@book{CTT100869099, author = {TOSHIRO TAKAO and Akiko Takao(Inagaki)}, title = {Mono- and Bis-cyclopentadienyl Complexes of Ruthenium and Osmium}, publisher = {Elsevier}, year = 2022, } @book{CTT100833271, author = {TOSHIRO TAKAO}, title = {多核錯体中の遷移金属原子間の相互作用}, publisher = {日本化学会}, year = 2020, } @book{CTT100627565, author = {Hiroyuki Kawaguchi and Hiroharu Suzuki and Toshiro Takao}, title = {11.遷移金属クラスターの化学}, publisher = {東京化学同人}, year = 2011, } @book{CTT100522954, author = {Hiroharu Suzuki and Toshiro Takao}, title = {Comprehensive Organometallic Chemistry III; Trinuclear Ru/Os Clusters: Compounds with Hydrocarbon Ligands (Cyclopentadienyls)}, publisher = {Elsevier}, year = 2006, } @book{CTT100499639, author = {Hiroharu Suzuki and Toshiro Takao}, title = {Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes}, publisher = {Wiley-VCH; Ruthenium in Organic Synthesis, Chapter 12}, year = 2004, } @book{CTT100499599, author = {鈴木寛治 and 高尾俊郎}, title = {有機金属クラスター錯体の合成(三および四核錯体)}, publisher = {丸善;第5版 実験化学講座21巻 有機遷移金属化合物・超分子錯体}, year = 2004, } @article{CTT100898177, author = {Toshiro Takao and Taichi Monoe and Ryuichi Shimogawa and Keigo Nakamura}, title = {Heterobimetallic Trihydrido Complex of Ruthenium and Rhodium Supported by Cyclopentadienyl Groups with Different Steric Demands}, journal = {Organometallics}, year = 2023, } @article{CTT100898171, author = {Ryuichi Shimogawa and Yuuki Muroi and Naoya Noguchi and Gen-ichi Konishi and Toshiro Takao and Hiroharu Suzuki}, title = {hoto-Induced Reaction of Cp*Ru(μ-H)4RuCp* with Arenes Resulting in Irreversible Formation of μ-η2:η2-Cyclohexadiene Complexes}, journal = {Organometallics}, year = 2022, } @article{CTT100869100, author = {TOSHIRO TAKAO and Yuta Takahashi and Masataka Kai}, title = {Formation of an Azaruthenacyclopentadiene Skeleton via Ammonia Activation by an Electron-Deficient Ru3 Cluster}, journal = {Chemistry A Europian Journal}, year = 2022, } @article{CTT100851581, author = {TOSHIRO TAKAO and Kouichi Seki}, title = {C-C Bond Formation Between the μ-Alkylidyne Ligands in a Diruthenium Bis(μ-alkylidyne) Complex; σ- and π-Aromaticity of the Ru2C2 Core}, journal = {European Journal of Inoganic Chemistry}, year = 2021, } @article{CTT100851579, author = {TOSHIRO TAKAO and Hidenori Suzuki and Ryuichi Shimogawa}, title = {Syntheses and Properties of Triruthenium Polyhydrido Complexes Composed of 1,2,4-tri-tert-butylcyclopentadienyl and p-Cymene Ruthenium Units}, journal = {Organometallics}, year = 2021, } @article{CTT100851578, author = {TOSHIRO TAKAO and Kouichi Seki}, title = {Synthesis of Diruthenium μ-Chloromethylidyne Complex: C-C Bond Formation at the Bridging Carbon Atom via the Reduction of a μ-Chloromethylidyne Ligand}, journal = {Organometallics}, year = 2021, } @article{CTT100851577, author = {Hajime Kameo and Shigeyoshi Sakaki and Yasuhiro Ohki and NAOKI UEHARA and Takuya Kosukegawa and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {The Four-electron Reduction of Dioxygen on a Metal Surface: Models of Dissociative and Associative Mechanisms in a Homogeneous System}, journal = {Inorganic Chemistry}, year = 2020, } @article{CTT100851573, author = {TOSHIRO TAKAO and Kouichi Seki}, title = {Reversible Transformation of a μ3-η3-C3 Ring into μ3-η2-Ethyne and μ-Vinylidene Ligands at a Triruthenium Site upon Deprotonation and Protonation}, journal = {Organometallics}, year = 2020, } @article{CTT100832424, author = {Yusuke Takahashi and Atsushi Tahara and TOSHIRO TAKAO}, title = {Intramolecular Nitrene Transfer via the C≡N Bond Cleavage of Acetonitrile to a μ3-Alkylidyne Ligand on a Cationic Triruthenium Plane}, journal = {Organometallics}, year = 2020, } @article{CTT100832423, author = {Hiroyuki Tsuruda and TOSHIRO TAKAO}, title = {Synthesis and Site-Dependent Reactivity of a Heterometallic Dinuclear Bis(μ-imido) Complex of Tungsten and Ruthenium}, journal = {J. Organomet. Chem.}, year = 2020, } @article{CTT100832422, author = {TOSHIRO TAKAO}, title = {電子豊富な二核ルテニウム錯体を触媒としたピリジンおよび環状アミンの変換反応}, journal = {有機合成化学協会誌}, year = 2020, } @article{CTT100820075, author = {Takeshi Kaneko and TOSHIRO TAKAO}, title = {Reaction of a Triruthenium μ3-Borylene Complex with Benzonitrile: Formation of a μ3-η3-BCN Ring on a Cationic Ru3 Plane via Photo-Induced Intramolecular Borylene Transfer}, journal = {Organometallics}, year = 2020, } @article{CTT100817331, author = {Ryuichi Shimogawa and Yohei Tsurumaki and Hidenori Suzuki and TOSHIRO TAKAO}, title = {Selective Synthesis of a Triruthenium Pentahydrido Complex with Mixed-Cp Ligands (C5tBu3H2 and C5Me5) and Its Transformation into Face-Capping Benzene Complexes; Fluxionality of a Face-Capping Benzene Ligand Induced by Oxidation}, journal = {Organometallics}, year = 2019, } @article{CTT100806303, author = {Faraday Discussions and Takashi Kawashima and Ryo Nagae and Hideyuki Kanda and Wataru Watanabe}, title = {Diruthenium Complexes Having a Partially Hydrogenated Bipyridine Ligand: Plausible Mechanism for the Dehydrogenative Coupling of Pyridines at a Diruthenium Site}, journal = {}, year = 2019, } @article{CTT100806305, author = {Hiroki Chikamori and Toshiro Takao}, title = {Formation of a μ3-Acetylide on a Ru3 Cluster via Coupling of μ-Methylene with Isocyanide Accompanied by Elimination of Amine: A Model of Hydrogen-Assisted C-C Bond Formation on a Metal Surface}, journal = {Organometallics}, year = 2019, } @article{CTT100817332, author = {Faraday Discussions and Takashi Kawashima and Ryo Nagae and Hideyuki Kanda and Wataru Watanabe}, title = {Diruthenium Complexes Having a Partially Hydrogenated Bipyridine Ligand: Plausible Mechanism for the Dehydrogenative Coupling of Pyridines at a Diruthenium Site}, journal = {Faraday Discussions}, year = 2019, } @article{CTT100806301, author = {Takeshi Kaneko and Hayato Ninagawa and Moe Matsuoka and Toshiro Takao}, title = {Synthesis and Properties of a Triruthenium Hydrido Complex Capped by a μ3-Oxoboryl Ligand}, journal = {Organometallics}, year = 2019, } @article{CTT100806300, author = {Moeko Saito and Shuuhei Kojima and Akiko Inagaki and Kouichi Seki and Toshiro Takao}, title = {Effect of Ring Size on the Properties of μ3-Cycloalkyne Complexes: Synthesis of Triruthenium Complexes Containing a Perpendicularly Coordinated μ3-Allenyl Ligand}, journal = {Jounal of Organometallic Chemistry}, year = 2019, } @article{CTT100787897, author = {Hiroki Chikamori and Atsushi Tahara and TOSHIRO TAKAO}, title = {Transformation of a μ3-Benzyne Ligand into Phenol on a Cationic