, pp. 2812-2820, 1994.
• MASAHIRO TERADA. Asymmetric Catalysis of Ene-Type Reaction with Fluoral by Chiral Titanium Complex : A semi-empilical and Ab-Initio Analysis of Ene Reactivity, Tetrahedron Lett., Vol. 34, No. 47, pp. 7591-7594, 1993.
• MASAHIRO TERADA. Enantio-and Disatereoselective Catalysis of Addition reaction of Allylic Silanes and stannanes to Glyoxylates by Binaphthol-Derived Titanium Complex, Tetrahedron, Vol. 49, No. 9, pp. 1783-1792, 1993.
• MASAHIRO TERADA. Control of Chelation/ Nonchelation Stereoselections in Lanthanide-Catalysed Aldol Reactions, J. Chem Soc. , Chem. commun., No. 4, pp. 343-345, 1993.
• MASAHIRO TERADA. Enantiomerically Pure Compound Synthesis by Asymmetric Glyoxylate-Ene Reaction with Uniylic Sulfides and Silenides Catalyzed by a Chirol Titanium Complex, J. Chim Soc. , chem commun, No. 3, pp. 327-328, 1993.
• MASAHIRO TERADA. Chiral Titanium Complex-Catalyzed Carbonyl-Ene Reaction with Glyoxylate : Remarkable Positive Nonlinear Effect, Tetrahedron, Vol. 48, pp. 27, 1992.
• MASAHIRO TERADA. Stereo-Modulating Catalysis by Europium(III) Complexes in Aldol Reactions of Chiral α-Alkoxy Aldehydes with Ketene Silyl Acetals, Chemistry Letters, pp. 1, 1992.
• MASAHIRO TERADA. Unique Stereocontrol in Europium(III)-Catalyzed Cyanosilylation of Chiral α-Alkoxy and α-Amino Aldehyde, Chemistry Letters, pp. 7, 1992.
• MASAHIRO TERADA. Asymmetric Catalysis for Carbonyl-Ene Reaction, Synlett, pp. 4, 1992.
• MASAHIRO TERADA. Asymmetric Desymmetrization by Erantioselective Catalysis of Carbonyl-Ene Reaction : Remote Internal Asymmetric Induction, Journal of American Chemical Society, Vol. 114, pp. 16, 1992.
• MASAHIRO TERADA. Unique Stereocontrol in Lanthanide(III)-Catalyzed Aldol Reactions with the Ketene Silyl Acetal of Methyl (R)-3-Hydroxybutanoate, Tetrahedron Letter, Vol. 33, pp. 11, 1992.
• MASAHIRO TERADA. Unique Catalysis by Eu(dppm)┣D23┫D2 : Catalytic Molecular Recognition in Aldol and Michael Reactions., Journal of Organic Chemistry., Vol. 56, pp. 18, 1991.
• MASAHIRO TERADA. Chiral Titanium Complex-Catalyzed Diels-Alder Reaction : A Practcal Route to Anthracycline Intermediates, Tetrahedron Asymmetry, Vol. 2, pp. 7, 1991.
• MASAHIRO TERADA. Asymmetric Catalysis by Chiral Titanium Perchlorate for Carbonyl-Ene Cyclization, Tetrahedron Asymmetry, Vol. 2, pp. 12, 1991.
• MASAHIRO TERADA. Remarkable Positive Nonlinear Effect in the Enantio Selective Glyoxylate-Ene Reaction Catalyzed by a Chiral Titarium Complex, J. Chem. , Chem. Commun., No. 22, pp. 1623-1624, 1990.
• MASAHIRO TERADA. Catalytic Asymmetric Glyoxylate-Ene Reaction : A Practical Access to α-Hydroxy Esters in High Enantiomeric Purities., Journal of American Chemical Society, Vol. 112, pp. 10, 1990.
• MASAHIRO TERADA. Asymmetric Glyoxylate-Ene Reaction Catalyzed by Chiral Titanium Complexes : Apractical Access to α-Hydroxy Esters in High Enantiomeric Purities, J. Am. Chem. Soc., Vol. 111, No. 5, pp. 1940-1941, 1989.

著書

• 寺田眞浩. 触媒の事典（分担）, 2000 , 小野嘉夫、御園生誠、諸岡良彦　編；朝倉書店, 小野嘉夫、御園生誠、諸岡良彦　編；朝倉書店, 2000.
• K. Mikami, M. Terada. Chiral Ti(IV) Lewis Acids, Handbook on Lewis Acids-Application in Organic Synthesis, (Ed. H. Yamamoto), Wiley-VCH, Handbook on Lewis Acids-Application in Organic Synthesis, (Ed. H. Yamamoto), Wiley-VCH, Vol. 2, pp. 799-847, 2000.
• K. Mikami, M. Terada, T. Korenaga, Y. Matsumoto, S. Matsukawa. Enantiomer-Selective Activation of Racemic Catalysts, Acc. Chem. Res., Acc. Chem. Res., Vol. 33, No. 6, pp. 391-401, 2000.
• K. Mikami, M. Terada. Ene-Type Reactions, Comprehensive Asymmetric Catalysis, (Eds. E. N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, Comprehensive Asymmetric Catalysis, (Eds. E. N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, Vol. 3, pp. 1143-1174, 1999.
• 寺田眞浩. 不斉配位子を用いない不斉触媒-その設計法-, 触媒, 触媒, Vol. 41, No. 5, pp. 334-335, 1999.
• K. Mikami, M. Terada. Chiral Titanium Reagents for Asymmetric Organic Synthesis, Lewis Acid Reagents: A Practical Approach, (Ed. H. Yamamoto), Oxford University Press, Lewis Acid Reagents: A Practical Approach, (Ed. H. Yamamoto), Oxford University Press, pp. 93-136, 1998.
• K. Mikami, T. Korenaga, M. Terada. 不斉活性化による触媒的不斉合成 , 現代化学, 現代化学, Vol. 329, pp. 14-21, 1998.
• K. Mikami, M. Terada, A. Osawa. 不斉重合触媒, 高分子学会協会誌, 高分子学会協会誌, Vol. 46, pp. 72-76, 1997.
• K. Mikami, M. Terada. キラルチタン錯体を触媒とする不斉合成, 科学と工業, 科学と工業, Vol. 71, pp. 249-258, 1997.
• MASAHIRO TERADA. Asymmetric Catalysis of Glyoxylate-Ene Reaction and Related Reactions, Advance in Catalytic Processes, Advance in Catalytic Processes, Vol. 1, pp. 123-149, 1995.

国内会議発表 (査読なし・不明)

• K. Mikami, M. Hatano, M. Terada. Catalytic C-H Bond Activation-Asymmetric Olefin Coupling Reaction : The First Example of Asymmetric Fujiwara-Moritani Reaction Catalyzed by Chiral Palladium(II) Complexes, Chem. Lett., No. 1, pp. 55-56, 1999.

学位論文

• ランタニドおよびチタン錯体を用いる炭素―炭素結合生成反応の不斉触媒化に関する研究,  本文,  Doctor of Engineering,  東京工業大学,  1993/--/--, 

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