@article{CTT100418211, author = {Shiro Hikichi and Hidehito Komatsuzaki and Munetaka Akita and Yoshihiko Moro-oka}, title = {Aliphatic C-H Bond Oxygenation by the CoIIOOX Species with the Hindered Hydrotris(pyrazolyl)borate Ligand(X=Co(II), Alkyl, H)}, journal = {Journal of the American Chemical Society}, year = 1998, } @article{CTT100438106, author = {Shiro Hikichi and Munetaka Akita and Yoshihiko Moro-oka}, title = {New aspects of the cobalt-dioxygen complex chemistry opened by hydrotris(pyrazoly)borate ligands (= TpR): Unique properties of TpRCo-dioxygen complexes}, journal = {Coord. Chem. Rev.}, year = 2000, } @article{CTT100833746, author = {Shin-ichiro Agake and 小松崎 秀人 and minoru Sato and tomohiro agou and Yuya Tanaka and MUNETAKA AKITA and jun nakazawa and SHIRO HIKICHI}, title = {A monomeric manganese(II) catecholato complex: Synthesis, crystal structure, and reactivity toward molecular oxygen}, journal = {Inorganica Chimica Acta}, year = 2019, } @article{CTT100450787, author = {SHIRO HIKICHI}, title = {Synthesis and Dehydrative Condensation of Monomeric Hydroxoruthenium Complexes with Hydrotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPr2Ru(L2)-OH (L2 = dppe, bipy)}, journal = {Inorg. Chem.}, year = 2001, } @article{CTT100450789, author = {SHIRO HIKICHI}, title = {N/O- and C-Bound (Enolato)palladium Complexes with Hydrotris(pyrazolyl)borato Ligands (TpR: R = iPr2, Me2) Obtained via Dehydrative Condensation between the Hydroxo Complexes TpRPd(Py)OH and Active Methylene Compounds: Factors Determining the Isomer Distribution and Dimerization of Cyano Compounds}, journal = {Organometallics}, year = 2001, } @article{CTT100450788, author = {SHIRO HIKICHI}, title = {Tetrahedral, Highly Coordinatively Unsaturated 14e (Fe) and 15e (Co) Hydrocarbyl Complexes Bearing Hydrotris(pyrazolyl)borato Ligands (TpR'), TpR'M-R (M = Fe, Co, Ni)}, journal = {Organometallics}, year = 2001, } @article{CTT100438110, author = {De-qiang Ma and Shiro Hikichi and Munetaka Akita and Yoshihiko Moro-oka}, title = {An entry to half-sandwich complexes of first row transition metals (Ni, Co, Mn) containing the Klaui tripodal ligand, LOMe: synthesis and crystal structures of oligomeric, [LOMeM(μ-X)(L)]n (n = 2, 4), and monomeric complexes, LOMeM(L2)(X)}, journal = {J. Chem. Soc., Dalton Trans.}, year = 2000, } @article{CTT100438109, author = {Koyu Fujita and Shiro Hikichi and Munetaka Akita and Yoshihiko Moro-oka}, title = {Synthesis and structural characterization of a new-class of organoborato ligands containing imidazolyl functional groups [MeB(ImN-Me)2(X)]-}, journal = {J. Chem. Soc., Dalton Trans.}, year = 2000, } @article{CTT100438108, author = {Koyu Fujita and Shiro Hikichi and Munetaka Akita and Yoshihiko Moro-oka}, title = {Novel monoanionic tripodal ligands: methylbis(1-methylimidazol-2-yl)(pyrazol-1-yl)borate (= MeB(ImN-Me)2(PzR)]-). Synthesis and structural characterization of their nickel complexes and carboxylate shift from nickel to boron}, journal = {J. Chem. Soc., Dalton Trans.}, year = 2000, } @article{CTT100438107, author = {Tamako Ogihara and Shiro Hikichi and Munetaka Akita and Yoshihiko Moro-oka}, title = {An approach to the O2 activating mononuclear non-heme Fe enzymes: structural characterization of Fe(II)-acetato complex and formation of alkylperoxoiron(III) species with the highly hindered hydrotris(3-tert-butyl-5-isopropyl-1-pyrazolyl)borate}, journal = {Inorg. Chim. Acta}, year = 2000, } @article{CTT100446068, author = {Udai P. SINGH and Rajender SINGH and Shiro HIKICHI and munetaka AKITA and Yoshihiko MORO-OKA}, title = {Characterization of a dinuclear Mn(II) tri(μ-carboxylato) complex with the hindered hydrotris(3,5-diisopropyl-1-pyrazolyl)borate (= TpiPr2) ligand: intramolecular hydrogen bonding interaction between the protonated TpiPr2 and Mn-coordinating carboxylate ligands}, journal = {Inorg. Chim. Acta}, year = 2000, } @article{CTT100438112, author = {Munetaka Akita and Mariko Hashimoto and Shiro Hikichi and Yoshihiko Moro-oka}, title = {Synthesis and Structural Comparison of TpiPr2Rh[cis-1,2-bis(diphenylphosphino)ethene]: Factors Determining Hapticity (χ2 vs. χ3) of the TpiPr2 ligand in TpiPr2Rh(diphosphine) Complexes}, journal = {Organometallics}, year = 2000, } @article{CTT100438111, author = {SHIRO HIKICHI}, title = {Synthesis and Dehydrative Condensation of Square-Planar Mono- and Dinuclear Hydroxopalladium Complexes with the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (TpiPr2), TpiPr2(Py)Pd-OH, and (μ-OH)2{PdTpiPr2(H2O)}2}, journal = {Inorg. Chem.