Triruthenium Cluster Supported by a μ3-Sulfido Ligand}, journal = {Organometallics}, year = 2018, } @article{CTT100787895, author = {Takuya Kosukegawa and TOSHIRO TAKAO}, title = {Synthesis of a Heterometallic Spiked Tetrahedral Cluster of Ruthenium and Nickel Containing Multiple Hydrido Ligands and Its Degradation to a Tetrahedral NiRu3 cluster}, journal = {Journal of organometallic chemistry}, year = 2018, } @article{CTT100777711, author = {TOSHIRO TAKAO and Sachie Horikoshi and Takashi Kawashima and Sachio Asano and Yuta Takahashi and Tarou Sawano and Hiroharu Suzuki}, title = {Catalytic Hydrogenation of Benzonitrile by Triruthenium Clusters; Consecutive Transformations of Benzonitrile on the Face of a Ru3 Plane}, journal = {Organometallics}, year = 2018, } @article{CTT100759432, author = {Ryuichi Shimogawa and Takuya Kuzutani and Toshiro Takao and Yohei Tsurumaki}, title = {Coordination of a P-H Bond at a Sterically Demanding Diruthenium Site: Tautomerization between Agostic μ-Phosphane and μ-Phosphanido Complexes via an η2-P-H Bond Cleavage.}, journal = {Organometallics}, year = 2018, } @article{CTT100754184, author = {Hiroyuki Tsuruda and Yoshihiro Hayashi and Susumu Kawauchi and TOSHIRO TAKAO}, title = {Preparation of Bis(μ3-silylyne) Complexes via Consecutive Si-H Bond Cleavage at a Triruthenium Site.}, journal = {Organometallics}, year = 2017, } @article{CTT100754183, author = {Yuuta Takahashi and Yumiko Nakajima and Hiroharu Suzuki and TOSHIRO TAKAO}, title = {Synthesis of an Electron-Deficient Triruthenium Hydrido Complex Having a Bridging Carbonyl Ligand: Influence of a CO Ligand on the Properties and Reactivities of a Hydrido Cluster.}, journal = {Organometallics}, year = 2017, } @article{CTT100743261, author = {Ryuichi Shimogawa and Ryosuke Fujita and Toshiro Takao and Hiroharu Suzuki}, title = {Dehydrogenative Oxidation of Cyclic Amines on a Diruthenium Complex}, journal = {Organometallics}, year = 2017, } @article{CTT100743260, author = {Hajime Kameo and Yutaka Ito and Ryuichi Shimogawa and Asuka Koizumi and Hiroki Chikamori and Jyunko Fujimoto and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {Synthesis and Characterisation of Tetranuclear Ruthenium Polyhydrido Clusters with Pseudo-Tetrahedral Geometry}, journal = {Dalton transactions}, year = 2017, } @article{CTT100743257, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Half-Sandwich Cyclopentadienyl Iridium Dichloride Monomer Cp‡IrCl2 (Cp‡ = 1,2,4-tri-tert-butylcylclopentadienyl)}, journal = {Chem. Lett.}, year = 2016, } @article{CTT100709385, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Versatile and Highly Efficient Synthesis of Diruthenium Tetrahydride Complex}, journal = {J. Organomet. Chem.}, year = 2016, } @article{CTT100713147, author = {TOSHIRO TAKAO and Takuya Kuzutani and Yushi Torihata and HIROHARU SUZUKI}, title = {Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Platinum with a Linear Alignment}, journal = {}, year = 2016, } @article{CTT100713145, author = {Masahiro Nagaoka and Takashi Kawashima and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear Complex of Ruthenium and Cobalt}, journal = {Organometallics}, year = 2016, } @article{CTT100713146, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Modified synthesis of mixed-ligand dinuclear Ru–Ir, Ru–Rh, and Ru–Ru polyhydride-bridged complexes, CpsRuH3ML (Cps = C5Me5 (Cp*), C5tBu3H2 (Cp‡); M = Rh, Ir, Ru; L = C5(CH3)5, C6H6, p-CH3C6H4CH(CH3)2)}, journal = {}, year = 2016, } @article{CTT100709388, author = {Takeshi Kaneko and Eisuke Murotani and Ryuichi Tenjimbayashi and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {Photolysis of Triruthenium m3-Alkyne Complexes Capped by a m3-Oxo Ligand}, journal = {J. Organomet. Chem.}, year = 2016, } @article{CTT100709389, author = {Ryuichi Shimogawa and Gen-ichi Konishi and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Photo-induced Reactions of Diruthenium Tetrahydride Complexes: Carbon–Hydrogen Bond Cleavage of Tetrahydrofuran Leading to Bridging Cyclic Fischer-Type Carbene Complexes}, journal = {Organometallics}, year = 2016, } @article{CTT100709384, author = {Masahiro Nagaoka and Hiroyuki Tsuruda and Masa-aki Amako and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {m3-h2:h2:h2-Coordination of Primary Silane on a Triruthenium Plane}, journal = {Angew. Chem. Int. Ed.}, year = 2015, } @article{CTT100692234, author = {Masahiro Nagaoka and Takanori Shima and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Trinuclear myu3-Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions and Transformation of a myu3-Silyl Complex of Ru2Ir into myu-Silyl and myu3-Silylene Complexes}, journal = {ORGANOMETALLICS}, year = 2014, } @article{CTT100676407, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and Gen-ichi Konishi and HIROHARU SUZUKI}, title = {Photochemical Reaction of Diruthenium Tetrahydride-bridged Complexes with Carbon Dioxide: Insertion of CO2 into Ru-H Bond versus C=O Double Bond Cleavage}, journal = {Organometallics}, year = 2014, } @article{CTT100678432, author = {TOSHIRO TAKAO and Hiroharu Suzuki}, title = {Activation of Linear Alkanes by a Hydrido Triruthenium Cluster and Associated Skeletal Rearrangements}, journal = {Bull. Chem. Soc. Jpn.}, year = 2013, } @article{CTT100678431, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and Hiroharu Suzuki}, title = {Synthesis, Characterization, and Reactions of Ru(II), Ru(III), and Ru(IV) Complexes with Sterically Demanding 1,2,4-Tri-tert-butylcyclopentadienyl Ligands}, journal = {Organometallics}, year = 2013, } @article{CTT100662676, author = {Takeshi Kaneko and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {A Triruthenium Complex Capped by a Triply Bridging Oxoboryl Ligand}, journal = {Angewandte chemie : international edition in English}, year = 2013, } @article{CTT100649023, author = {Takeshi Kaneko and Hitoshi Suwa and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Intramolecular Borylene Transfer Leading to the Formation of a μ3-BC2 Ring on a Triruthenium Plane}, journal = {Organometallics}, year = 2013, } @article{CTT100649016, author = {Atsushi Tahara and Mana Kajigaya and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Complex Containing μ3-η2(||)-Ethyne and μ3-Methylidyne Ligands: Equilibrium of an Ethyne–Hydrido Complex with a Nonclassical μ3-Vinyl Complex}, journal = {Organometallics}, year = 2013, } @article{CTT100649021, author = {HIROHARU SUZUKI and Ryuichi Shimogawa and Yuuki Muroi and TOSHIRO