@book{CTT100629949, author = {占部 弘和 and 秦 猛志}, title = {芳香族化合物−医薬品化学への展開}, publisher = {}, year = 2011, } @book{CTT100629947, author = {占部弘和 and 秦 猛志}, title = {医薬・生体機能分子の未来指向型合成法の開発}, publisher = {工学図書株式会社}, year = 2009, } @book{CTT100560578, author = {占部弘和}, title = {バイオ系のための基礎化学問題集}, publisher = {}, year = 2008, } @book{CTT100470413, author = {F. Sato and H. Urabe}, title = {Titanium(II) Alkoxide in Organic Synthesis}, publisher = {Titanium and Zirconium in Organic Synthesis (分担)Wiley-VCH}, year = 2002, } @book{CTT100470414, author = {HIROKAZU URABE}, title = {New Synthetic Reactions Mediated by Organometallic Compounds}, publisher = {My Favorite Organic Synthesis 化学同人}, year = 2002, } @book{CTT100426424, author = {Hirokazu Urabe and Fumie Sato}, title = {Achiral Titanium (IV) Lewis Acids}, publisher = {Lewis Acids in Organic Synthesis (分担) Wiley-VCH}, year = 2000, } @book{CTT100426428, author = {HIROKAZU URABE}, title = {Hydromagnesiation of Alkenes and Alkynes}, publisher = {Grignard Reagents - New Developments(分担) Wiley}, year = 1999, } @book{CTT100411925, author = {HIROKAZU URABE}, title = {Preparation of Grignard Reagents from Olefins and Acetylenes}, publisher = {Handbook of Grignard Reagents (分担) Marcel Dekker Inc}, year = 1996, } @book{CTT100411926, author = {HIROKAZU URABE}, title = {Metal-catalyzed Reactions}, publisher = {Handbook of Grignard Reagents;Marcel Dekker,Inc}, year = 1996, } @article{CTT100915542, author = {Azusa Ishii and Takeshi Hata and Masayuki Shigeta and Hirokazu Urabe}, title = {Nucleophilic Addition of Amides to Haloalkynes: Synthesis of (Z)-β-Halovinylamides as Dual Precursors of Allyl Halides and Alkylidene Carbenes}, journal = {Organic Letters}, year = 2024, } @article{CTT100915544, author = {Takeshi Hata and Yuta Tatsumi and Yuki Kanai and Naoto Takahashi and Masayuki Shigeta and Hirokazu Urabe}, title = {Preparation of Hetero-π-conjugated Compounds via Double Nucleophilic Addition to Haloalkynes and C-H Activation}, journal = {Advanced Synthesis & Catalysis}, year = 2024, } @article{CTT100911207, author = {Kento Miyanaka and Tomona Harada and Masayuki Shigeta and Takeshi Hata and Hirokazu Urabe}, title = {Iron-catalyzed Regio- and Stereoselective Substitution of 2,4-Alkadienyl Carboxylates with Aryl Grignard Reagents}, journal = {Tetrahedron Letters}, year = 2023, } @article{CTT100793257, author = {Takeshi Hata and Yoshiki Hayashi and Yuki Hasegawa and Masaaki Iwai and Ayumi Ishii and Miki Hasegawa and Masayuki Shigeta and Hirokazu Urabe}, title = {Preparation of Tetrazole-fused π-Conjugated Molecules and Their Fluorescence Behavior}, journal = {Chemistry Letters}, year = 2019, } @article{CTT100785673, author = {Ayana Furukawa and Takeshi Hata and Masayuki Shigeta and Hirokazu Urabe}, title = {Rh-catalyzed Intramolecular Cyclization of 1-Sulfonyl-1,2,3- triazole and Sulfinate. Concise Preparation of Sulfonylated Unsaturated Piperidines}, journal = {Tetrahedron Letters}, year = 2019, } @article{CTT100783615, author = {Goshi Sugano and Kojiro Kawada and MASAYUKI SHIGETA and Takeshi Hata and HIROKAZU URABE}, title = {Iron-catalyzed δ-Selective Conjugate Addition of Methyl and Cyclopropyl Grignard Reagents to α,β,γ,δ-Unsaturated Esters and Amides}, journal = {Tetrahedron Letters}, year = 2019, } @article{CTT100701874, author = {Masato Senoo and Ayana Furukawa and Takeshi Hata and Hirokazu Urabe}, title = {Rh-catalyzed Intramolecular C–H Bond Activation with Triazoles. Preparation of Stereo-defined Pyrrolidines and Other Related Cyclic Compounds}, journal = {Chemistry - A European Journal}, year = 2016, } @article{CTT100681338, author = {Masahito Yamagishi and Azusa Ishii and Takeshi Hata and Hirokazu Urabe}, title = {Facile Preparation of 1,2-Dihydroisoquinolines from N-Benzylsulfonamides and Bromoacetylenes}, journal = {Heterocycles (Current Special Issue: Isao Kuwajima's Special Issues)}, year = 2015, } @article{CTT100681337, author = {Tomoya Mizumori and Takeshi Hata and Hirokazu Urabe}, title = {Alkylation of Pyridines at Their 4-Position with Stylenes plus an Yttrium Reagent or Benzyl Grignard Reagents}, journal = {Chemistry - A European Journal}, year = 2015, } @article{CTT100677101, author = {Takeshi Hata and Hideyuki Gotoh and Tomofumi Yokomizo and Hirokazu Urabe}, title = {Iron-catalyzed 1,6-Selective Addition of Aryl Grignard Reagent to 2,4-Alkadienoates: t-Butyl (Z)-5-Phenyl-3-hexenoate}, journal = {Organic Syntheses}, year = 