}, year = 2000, } @article{CTT100426316, author = {穐田宗隆 and 引地史郎 and 諸岡良彦}, title = {ヒドロトリス(ピラゾリル)ボレートを配位子とする金属錯体の化学 -酸素錯体を中心に- (共著)}, journal = {有機合成化学協会誌}, year = 1999, } @article{CTT100425681, author = {Nobuhiko SHIRASAWA and Munetaka AKITA and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Thermally stable coordinatively unsaturated alkyl complexes resistant to β-hydride elimination: TpiPrM-CH2CH3 (M = Co, Fe) (共著)}, journal = {Chemical Communications}, year = 1999, } @article{CTT100426278, author = {Masahiro KOSUGI and Shiro HIKICHI and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {The first evidence for activation of exogenous O2 on a vanadium(IV) center: Synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropyl-1-pyrazolyl)borate (共著)}, journal = {Journal of the Chemical Society, Dalton Transaction}, year = 1999, } @article{CTT100426279, author = {Masahiro KOSUGI and Shiro HIKICHI and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {Inter- and Intramolecular Hydrogen-bonding Interaction of Hydroxo Groups and Steric Effect of Alkyl Substituents on Pyrazolyl Rings in TpR Ligands: Synthesis and Structural Characterization of Chloro- and Hydroxo Complexes of VO2+ with TpPri2 and TpMe2 Ligands (共著)}, journal = {Inorganic Chemistry}, year = 1999, } @article{CTT100426309, author = {Yoshiaki TAKAHASHI and Shiro HIKICHI and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {Oxidative C(sp3)-C(sp3) bond cleavage reaction of an isopropyl group to give an acetyl group via O2-treatment of a labile cationic ruthenium species, [TpiPrRu(dppene)(OH2)]+ (共著)}, journal = {Chemical Communications}, year = 1999, } @article{CTT100426310, author = {Munetaka AKITA and De-qiang MA and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Synthesis and crystal structures of mononuclear half-sandwich Ni and Co complexes containing the Klaui's tripodal ligand, [κ3-(η5-C5H5)Co{P(=O)(OCH3)2}3]M(κ2-NO3)(L) (M= Ni, Co) (共著)}, journal = {Journal of the Chemical Society, Dalton Transaction}, year = 1999, } @article{CTT100426311, author = {Yoshiaki TAKAHASHI and Shiro HIKICHI and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {A Coordinatively Unsaturated Species with Agostic C-H Interaction, [κ4-TpiPrRu(dppe)]OSO2CF3, and its Addition Reaction (共著)}, journal = {Organometallics}, year = 1999, } @article{CTT100426312, author = {Keisuke OHTA and Mariko HASHIMOTO and Yoshiaki TAKAHASHI and Shiro HIKICHI and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {Synthesis of a Series of Rhodium Complexes, TpiPrRhIL2 and TpiPrRhIII(X)(Y)(MeCN), with Hydrotris(3,5-diisopropyl-pyrazolyl)borato Ligand (TpiPr) from the Versatile Precursor, (κ3-TpiPr)Rh(coe)(MeCN), and Dependence of the κ23 Interconversion Rate of the TpiPr Ligand on th}, journal = {Organometallics}, year = 1999, } @article{CTT100426313, author = {Munetaka AKITA and Taichi MIYAJI and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {A Transition Metal-Hydroperoxo Complex Stabilized by Hydrogen-Bonding Interaction: The First Example of a Hydroperoxopalladium Species Characterized by X-Ray Crystallography, (κ2-TpiPr)Pd(PPh3)(OOH) [TpiPr = hydrotris(3,5-diisopropylpyrazolyl)borato] (共著)}, journal = {Chemistry Letters}, year = 1999, } @article{CTT100426314, author = {Yoshiaki and TAKAHASHI and Mariko HASHIMOTO and Shiro HIKICHI and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {Conversion