TAKAO and Masato Osima and Gen-ichi Konishi}, title = {Bimetallic Activation of 2-Alkanones through Photo-Induced α-Hydrogen Abstraction Mediated by a Dinuclear Tetrahydride Complex}, journal = {Angewandte Chemie Internal Edition}, year = 2013, } @article{CTT100661583, author = {Masahiro Nagaoka and Takanori Shima and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Iridium Containing a Perpendicularly Coordinated Alkyne Ligand and Its Dynamic Behavior}, journal = {Journal of Organometallic Chemistry}, year = 2013, } @article{CTT100649006, author = {Masahiro Nagaoka and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Synthesis of a Heterometallic Trinuclear Cluster Containing Ruthenium and Cobalt and Its Reactivity with Internal Alkynes}, journal = {Organometallics}, year = 2012, } @article{CTT100641425, author = {Toshiro Takao and Takashi Kawashima and Hideyuki Kanda and Rei Okamura and Hiroharu Suzuki}, title = {Synthesis of Triruthenium Complexes Containing a Triply Bridging Pyridyl Ligand and Its Transformations to Face-Capping Pyridine and Perpendicularly Coordinated Pyridyl Ligands}, journal = {Organometallics}, year = 2012, } @article{CTT100641424, author = {Toshiro Takao and Hiroharu Suzuki}, title = {Skeletal Rearrangement of Hydrocarbyl Ligands on a Triruthenium Core Induced by Chemical Oxidation}, journal = {Coordination Chemistry Reviews}, year = 2012, } @article{CTT100641423, author = {Hideyuki Kanda and Takashi Kawashima and Toshiro Takao and Hiroharu Suzuki}, title = {Reactions of a Triruthenium Pentahydrido Complex with Imines Leading to the Formation of a Perpendicularly Coordinated Iminoacyl Ligand and the Scission of a C=N Bond on a Triruthenium Plane}, journal = {Organometallics}, year = 2012, } @article{CTT100641422, author = {Toshiro Takao and Hitoshi Suwa and Rei Okamura and Hiroharu Suzuki}, title = {Formation of a Boraruthenacyclopentenyl Skeleton via B–C Bond Formation across a Triruthenium Plane}, journal = {Organometallics}, year = 2012, } @article{CTT100629456, author = {Toshiro Takao and Nozomi Obayashi and Bo Zhao and Kazunori Akiyoshi and Hideki Omori and Hiroharu Suzuki}, title = {Synthesis and Property of Diruthenium Complexes Containing Bridging Cyclic Diene Ligands and the Reaction of Diruthenium Tetrahydrido Complex with Benzene Forming a m-h2:h2-Cyclohexadiene Complex via Partial Hydrogenation on a Ru2 Center}, journal = {Organometallics}, year = 2011, } @article{CTT100617520, author = {Atsushi Tahara and Mana Kajigaya and Makoto Moriya and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Metathesis Reaction of Hydrocarbyl Ligands across Triruthenium Plane}, journal = {Angew. Chem. Int. Ed.}, year = 2010, } @article{CTT100617523, author = {TOSHIRO TAKAO and Makoto Moriya and Mana Kajigaya and HIROHARU SUZUKI}, title = {Direct Arylation of a Cluster-Bound Alkyne Ligand with Benzene}, journal = {Organometallics}, year = 2010, } @article{CTT100617517, author = {Makoto Moriya and Atsushi Tahara and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Arylation of a Hydrocarbyl Ligand Formed from n-Alkane via C-H Bond Activation of Benzene using a Triruthenium Cluster}, journal = {Eur. J. Inorg. Chem.}, year = 2009, } @article{CTT100582095, author = {TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Skeletal Rearrangement of a Hydrocarbyl Moiety on a Triruthenium Cluster}, journal = {Journal of Synthetic Organic Chemistry, Japan}, year = 2009, } @article{CTT100564750, author = {TOSHIRO TAKAO and Kazunori Akiyoshi and HIROHARU SUZUKI}, title = {Preparation and Properties of Diruthenium Hydrido Complexes Having a Bridging Benzoquinone Ligand: Formation of an Alcohol Adduct of a m-h2:h2-Benzoquinone Complex through Hydrogen Bonding}, journal = {Organometallics}, year = 2008, } @article{CTT100551304, author = {TOSHIRO TAKAO and Makoto Moriya and HIROHARU SUZUKI}, title = {Insertion of Acetylene and Nitriles into a Ru-C Bond of a Dicationic Triruthenium Complex Having a m3-h3-C3 Ring: Formation of Six-Membered Ruthenacycles on a Triruthenium Core}, journal = {Organometallics}, year = 2008, } @article{CTT100548553, author = {TOSHIRO TAKAO and Makoto Moriya and HIROHARU SUZUKI}, title = {Introduction of a Methoxy Group into a Hydrocarbyl Ligand Derived from a Linear Alkane on a Triruthenium Cluster via Chemical Oxidation}, journal = {Organometallics}, year = 2008, } @article{CTT100546682, author = {TOSHIRO TAKAO and HIROHARU SUZUKI and Takashi Kawashima}, title = {Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by Diruthenium Complexes}, journal = {J. Am. Chem. Soc}, year = 2007, } @article{CTT100532271, author = {Makoto Moriya and Toshiro Takao and Hiroharu Suzuki}, title = {Synthesis and Structure of Cationic Triruthenium Complexes Containing an Oxametallacycle; Reversible Carbon-Oxygen Bond Formation and Scission on an Electron-Deficient Triruthenium Plane}, journal = {Organometallics}, year = 2007, } @article{CTT100520893, author = {Takashi Kawashima and Toshiro Takao and Hiroharu Suzuki}, title = {Synthesis and Structure of a Triruthenium Complex Containing a Face-Capping Pyridine Ligand}, journal = {Angew. Chem., Int. Ed.}, year = 2006, } @article{CTT100520897, author = {Toshiro Takao and Akiko Inagaki and Tsubomi Imamura and Hiroharu Suzuki}, title = {Oxidation-induced Rearrangement from a nido- to a closo-Ruthenacyclopentadiene}, journal = {Organometallics}, year = 2006, } @article{CTT100402263, author = {Takashi Kawashima and Toshiro Takao and Hiroharu Suzuki}, title = {Cleavage of the C-N Triple Bond on the Triruthenium Cluster: Synthesis and Structure of a Triruthenium Complex Containing a μ3-Nitrido Ligand}, journal = {Angew. Chem. Int. Ed.}, year = 2006, } @article{CTT100392974, author = {Toshiro Takao and Shigeru Yoshida and Hiroharu Suzuki}, title = {Substitution Reaction at a Bridging Silicon Ligand. Formation of a Bis(μ-Silylene) Complex Containing a Trifluoroacetoxyl Group, and Mechanistic Studies of the Site-exchange Process of the Hydride Ligands}, journal = {Organometallics}, year = 2005, } @article{CTT100499638, author = {Hiroharu Suzuki and Takeaki Kakigano and Ken-ichi Tada and Minoru Igarashi and Kouki Matsubara and Akiko Inagaki and Masato Oshima and Toshiro Takao}, title = {Synthesis, Structures, and Reactions of Coordinatively Unsaturated Trinuclear Ruthenium Polyhydrido Complexes, [{Ru(C5Me5)}3(μ-H)6](Y) (Y = BF4, CF3SO3, 1/2(SO4), C6H5CO2, CH3CO2, B(C6H5)4, PF6) and [{Ru(C5Me5)}3(μ-H)33-H)2]}, journal = {Bull. Chem. Soc. Jpn.}, year = 2005, } @article{CTT100392973, author = {Toshiro Takao and Takashi Kawashima and Kouki Matsubara and Hiroharu Suzuki}, title = {Synthesis and Structure of a Triruthenium Complex Containing a Perpendicularly Coordinated μ322(⊥)-Nitrile Ligand, and Its Protonation to Yield a Perpendicularly Coordinated Iminoacyl Ligand}, journal = {Organometallics}, year = 2005, } @article{CTT100499636, author = {Toshiro Takao and Yoshiaki Takaya and Eisuke Murotani and Ryu-ichi Tenjimbayashi and Hiroharu Suzuki}, title = {Synthesis and Characterization of Triruthenium Complexes Containing a Perpendicularly Coordinated Alkyne Ligand}, journal = {Organometallics}, year = 2004, } @article{CTT100499637, author = {Toshiro Takao and Satoshi Kakuta and Ryu-ichi Tenjimbayashi and Toshifumi Takemori and Eisuke Murotani and Hiroharu Suzuki}, title = {Fluxional Behavior of a Perpendicularly Coordinated μ3-Alkyne ligand on a Triruthenium cluster. Synthesis and Structure of a μ322(⊥)-Cycloalkyne Complex}, journal = {Organometallics}, year = 2004, } @article{CTT100678462, author = {Akiko Inagaki and TOSHIRO TAKAO and Makoto Moriya and Hiroharu Suzuki}, title = {Thermal Skeletal Rearrangement of a nido-Ruthenacyclopentadiene Complex Involving Reversible Rupture and Formation of a Ruthenium-Ruthenium Bond}, journal = {Organometallics}, year = 2003, } @article{CTT100678455, author = {TOSHIRO TAKAO and Akiko Inagaki and Eisuke Murotani and Tsubomi Imamura and Hiroharu Suzuki}, title = {Bimetallic Reductive C-C Coupling Reaction Induced by Chemical Oxidation; Formation of a myu3-C3 Ring on a Triruthenium Cluster}, journal = {Organometallics}, year = 2003, } @article{CTT100483197, author = {Toshiro Takao and Masa-aki Amako and Hiroharu Suzuki}, title = {Successive Si-H/Si-C Bond Cleavage of Tertiarysilanes on Diruthenium Centers. Reactivities and Fluxional Behavior of the Bis(μ-silylene) Complexes Containing μ-Hydride Ligands}, journal = {Organometallics}, year = 2003, } @article{CTT100678463, author = {TOSHIRO TAKAO and Toshifumi Takemori and Makoto Moriya and Hiroharu Suzuki}, title = {Skeletal Rearrangement of a C2 Unit on a Triruthenium Cluster. Synthesis of m-Ethylidene,m3-Ethylidyne, and m3-Vinylidene Complexes by the Reaction of {Cp*Ru(m-H)}3(m3-H)2 with Acetylene}, journal = {Organometallics}, year = 2002, } @article{CTT100678460, author = {TOSHIRO TAKAO and Masa-aki Amako and Hiroharu Suzuki}, title = {Reactions of Diruthenium Tetrahydride Complex (h5-C5Me5)Ru(m-H)4Ru(h5-C5Me5) with Vinylsilanes: Formation of a m-Silylene Complex via Successive Si–H and Si–C Bond Cleavage of Dimethylvinylsilane}, journal = {Organometallics}, year = 2001, } @article{CTT100678459, author = {TOSHIRO TAKAO and Shigeru Yoshida and Hiroharu Suzuki}, title = {Protonation of Bis-m-Diethylsilyl Complex {(C5Me5)Ru(m-h2-HSiEt2)}(m-H)(H). Enhancement of Bonding Interaction between Bridging Silicon and Hydride Ligands}, journal = {Chem. Lett.}, year = 2001, } @article{CTT100449713, author = {Toshiro Takao and Masa-aki Amako and Hiroharu Suzuki}, title = {Reactions of Diruthenium Tetrahydride Complex (C5Me5)Ru(μ-H)4Ru(C5Me5) with Vinylsilanes: Formation of a μ-Silylene Complex via Successive Si-H and Si-C Bond Cleavage of Dimethylvinylsilane}, journal = {Organometallics}, year = 2001, } @article{CTT100678461, author = {TOSHIRO TAKAO and Shigeru Yoshida and Hiroharu Suzuki and Masako Tanaka}, title = {Synthesis, Characterization, and Reactivities of Diruthenium Complexes Containing m-Silane Ligand, and Structural Studies of m-Silane Complex [Cp'Ru(CO)]2(m-h2:h2-H2SitBu2)}, journal = {Organometallics}, year = 1995, } @article{CTT100427142, author = {Toshiro Takao and Hiroharu Suzuki and Masako Tanaka}, title = {Insertion of Acetylene into The Ru-Si Bond of a Bis(μ-Silylene) Complex. Synthesis and Structure of a 2,5-Disilaruthenacyclopentene Complex}, journal = {Organometallics}, year = 1994, } @article{CTT100427030, author = {Hiroharu Suzuki; Toshiro Takao; Masako Tanaka; Yoshihiko Moro-oka and HIROHARU SUZUKI and Masako Tanaka and Yoshihiko Moro-oka}, title = {Synthesis and Reactivities of Dinuclear μ-Silyl Complexes of Ruthenium having Three-center Two-electron Ru-H-Si Interactions.}, journal = {J. C. S., Chem. Commun.}, year = 1992, } @inproceedings{CTT100898193, author = {Naoya Noguchi and TOSHIRO TAKAO}, title = {二重芳香族性 Ru2C2コアをもつ二核ルテニウムビス架橋エチリジ ン錯体の反応性}, booktitle = {}, year = 2023, } @inproceedings{CTT100898194, author = {Shiyu Egawa and TOSHIRO TAKAO}, title = {三重架橋メチリジン配位子を有する 50 電子カチオン性ルテニウ ム三核錯体の合成及び反応性}, booktitle = {}, year = 2023, } @inproceedings{CTT100898195, author = {Yuji Shibata and Takuya Kosukegawa and TOSHIRO TAKAO}, title = {Cp*, p-cymene 混合配位子型三核ルテニウムヒドリド錯体の合成 と反応性の検討}, booktitle = {}, year = 2023, } @inproceedings{CTT100869096, author = {TOSHIRO TAKAO and Kouichi Seki}, title = {Dual Aromaticity of the Ru2C2 Core in a Diruthenium Bis(μ-alkylidyne) Complex; C−C Bond Formation Between the μ-Alkylidyne Ligands}, booktitle = {}, year = 2021, } @inproceedings{CTT100869098, author = {Masataka Kai and TOSHIRO TAKAO}, title = {ジカチオン性ベンザイン三核ルテニウム錯体とアンモニアとの反応によるC-N結合の形成}, booktitle = {}, year = 2021, } @inproceedings{CTT100869097, author = {Shinji Matsuzawa and Masahiro Nagaoka and TOSHIRO TAKAO}, title = {レニウムと9族金属からなる二核ポリヒドリド錯体の合成と反応性}, booktitle = {}, year = 2021, } @inproceedings{CTT100833414, author = {Hidenori Suzuki and TOSHIRO TAKAO}, title = {Cp/Arene 混合配位子型カチオン性三核ルテニウムヒドリド錯体の合成とその反応性}, booktitle = {}, year = 2020, } @inproceedings{CTT100833415, author = {Kouichi Seki and TOSHIRO TAKAO}, title = {クロロメチリジン配位子を持つ二核ルテニウム錯体を用いたカーバイド錯体の合成}, booktitle = {}, year = 2020, } @inproceedings{CTT100806307, author = {TOSHIRO TAKAO and Takashi Kawashima and Hideyuki Kanda and Ryo Nagae}, title = {フェナントロリン配位子を有する二核ルテニウム錯体の性質と二核ルテニウム反応場でのピリジンの脱水素カップリング反応のメカニズム}, booktitle = {}, year = 2019, } @inproceedings{CTT100787899, author = {Takuya Kosukegawa and TOSHIRO TAKAO}, title = {Ru4Niデカヒドリドクラスターと不飽和結合を有する基質との反応}, booktitle = {}, year = 2019, } @inproceedings{CTT100817330, author = {TOSHIRO TAKAO and Hiroyuki Tsuruda}, title = {Synthesis and Reactivity of WRu Dinuclear Polyhydrido Complexes with Trimethylphosphine Ligands on Tungsten}, booktitle = {}, year = 2019, } @inproceedings{CTT100806309, author = {Hiroyuki Tsuruda and Toshiro Takao}, title = {Synthesis and Reactivity of Heteronuclear WRu Complexes Bridged by Imido Ligands}, booktitle = {}, year = 2019, } @inproceedings{CTT100806308, author = {Hidenori Suzuki and Ryuichi Shimogawa and