of Molecular Oxygen into a Hydroperoxo Species via Ring Opening Protonation of a Cyclic η2-Peroxide Intermediate: Characterization of the η2-Peroxide and Hydroperoxo Complexes Obtained by Oxygenation of a Rhodium(I) Complex, TpiPrRh(dppe) [TpiPr = hydrotris(3,5-di-iso-propy}, journal = {Angewandte Chemie International Edition}, year = 1999, } @article{CTT100426325, author = {Shiro HIKICHI and Michito YOSHIZAWA and Yasuyuki SASAKURA and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {Characterization of reactive bis(μ-oxo) dimetal(III) complexes with tris(pyrazolyl)borate ligands}, journal = {J. Inorg. Biochem}, year = 1999, } @article{CTT100426326, author = {引地史郎}, title = {複核遷移金属中心上での酸素活性化 -高原子価オキソ種の生成-}, journal = {触媒}, year = 1999, } @article{CTT100426281, author = {Yoshiaki TAKAHASHI and Munetaka AKITA and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Synthesis of Various Cationic Ruthenium-Aqua Complexes with the Hydrotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPrRu(OH2)n(L)3-n(CF3SO3)(THF)x, and Their Structures Supported by Hydrogen-Bonding Networks (共著)}, journal = {Inorganic Chemistry}, year = 1998, } @article{CTT100426282, author = {Yoshiaki TAKAHASHI and Munetaka AKITA and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Two Isomeric Structures of Hydridoruthenium Complexes Supported by Hydrotrispyrazolylborates, TpRRu(H)(1,5-cyclooctadiene): An Octahedral Structure with Additional 3-Center-2-Electron Ru-H-B Interaction Is More Stable than a Square-Pyramidal Structure with a κ2-TpR Ligand (共著)}, journal = {Organometallics}, year = 1998, } @article{CTT100418214, author = {Munetaka AKITA and Taichi MIYAJI and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Systematic synthesis of a series of hydroperoxo-alkylperoxo-and μ-peroxo-palladium complexes supported by the hydrotris(3,5-diis opropylpyrazolyl)borate ligand(TpiPr), TpiPrPd(py)-OOX[X=PdTpiPr(py), H, But], via dehydrative condensation of a hydroxo complex, TpiPrPd-OH(共著)}, journal = {Chemical Communications}, year = 1998, } @article{CTT100418213, author = {Munetaka AKITA and Nobuhiko SHIRASAWA and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {14e η1-Hydrocarbyliron complexes supported by hydrotris(3,5-diis opropylpyrazolyl)borate : the allyl complex prefers a highly coordinatively unsaturated 14e η1-structure to a 16e η3-structure(共著)}, journal = {Chemical Communications}, year = 1998, } @article{CTT100426274, author = {Tamako Ogihara and Shiro Hikichi and Munetaka Akita and Yoshihiko Moro-oka}, title = {Synthesis, Structural Characterization, and Extradiol Oxygenation of Iron-Catecholato Complexes with Hydrotris(pyrazolyl)borate Ligands}, journal = {Inorganic Chemistry}, year = 1998, } @article{CTT100426275, author = {Hidehito KOMATSUZAKI and Shinobu ICHIKAWA and Shiro HIKICHI and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {Characterization of a Dinuclear Mn(II) (μ-Hydroxo)(μ-Pyrazolato) Complex and Hydrolytic Equilibrium of the Bridging Pyrazolate Ligand (共著)}, journal = {Inorganic Chemistry}, year = 1998, } @article{CTT100426277, author = {Hidehito KOMATSUZAKI and Minoru SATOH and Naoko SAKAMOTO and Shiro HIKICHI and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {The First Synthesis and Structural Characterization of Alkylperoxo Complex of Mn(II) (共著)}, journal = {Inorganic Chemistry}, year = 1998, } @article{CTT100418210, author = {Hidehito KOMATSUZAKI and Yuichi NAGASU and Kantaro SUZUKI and Takao SHIBASAKI and Minoru SATOH and Fujjio EBINA and Shiro HIKICHI and Munetak}, title = {Dioxygen activation by a novel manganese(II) thiolate complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate ligand(共著)}, journal = {Journal of the Chemical Society, Dalton Transactions}, year = 1998, } @article{CTT100426315, author = {Munetaka AKITA and Kiyoshi FUJISAWA and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Chemistry of μ-η22-Peroxo Dimetal Complexes: A Bioinorganic Model Triggers a New