TOSHIRO TAKAO}, title = {Cp-Ar 混合配位子型三核トリヒドリド錯体の合成とその性質}, booktitle = {}, year = 2019, } @inproceedings{CTT100787898, author = {Hiroki Chikamori and Atsushi Tahara and TOSHIRO TAKAO}, title = {カチオン性三核ルテニウム錯体上でのベンゼンのヒドロキシル化}, booktitle = {}, year = 2018, } @inproceedings{CTT100787901, author = {TOSHIRO TAKAO and Ryuichi Shimogawa}, title = {Dehydrogenative Oxidation of Cyclic Amines on a Diruthenium Complex Supported by Bulky Cyclopentadienyl Ligands}, booktitle = {}, year = 2018, } @inproceedings{CTT100787903, author = {Hiroyuki Tsuruda and TOSHIRO TAKAO}, title = {Preparation of Bis(μ3-silylyne) Complexes via Consecutive Si-H Bond Cleavage at a Triruthenium Site}, booktitle = {}, year = 2018, } @inproceedings{CTT100787902, author = {Hiroki Chikamori and Atsushi Tahara and TOSHIRO TAKAO}, title = {Phenol Synthesis by the Oxidation and Hydroxylation of a Triruthenium Benzyne Complex}, booktitle = {}, year = 2018, } @inproceedings{CTT100761118, author = {Ryo Nagae and TOSHIRO TAKAO}, title = {ジヒドロビピリジン配位子を有した二核ルテニウム錯体の反応性}, booktitle = {}, year = 2018, } @inproceedings{CTT100761119, author = {Takuya Kosukegawa and TOSHIRO TAKAO}, title = {Ru4Ni デカヒドリドクラスターの構造と反応}, booktitle = {}, year = 2018, } @inproceedings{CTT100761117, author = {Hayato Ninagawa and TOSHIRO TAKAO}, title = {三重架橋オキソボリル配位子を有する三核ルテニウム錯体の反応性}, booktitle = {}, year = 2018, } @inproceedings{CTT100759433, author = {Hiroki Chikamori and Atsushi Tahara and Toshiro Takao}, title = {Hydroxylation of Benzene to Form Phenol via μ3-Benzyne Complex}, booktitle = {}, year = 2018, } @inproceedings{CTT100754190, author = {TOSHIRO TAKAO and Takuya Kosukegawa}, title = {RuとNiを含むポリヒドリドクラスターの合成}, booktitle = {}, year = 2017, } @inproceedings{CTT100754189, author = {Naoya Osamura and TOSHIRO TAKAO}, title = {Inを導入したRuヒドリドクラスターの合成と反応性}, booktitle = {}, year = 2017, } @inproceedings{CTT100754187, author = {Hiroyuki Tsuruda and TOSHIRO TAKAO}, title = {Synthesis of Heteronuclear WRu Complexes Bridged by Imido Ligand}, booktitle = {}, year = 2017, } @inproceedings{CTT100754186, author = {Hiroki CHikamori and TOSHIRO TAKAO}, title = {Transformations of the Methylidyne and Methylene Ligand on the Triruthenium Complex}, booktitle = {}, year = 2017, } @inproceedings{CTT100754185, author = {Yuta Takahashi and TOSHIRO TAKAO}, title = {Synthesis and Photo-reactivity of a Triruthenium Cluster Having a μ3-η3-C3 Ring}, booktitle = {}, year = 2017, } @inproceedings{CTT100743263, author = {Ryuichi Shimogawa and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {ハーフサンドイッチ型イリジウムジクロリド単量体の合成と性質}, booktitle = {}, year = 2017, } @inproceedings{CTT100743266, author = {Sachie Horikoshi and Takashi Kawashima and TOSHIRO TAKAO}, title = {架橋カルボニル配位子を有する三核ルテニウム錯体を用いたベンゾニトリルの触媒的水素化によるベンジルアミンの選択的合性}, booktitle = {}, year = 2017, } @inproceedings{CTT100743265, author = {Hiroki Chikamori and TOSHIRO TAKAO}, title = {三重架橋スルフィド配位子を有する三核ルテニウムメチリジン錯体の合成と反応性}, booktitle = {}, year = 2017, } @inproceedings{CTT100743264, author = {Yuuta Takahashi and TOSHIRO TAKAO}, title = {架橋カルボニル配位子を有する三核ルテニウムトリヒドリド錯体の性質}, booktitle = {}, year = 2017, } @inproceedings{CTT100743262, author = {Ryuichi Shimogawa and Yohei Tsurumaki and Takuya Kuzutani and Hiroharu Suzuki and Toshiro Takao}, title = {Formation of an Agostic P–H bond on a Sterically Demanding Diruthenium Complex}, booktitle = {}, year = 2017, } @inproceedings{CTT100719960, author = {Yuuta Takahashi and TOSHIRO TAKAO}, title = {炭素三員環を有する三核ルテニウム錯体の光反応性}, booktitle = {}, year = 2016, } @inproceedings{CTT100743271, author = {Ryuichi Shimogawa and Ryosuke Fujita and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {Dehydrogenative Coupling Reaction of Saturated Cyclic Amines and Water using Di-Ruthenium Complex and Mechanistic Studies}, booktitle = {}, year = 2016, } @inproceedings{CTT100743270, author = {Yusuke Takahashi and TOSHIRO TAKAO}, title = {Metathesis of a μ3-Imidoyl Ligand via Partial Breaking at a Triruthenium Skeleton}, booktitle = {}, year = 2016, } @inproceedings{CTT100743269, author = {Yuuta Takahashi and TOSHIRO TAKAO}, title = {Photo-reactivity of a Triruthenium Cluster Having a μ3-η3-C3 Ring}, booktitle = {}, year = 2016, } @inproceedings{CTT100719965, author = {TOSHIRO TAKAO and Hiroyuki Tsuruda}, title = {タングステン上に三座キレートホスフィン配位子を有するWRu二核ヒドリド錯体の合成}, booktitle = {}, year = 2016, } @inproceedings{CTT100719964, author = {Hiroki Chikamori and TOSHIRO TAKAO}, title = {Synthesis and Reactivities of Cationic Triruthenium Alkyne Complexes Supported by a μ3-Sulfido and μ3-Oxo Ligand}, booktitle = {}, year = 2016, } @inproceedings{CTT100719963, author = {Ryuichi Shimogawa and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {Photo- and thermoreactions of diruthenium tetrahydride complex with saturated heterocyclic comppunds}, booktitle = {}, year = 2016, } @inproceedings{CTT100713180, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Versatile and Highly Efficient Synthesis of Dinuclear Polyhydride Complexes Using 2-propanol/base Method}, booktitle = {}, year = 2016, } @inproceedings{CTT100719962, author = {Masahiro Nagaoka and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear Complex of Ruthenium and Cobalt}, booktitle = {}, year = 2016, } @inproceedings{CTT100713189, author = {TOSHIRO TAKAO and Takeshi Kaneko}, title = {三重架橋ボリレン錯体への光照射によるBCN三員環骨格の構築}, booktitle = {}, year = 2016, } @inproceedings{CTT100713172, author = {Ryuichi Shimogawa and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {二核ルテニウムテトラヒドリド錯体と二硫化炭素との反応: 二酸化炭素の二重結合切断反応の機構的考察}, booktitle = {}, year = 2016, } @inproceedings{CTT100713171, author = {Masahiro Nagaoka and TOSHIRO TAKAO}, title = {ビピリジン-コバルトとCp*-ルテニウム部位から成る異種金属錯体の電子構造と反応挙動}, booktitle = {}, year = 2016, } @inproceedings{CTT100713170, author = {Takeshi Kaneko and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三核ルテニウムクラスター上での BCN 三員環の形成}, booktitle = {}, year = 2016, } @inproceedings{CTT100713176, author = {Yohei Tsurumaki and Ryuichi Shimogawa and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {混合配位子三核ルテニウムヒドリド錯体上での面配位ベンゼン配位子の動的性質}, booktitle = {}, year = 2016, } @inproceedings{CTT100713174, author = {Yusuke Takahashi and Takeshi Kaneko and TOSHIRO TAKAO}, title = {三核ルテニウム錯体上でのアルキンとアセトニトリルのメタセシス反応}, booktitle = {}, year = 2016, } @inproceedings{CTT100713173, author = {Moeko Saito and TOSHIRO TAKAO}, title = {環状アルキン配位子を有する三核ルテニウム錯体の酸化反応}, booktitle = {}, year = 2016, } @inproceedings{CTT100713177, author = {Ryosuke Fujita and Ryuichi Shimogawa and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {二核ルテニウムテトラヒドリド錯体を用いた環状アミンの触媒的脱水素酸化反応}, booktitle = {}, year = 2016, } @inproceedings{CTT100713169, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Photochemical reaction of diruthenium tetrahydride-bridged complexes with carbon dioxide: Insertion of CO2}, booktitle = {}, year = 2015, } @inproceedings{CTT100713148, author = {Takeshi Kaneko and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {Synthesis and Property of a Triruthenium Tetrahydride Cluster Capped by a Triply Bridging Oxoboryl Ligand}, booktitle = {}, year = 2015, } @inproceedings{CTT100713167, author = {Hiroyuki Tsuruda and Masa-aki Amako and Masahiro Nagaoka and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三核ルテニウム錯体上での一級シランの段階的な酸化付加反応}, booktitle = {}, year = 2015, } @inproceedings{CTT100713151, author = {Moeko Saito and TOSHIRO TAKAO and Shuuhei Kojima and HIROHARU SUZUKI}, title = {三核ルテニウム反応場上での八員環の環縮小反応}, booktitle = {}, year = 2015, } @inproceedings{CTT100713150, author = {Ryuichi Shimogawa and Ryosuke Fujita and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {Dehydrogenative Coupling Reactions of Saturated Cyclic Amines on Di-Ruthenium Tetrahydride Complex}, booktitle = {}, year = 2015, } @inproceedings{CTT100713149, author = {Masahiro Nagaoka and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Mechanistic Insight into the Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by Trinuclear Complex Composed of Ruthenium and Cobalt}, booktitle = {}, year = 2015, } @inproceedings{CTT100713168, author = {TOSHIRO TAKAO and Masahiro Nagaoka and HIROHARU SUZUKI}, title = {Synthesis of μ3-Silyl Complexes of Ruthenium and Group 9 Metals and Its Transformation into μ3-Silylene Complex}, booktitle = {}, year = 2015, } @inproceedings{CTT100692245, author = {Takeshi Kaneko and TOSHIRO TAKAO}, title = {オキソボリル配位子のプロトン感応性を利用した新規多核反応場の構築}, booktitle = {}, year = 2015, } @inproceedings{CTT100692239, author = {Hiroki Chikamori and Atsushi Tahara and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三重架橋スルフィド配位子を有する常磁性三核ルテニウムベンザイン錯体の合成およびフェノール生成反応}, booktitle = {}, year = 2015, } @inproceedings{CTT100692238, author = {Takuya Kuzutani and Yushi Torihata and Kyo Namura and TOSHIRO TAKAO}, title = {ルテニウム及び白金からなる直線型異種金属ポリヒドリド錯体の反応性}, booktitle = {}, year = 2015, } @inproceedings{CTT100692236, author = {Yuuta Takahashi and TOSHIRO TAKAO}, title = {架橋カルボニル配位子を有する三核ルテニウムトリヒドリド錯体と不飽和炭化水素との反応}, booktitle = {}, year = 2015, } @inproceedings{CTT100692235, author = {Takeshi Kaneko and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三重架橋オキソボリル配位子を有する三核ルテニウムテトラヒドリド錯体の効率的合成}, booktitle = {}, year = 2015, } @inproceedings{CTT100692240, author = {Hiroyuki Tsuruda and Masahiro Nagaoka and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {ビス三重架橋シリリン錯体の合成}, booktitle = {}, year = 2015, } @inproceedings{CTT100692242, author = {TOSHIRO TAKAO}, title = {三重架橋ベンザイン錯体を鍵としたベンゼンへの直截的官能基導入反応の開発}, booktitle = {}, year = 2015, } @inproceedings{CTT100678452, author = {TOSHIRO TAKAO and Atsushi Tahara and Mana Kajigaya and Makoto Moriya and Hiroharu Suzuki}, title = {Consecutive Carbyne Migration across the Triruthenium Plane}, booktitle = {}, year = 2014, } @inproceedings{CTT100678434, author = {Takeshi Kaneko and TOSHIRO TAKAO and Hiroharu Suzuki}, title = {Photochemical Reaction of Triruthenium Alkyne Complexes Having a Triply Bridging Oxo Ligand}, booktitle = {}, year = 2014, } @inproceedings{CTT100678436, author = {Takuya Kuzutani and Yushi Torihata and Kyo Namura and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {ルテニウム及び白金を含む異種金属ポリヒドリド錯体の合成と反応性}, booktitle = {}, year = 2014, } @inproceedings{CTT100678435, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {2-propanolをヒドリド源として用いた新規異種金属および混合配位子型二核ポリヒドリド錯体 (RuRu, RuRh, RuIr) の合成と性質}, booktitle = {}, year = 2014, } @inproceedings{CTT100678433, author = {Masahiro Nagaoka and TOSHIRO TAKAO and Hiroharu Suzuki}, title = {Dehydrogenative Coupling of Pyridines Catalyzed by Trinuclear Complex Composed of Ruthenium and Cobalt}, booktitle = {}, year = 2014, } @inproceedings{CTT100678440, author = {Masahiro Nagaoka and TOSHIRO TAKAO and Hiroharu Suzuki}, title = {Trinuclear myu3-Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions}, booktitle = {}, year = 2014, } @inproceedings{CTT100678442, author = {Masahiro Nagaoka and TOSHIRO TAKAO and Hiroharu Suzuki}, title = {Synthesis of a Heterometallic Cluster Containing Ruthenium and Cobalt and Its Reactivity with Internal Alkynes}, booktitle = {}, year = 2014, } @inproceedings{CTT100678437, author = {TOSHIRO TAKAO and Takashi Kawashima and Hideyuki Kanda and Wataru Watanabe and Hiroharu Suzuki}, title = {Synthesis and Property of Diruthenium Complexes having a Partially Hydrogenated Bipyridine Ligand}, booktitle = {}, year = 2014, } @inproceedings{CTT100678438, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and Hiroharu Suzuki}, title = {Synthesis, Characterization, and Reactions of Ru(II), Ru(III), and Ru(IV) Complexes with Sterically Demanding 1,2,4-Tri-tert-butylcyclopentadienyl Ligands}, booktitle = {}, year = 2014, } @inproceedings{CTT100678439, author = {Takeshi Kaneko and TOSHIRO TAKAO and Hiroharu Suzuki}, title = {Reaction of a Triruthenium Borylene Complex with Water Leading to the Formation of a myu3-Oxoboryl Complex}, booktitle = {}, year = 2014, } @inproceedings{CTT100678441, author = {Takeshi Kaneko and TOSHIRO TAKAO and Hiroharu Suzuki}, title = {Formation of a BC2-Ring on a Triruthenium Plane}, booktitle = {}, year = 2014, } @inproceedings{CTT100678443, author = {Masahiro Nagaoka and TOSHIRO TAKAO}, title = {ルテニウムと9族金属から成る一連の異種金属クラスターの合成と反応}, booktitle = {}, year = 2014, } @inproceedings{CTT100678444, author = {TOSHIRO TAKAO}, title = {三重架橋ボリレン配位子の光感応性を用いた新規多核反応場の構築}, booktitle = {}, year = 2014, } @inproceedings{CTT100678445, author = {Takeshi Kaneko and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三重架橋オキソボリル配位子を有する三核ルテニウムアルキン錯体の合成と反応}, booktitle = {}, year = 2014, } @inproceedings{CTT100678446, author = {HIROHARU SUZUKI and TOSHIRO TAKAO and Ryuichi Shimogawa}, title = {二核ルテニウムポリヒドリドクラスターと二酸化炭素との光反応}, booktitle = {}, year = 2014, } @inproceedings{CTT100678447, author = {Masahiro Nagaoka and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {レニウムとイリジウムから成る異種金属二核錯体の合成と性質}, booktitle = {}, year = 2014, } @inproceedings{CTT100678448, author = {Tomohiro Kawahara and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {トリフルオロメチル基で置換したシクロペンタジエニル基を支持配位子として有する多核ルテニウムポリヒドリド錯体の合成と性質}, booktitle = {}, year = 