Trend of Transition Metal Peroxo Species (共著)}, journal = {Res. Chem. Intermed}, year = 1998, } @article{CTT100418209, author = {Shiro HIKICHI and Tamako OGIHARA and Kiyoshi FUJISAWA and Nobumasa KITAJIMA and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {Synthesis and Characterization of the Benzoylformato Ferrous Complexes with the Hindered Tris(pyrazolyl)borate Ligand as a Structural Model for Mononuclear Non-Heme Iron Enzymes(共著)}, journal = {Inorganic Chemistry}, year = 1997, } @article{CTT100418212, author = {Munetaka AKITA and Keisuke OHTA and Yoshiaki TAKAHASHI and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Synthesis and Structure Determination of Rh-diene Complexes with the Hydridotris(3,5-diis opropylpyrazolyl)borate Ligand, TpiPrRh(diene)(diene=cod, nbd) : Dependence of the ν(B-H)Values on the Hapticity of the TpiPr Ligand(κ2 vs κ3)(共著)}, journal = {Organometallics}, year = 1997, } @article{CTT100418202, author = {Shiro Hikichi and Hidehito KOMATSUZAKI and Nobumasa KITAJIMA and Munetaka AKITA and Masahiro MUKAI and Teizo KITAGAWA and Yoshihiko MO}, title = {Characterization of a μ-η22-Peroxo Dinuclear Cobalt(II) Complex}, journal = {Inorganic Chemistry}, year = 1997, } @article{CTT100426324, author = {Shiro HIKICHI and Hidehito KOMATSUZAKI and Munetaka AKITA and Yoshihiko MORO-OKA}, title = {Aliphatic C-H Bond Functionalization by Reaction of Hydroxo Complexes of Cobalt(II) and Nickel(II) with ROOH (R = H, alkyl) (共著)}, journal = {Journal of Inorganic Biochemistry}, year = 1997, } @article{CTT100418203, author = {Nobumasa KITAJIMA and Hidehito KOMATSUZAKI and Shiro HIKICHI and Masahisa OSAWA and Yoshihiko MORO-OKA}, title = {A Monomeric Side-On Peroxo Manganese(III)Complex : Mn(O2)(3,5-iPr2PzH)(HB(3,5-iPr2pz)3)(共著)}, journal = {Journal of the American Chemical Society}, year = 1994, } @article{CTT100418204, author = {Shiro HIKICHI and Masako Tanaka and Yoshihiko MORO-OKA and Nobumasa KITAJIMA}, title = {Reaction of Hydroxo Complexes of Divalent Metal Ions with Amide(共著)}, journal = {Journal of the Chemical Society, Chemical Communications}, year = 1994, } @article{CTT100418206, author = {Nobumasa KITAJIMA and Shiro HIKICHI and Masako TANAKA and Yoshihiko MORO-OKA}, title = {Fixation of Atmospheric CO2 by a Series of Hydroxo Complexes of Divalent Metal Ions and the Implication for the Catalytic Role of Metal Ion in Carbonic Anhydrase. (共著)}, journal = {Journal of the American Chemical Society}, year = 1993, } @article{CTT100418205, author = {Nobumasa KITAJIMA and Kiyoshi FUJISAWA and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Formation of(μ-Hydroxo)(μ-azido)Dinuclear Copper Complex from μ-η22-Peroxo Complex(共著)}, journal = {Journal of the American Chemical Society}, year = 1993, } @article{CTT100418207, author = {Shiro HIKICHI and Masako TANAKA and Yoshihiko MORO-OKA and Nobumasa KITAJIMA}, title = {Phosphate Ester Cleavage with a Zinc Hydroxide Complex. Formation and Crystal Structure of a Dinuclear Zinc Complex Bridged with a Phosphate Monoester(共著)}, journal = {Journal of the Chemical Society, Chemical Communications}, year = 1992, } @article{CTT100426323, author = {Nobumasa KITAJIMA and Kiyoshi FUJISAWA and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Copper Complexes with a Hindered Tris(pyrazolyl)borate Ligand as Synthetic Models for the Active Sites of Copper Proteins (共著)}, journal = {Journal of Inorganic Biochemistry}, year = 1991, } @article{CTT100418208, author = {Nobumasa KITAJIMA and Kiyoshi FUJISAWA and Takayuki KODA and Shiro HIKICHI and Yoshihiko MORO-OKA}, title = {Fixation of Atmospheric CO2 by a Copper(II) Complex(共著)}, journal = {Journal of the Chemical Society, Chemical Communications}, year = 1990, } @misc{CTT100595958, author = {SHIRO HIKICHI}, title = {トリスピラゾリルボレートを配位子とする第一周期遷移金属二価イオンヒドロキソ錯体の反応性}, year = 1995, } @phdthesis{CTT100595958, author = {SHIRO HIKICHI}, title = {トリスピラゾリルボレートを配位子とする第一周期遷移金属二価イオンヒドロキソ錯体の反応性}, school = {東京工業大学}, year = 1995, }