2014, } @inproceedings{CTT100678450, author = {Masahiro Nagaoka and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {ルテニウムと9族金属から成る異種金属クラスターの合成と反応性}, booktitle = {}, year = 2013, } @inproceedings{CTT100661592, author = {Ryuichi Shimogawa and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {嵩高い1,2,4-tri-tert-butylcyclopentadienylを支持配位子に有する二価、三価、四価クロロルテニウム錯体の合成と反応性}, booktitle = {}, year = 2013, } @inproceedings{CTT100661593, author = {Yuuta Takahashi and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三核ルテニウム錯体上での二酸化炭素の分子変換反応の開発}, booktitle = {}, year = 2013, } @inproceedings{CTT100661591, author = {Masahiro Nagaoka and Takanori Shima and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {ルテニウムと9族金属から成る異種金属クラスターを用いた三重架橋シリル錯体の合成}, booktitle = {}, year = 2013, } @inproceedings{CTT100649029, author = {Atsushi Tahara and Yumiko Yamamoto and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Activation of Benzene by a Triruthenium Cluster having a μ3-Sulfido Ligand}, booktitle = {}, year = 2013, } @inproceedings{CTT100661588, author = {Takeshi Kaneko and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {The Formation of a m3-h3-BC2 Ring via Intramolecular Borylene Transfer and Its Property}, booktitle = {}, year = 2013, } @inproceedings{CTT100661589, author = {Masahiro Nagaoka and HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {Heterometallic Clusters Composed of Ruthenium and Group 9 Metals}, booktitle = {}, year = 2013, } @inproceedings{CTT100653005, author = {Masahiro Nagaoka and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {9族金属とルテニウムから成る一連の異種金属クラスターの合成と性質}, booktitle = {}, year = 2013, } @inproceedings{CTT100649024, author = {TOSHIRO TAKAO and Takeshi Kaneko}, title = {三重架橋ボリレン錯体の光照射によるBC2三員環およびB=O結合の形成}, booktitle = {}, year = 2013, } @inproceedings{CTT100653008, author = {Takeshi Kaneko and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {光照射によるオキソボリル配位子を有する新規な三核ルテニウム錯体の合成}, booktitle = {}, year = 2013, } @inproceedings{CTT100653009, author = {Atsushi Tahara and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三核ルテニウム錯体を用いたベンゼンの活性化及び新規結合形成反応の開発}, booktitle = {}, year = 2013, } @inproceedings{CTT100649025, author = {Toshiro Takao}, title = {Boron–Carbon Bond Formation on a Flexible Triruthenium Skeleton}, booktitle = {}, year = 2012, } @inproceedings{CTT100649027, author = {Masahiro Nagaoka and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {ルテニウムとコバルトを含む異種金属三核ポリヒドリドクラスター}, booktitle = {}, year = 2012, } @inproceedings{CTT100649026, author = {Atsushi Tahara and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {INTERCONVERSION BETWEEN AN ALKYNE-HYDRIDO COMPLEX AND AN AGOSTIC-VINYL COMPLEX LEADING TO ACTIVATION OF BENZENE ON A TRIRUTHENIUM CLUSTER}, booktitle = {}, year = 2012, } @inproceedings{CTT100641433, author = {Atsushi Tahara and Toshiro Takao and Hiroharu Suzuki}, title = {Activation of C-H bond of benzene induced by triruthenium cluster containing a triply bridging ligand}, booktitle = {}, year = 2012, } @inproceedings{CTT100641435, author = {Masahiro Nagaoka and Toshiro Takao and Hiroharu Suzuki}, title = {Reactivity of a Heterometallic Trinuclear Polyhydrido Cluster Composed of Ruthenium and Cobalt with Alkynes}, booktitle = {}, year = 2012, } @inproceedings{CTT100641428, author = {TOSHIRO TAKAO}, title = {Synthesis of Triruthenium Complexes Containing a Triply-Bridging Pyridyl Ligand; Dehydrogenative Coupling of Pyridines on a Ru3 Plane}, booktitle = {}, year = 2011, } @inproceedings{CTT100627561, author = {Atsushi Tahara and Makoto Moriya and Toshiro Takao and Hiroharu Suzuki}, title = {Direct Arylation of a Cluster-Bound Alkyne LIgand with Benzene via an Interconversion of an Alkyne Ligand into a Vinyl Ligand}, booktitle = {}, year = 2011, } @inproceedings{CTT100627557, author = {Nyu Yan and Toshiro Takao and Hiroharu Suzuki}, title = {カチオン性イリジウムを含む異種金属錯体の反応性}, booktitle = {}, year = 2011, } @inproceedings{CTT100627558, author = {Masahiro Nagaoka and Toshiro Takao and Hiroharu Suzuki}, title = {ルテニウムとコバルトを含む種金属三核ポリヒドリドクラスターの合成および内部アルキンとの反応}, booktitle = {}, year = 2011, } @inproceedings{CTT100627563, author = {Atsushi Tahara and Toshiro Takao and Hiroharu Suzuki}, title = {Carbon Chain Rearrangement of Hydrocarbyl Ligands using Triruthenium Cluster}, booktitle = {}, year = 2011, } @inproceedings{CTT100627553, author = {Atsushi Tahara and Toshiro Takao and Hiroharu Suzuki}, title = {Interconversion of an myu3-(//)-alkyne ligand into a myu3-vinyl ligand on a triruthenium cluster}, booktitle = {}, year = 2011, } @inproceedings{CTT100627555, author = {Hitoshi Suwa and Rei Okamura and Toshiro Takao and Hiroharu Suzuki}, title = {Intramolecular B-C coupling reaction on a triruthenium complex with a myu3-borylene ligand}, booktitle = {}, year = 2011, } @inproceedings{CTT100610846, author = {Atsushi Tahara and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三核ルテニウム錯体上におけるアルキン配位子の不均化反応}, booktitle = {}, year = 2010, } @inproceedings{CTT100610847, author = {Sachio Asano and Takashi Kawashima and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三核ルテニウムポリヒドリド錯体上でのニトリルの配位様式の変化}, booktitle = {}, year = 2010, } @inproceedings{CTT100610852, author = {TOSHIRO TAKAO and Atsushi Tahara and Makoto Moriya and Mana Kajigaya and Akinobu Nagai and HIROHARU SUZUKI}, title = {C-C Bond Formation on a Trimetallic Cluster with Partial Breaking of a Cluster Skeleton}, booktitle = {}, year = 2010, } @inproceedings{CTT100610848, author = {Hideyuki Kanda and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三重架橋イミド-三重架橋アルキリジン錯体の合成と性質}, booktitle = {}, year = 2010, } @inproceedings{CTT100610849, author = {Atsushi Tahara and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三核ルテニウム錯体と直鎖不飽和炭化水素との反応-三核反応場における炭素鎖不均化反応の反応機構に関する考察}, booktitle = {}, year = 2010, } @inproceedings{CTT100610842, author = {TOSHIRO TAKAO}, title = {Control over the Reactivity of a Polyhydrido Cluster via Interaction wit Alcohol}, booktitle = {}, year = 2009, } @inproceedings{CTT100610845, author = {Nozomi Oobayashi and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {ルテニウムを含む二核架橋ホスフィド錯体の合成とその反応性}, booktitle = {}, year = 2009, } @inproceedings{CTT100610844, author = {Hideyuki Kanda and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Synthesis, Structure, and Property of Dirutheniu Azaruthenacyclopentadiene Complexes}, booktitle = {}, year = 2009, } @inproceedings{CTT100610843, author = {TOSHIRO TAKAO and Atsushi Tahara and Makoto Moriya and Mana Kajigaya and HIROHARU SUZUKI}, title = {C-C Bond Formation on a Triruthenium Complex Utilizing Flexibility of a Cluster Skelton}, booktitle = {}, year = 2009, } @inproceedings{CTT100582097, author = {Nozomi Oobayashi and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Synthesis of a Phosphido-Bridged Dinuclear Complex Containing Ruthenium and Rhodium and Cleavage of an aromatic C-H bond on the complex}, booktitle = {}, year = 2009, } @inproceedings{CTT100582096, author = {Atsushi Tahara and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Reconstruction of Alkyne Ligands with Trinuclear Ruthenium Cluster}, booktitle = {}, year = 2009, } @inproceedings{CTT100582101, author = {TOSHIRO TAKAO and Makoto Moriya and Atsushi Tahara and Mana Kajigaya}, title = {Arylation of a Hydrocarbyl Ligand on a Triruthenium Cluster via C-H Bond Activation of Benzene}, booktitle = {}, year = 2009, } @inproceedings{CTT100582098, author = {TOSHIRO TAKAO and HIROHARU SUZUKI and ZhenZhen Wu}, title = {Subtle Interaction between a Heterometallic Polyhydrido Cluster Containing Ruthenium and Iridium with Fluoroalcohol}, booktitle = {}, year = 2009, } @inproceedings{CTT100565505, author = {Shinsuke Mochizuki and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Ru4MおよびRu5M骨格を有する異種金属ヒドリド錯体の合成とその性質}, booktitle = {}, year = 2008, } @inproceedings{CTT100565501, author = {TOSHIRO TAKAO and Takashi Kawashima and Rei Okamura and HIROHARU SUZUKI}, title = {Various Coordination Modes of a Pyridine Molecule on a Triruthenium Cluster}, booktitle = {}, year = 2008, } @inproceedings{CTT100565503, author = {Nozomi Oobayashi and Takashi Kawashima and Hideyuki Kanda and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {二核ルテニウム架橋ホスフィド錯体上でのピリジン配位子の挙動}, booktitle = {}, year = 2008, } @inproceedings{CTT100565504, author = {Hideyuki Kanda and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {二核ルテニウムヒドリド錯体とイミン類との反応}, booktitle = {}, year = 2008, } @inproceedings{CTT100564204, author = {TOSHIRO TAKAO and Makoto Moriya and HIROHARU SUZUKI}, title = {Synthesis and reactivity of a m3-h3-C3 Ring on a dicationic triruthenium cluster}, booktitle = {}, year = 2008, } @inproceedings{CTT100564205, author = {TOSHIRO TAKAO}, title = {Dehydrogenative Coupling of Pyridines Catalyzed by Ruthenium Clusters}, booktitle = {}, year = 2008, } @inproceedings{CTT100561497, author = {Atsushi Tahara and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {三重架橋ルテナシクロペンタジエン骨格を有する新規三核錯体の合成と構造}, booktitle = {}, year = 2008, } @inproceedings{CTT100561496, author = {Shinsuke Mochizuki and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {Ru5M骨格を有する六核ポリヒドリドクラスターの合成と構造}, booktitle = {}, year = 2008, } @inproceedings{CTT100561494, author = {Hideyuki Kanda and Takashi Kawashima and TOSHIRO TAKAO and HIROHARU SUZUKI}, title = {ルテニウムポリヒドリドクラスターとイミン類との反応}, booktitle = {}, year = 2008, } @inproceedings{CTT100548552, author = {TOSHIRO TAKAO}, title = {二核ルテニウム錯体を用いたピリジン類の脱水素カップリング反応}, booktitle = {}, year = 2008, } @inproceedings{CTT100521529, author = {梶ヶ谷真奈 and 守谷誠 and 高尾俊郎 and 鈴木寛治}, title = {炭化水素骨格を持つフレキシブルな三核ルテニウムクラスター上における炭素-炭素結合形成反応}, booktitle = {}, year = 2006, } @inproceedings{CTT100521530, author = {高尾俊郎 and 鈴木智美 and 川島敬史 and 稲垣昭子 and 鈴木寛治}, title = {ヒドリドの炭化水素配位子上への移動を伴うクラスターの骨格変換反応}, booktitle = {}, year = 2006, } @inproceedings{CTT100521528, author = {Ryu-ichi Tenjimbayashi and Toshiro Takao and Hiroharu Suzuki}, title = {Skeletal Rearrangement of a Triruthenium μ3(⊥)-Alkyne Complex via the Formation of a μ3-Vinylidene Intermediate}, booktitle = {}, year = 2006, } @inproceedings{CTT100521027, author = {守谷誠 and 島隆則 and 高尾俊郎 and 鈴木寛治}, title = {ルテニウムとオスミウムからなる三核ポリヒドリドクラスターを用いたアルカンの活性化}, booktitle = {}, year = 2006, } @inproceedings{CTT100521030, author = {川島敬史 and 岡村玲 and 高尾俊郎 and 鈴木寛治}, title = {三核ルテニウムペンタヒドリド錯体 (Cp*Ru)33-H)2(μ-H)3とピリジンとの反応}, booktitle = {}, year = 2006, } @inproceedings{CTT100392994, author = {Ryu-ichi Tenjimbayashi and Toshiro Takao and Hiroharu Suzuki}, title = {Synthesis and Characterization of a Cataionic μ3-alkylidyne Complex; Elucidation of the Mechanism of the Alkane Activation on the Triruthenium Complex}, booktitle = {}, year = 2005, } @inproceedings{CTT100392981, author = {Toshiro Takao and Tomomi Suzuki and Hiroharu Suzuki}, title = {Control over the Reactivity of a Polyhydrido Cluster via Interaction with Alcohol}, booktitle = {}, year = 2005, } @inproceedings{CTT100392993, author = {梶ヶ谷真奈 and 守谷誠 and 高尾俊郎 and 鈴木寛治}, title = {三核ルテニウムクラスター上でのベンゼンの炭素-水素結合切断と炭素-炭素結合形成}, booktitle = {}, year = 2005, } @inproceedings{CTT100392982, author = {高尾俊郎 and 鈴木智美 and 秋吉一憲 and 鈴木寛治}, title = {アルコール分子との相互作用を用いたポリヒドリドクラスターの反応性の制御}, booktitle = {}, year = 2005, } @inproceedings{CTT100392985, author = {川島敬史 and 岡村玲 and 高尾俊郎 and 鈴木寛治}, title = {μ3222-ピリジン錯体の合成とその性質}, booktitle = {}, year = 2005, } @inproceedings{CTT100392990, author = {Makoto Moriya and Toshiro Takao and Takanori Shima and Yumi Osaku and Hiroharu Suzuki}, title = {Cleavage of C-H and C-C Bonds of n-Alkane on a Heterometallic Polyhydrido Cluster Containing Ruthenium and Rhodium or Iridium}, booktitle = {}, year = 2005, } @inproceedings{CTT100392991, author = {Ryu-ichi Tenjimbayashi and Toshiro Takao and Hiroharu Suzuki}, title = {Synthesis and Characterization of a Cataionic μ3-alkylidyne Complex; Elucidation of the Mechanism of the Alkane Activation on the Triruthenium Complex}, booktitle = {}, year = 2005, } @inproceedings{CTT100392992, author = {川島敬史 and 高尾俊郎 and 鈴木寛治}, title = {三核ルテニウム上でのニトリルの還元反応}, booktitle = {}, year = 2005, } @inproceedings{CTT100392989, author = {鈴木智美 and 高尾俊郎 and 鈴木寛治}, title = {アルコールとの相互作用を用いたポリヒドリドクラスターの反応性の制御}, booktitle = {}, year = 2005, } @inproceedings{CTT100392986, author = {川島敬史 and 高尾俊郎 and 鈴木寛治}, title = {三核ルテニウム錯体上での炭素-窒素結合の切断}, booktitle = {}, year = 2005, } @inproceedings{CTT100392987, author = {守谷誠 and 高尾俊郎 and 鈴木寛治}, title = {三核ルテニウム錯体によるベンゼンの炭素-水素結合活性化と炭素-炭素結合の形成}, booktitle = {}, year = 2005, } @inproceedings{CTT100392988, author = {天神林隆一 and 室谷英介 and 高尾俊郎 and 鈴木寛治}, title = {三核ルテニウム錯体上での炭素-炭素三重結合の段階的切断反応}, booktitle = {}, year = 2005, } @misc{CTT100594774, author = {TOSHIRO TAKAO}, title = {二核ルテニウム錯体による有機ケイ素化合物の活性化}, year = 1995, } @misc{CTT100573382, author = {HIROHARU SUZUKI and TOSHIRO TAKAO}, title = {2,2’-ビピリジン類の製造方法}, howpublished = {PublishedPatent}, year = 2008, month = {}, note = {特願2006-317936(2006/11/27), 特開2008-074825(2008/04/03)} } @phdthesis{CTT100594774, author = {TOSHIRO TAKAO}, title = {二核ルテニウム錯体による有機ケイ素化合物の活性化}, school = { Tokyo Institute of Technology}, year = 1995, }