2014, } @article{CTT100666132, author = {Hirohiko Murase and Kousuke Senda and Masato Senoo and Takeshi Hata and Hirokazu Urabe}, title = {Rhodium-Catalyzed Intramolecular Hydroarylation of 1-Halo-1- alkynes: Regioselective Synthesis of Semihydrogenated Aromatic Heterocycles}, journal = {Chemistry - A European Journal}, year = 2014, } @article{CTT100661762, author = {Satoshi Iwata and Masato Senoo and Takeshi Hata and Hirokazu Urabe}, title = {Preparation of S-Aryl Arenethiosulfonates from N,N-Di(arenesulfonyl)hydrazines. Reduction of Sulfonyl Chlorides with an Organic Reagent}, journal = {Heteroatom Chemistry}, year = 2013, } @article{CTT100657712, author = {Takeshi Hata and Takuya Nakada and Yun Taek Oh and Naoki Hirone and Hirokazu Urabe}, title = {Iron-Catalyzed Regio- and Stereoselective Conjugate Addition of Aryl-Grignard Reagents to α,β,γ,δ-Unsaturated Sulfones and its Synthetic Application}, journal = {Advanced Synthesis & Catalysis}, year = 2013, } @article{CTT100646656, author = {Satoshi Iwata and Takeshi Hata and HIROKAZU URABE}, title = {Synthesis of tert-Butyl Peroxyacetals from Benzyl, Allyl, or Propargyl Ethers via Iron-Promoted C-H Bond Functionalization}, journal = {Advanced Synthesis & Catalysis}, year = 2012, } @article{CTT100640124, author = {Takeshi Hata and Satoshi Iwata and Shumpei Seto and Hirokazu Urabe}, title = {Iron-Catalyzed Synthesis of Allenes from 2-Alken-4-ynoates and Grignard Reagents}, journal = {Advanced Synthesis & Catalysis}, year = 2012, } @article{CTT100639459, author = {Masahito Yamagishi and Ken Nishigai and Azusa Ishii and Takeshi Hata and Hirokazu Urabe}, title = {Facile Preparation of Indoles and 1,2-Benzothiazine 1,1-Dioxides: Nucleophilic Addition of Sulfonamides to Bromoacetylenes and Subsequent Palladium-Catalyzed Cyclization}, journal = {Angewandte Chemie International Edition}, year = 2012, } @article{CTT100639012, author = {Takeshi Hata and Haduki Imade and HIROKAZU URABE}, title = {Four Nucleophilic Additions to Alkenynedioic Acid Derivatives in Tandem; Efficient One-Pot Synthesis of Bicyclo[4.2.0]octenols}, journal = {Organic Letters}, year = 2012, } @article{CTT100633861, author = {Masahito Yamagishi and Jun Okazaki and Ken Nishigai and Takeshi Hata and Hirokazu Urabe}, title = {Additive-Free Nucleophilic Addition of Imidazolines and Imidazoles to Haloacetylenes}, journal = {Organic Letters}, year = 2012, } @article{CTT100633860, author = {Takeshi Hata and Shiro Sujaku and Naoki Hirone and Kirihiro Nakano and Junsuke Imoto and Haduki Imade and Hirokazu Urabe}, title = {Iron-Mediated and -Catalyzed Metalative Cyclization of Electron- Withdrawing-Group-Substituted Alkynes and Alkenes with Grignard Reagents}, journal = {Chemistry - A European Journal}, year = 2011, } @article{CTT100629946, author = {Masahito Yamagishi and Ken Nishigai and Takeshi Hata and Hirokazu Urabe}, title = {Nucleophilic Addition of Sulfonamides to Bromoacetylenes: Facile Preparation of Pyrroles}, journal = {Organic Letters}, year = 2011, } @article{CTT100629944, author = {Oh Yun Taek and Kosuke Senda and Takeshi Hata and Hirokazu Urabe}, title = {Rh-catalyzed Intramolecular Debenzylative Cyclization of Amines. Butyrolactams from Benzylamines Having a Chloroacetylene Moiety}, journal = {Tetrahedron Letters}, year = 2011, } @article{CTT100613483, author = {Naoki Hirone and Ryoichi Tanaka and Hiroaki Sanjiki and Takeshi Hata and Hirokazu Urabe}, title = {Acceleration of the Substitution of Silanes with Grignard Reagents by Using either LiCl or YCl3/MeLi}, journal = {Angewandte Chemie International Edition}, year = 2010, } @article{CTT100613482, author = {Yuzo Kato and Dinh Hoang Yen and Yasuhiro Fukudome and Takeshi Hata and Hirokazu Urabe}, title = {Aryl(sulfonyl)amino Group: A Convenient and Stable yet Activated Modification of Amino Group for Its Intramolecular Displacement}, journal = {Organic Letters}, year = 2010, } @article{CTT100601023, author = {Takeshi Hata and Rie Bannai and Mamoru Otsuki and Hirokazu Urabe}, title = {Iron-Catalyzed Regio- and Stereoselective Substitution of γ,δ-Epoxy-α,β-unsaturated Esters and Amides with Grignard Reagents}, journal = {Organic Letters}, year = 2010, } @article{CTT100601024, author = {Hiroyuki Naito and Takeshi Hata and Hirokazu Urabe}, title = {Selective Deprotection of Methanesulfonamides to Amines}, journal = {Organic Letters}, year = 2010, } @article{CTT100601022, author = {Daisuke Shikanai and Hirohiko Murase and Takeshi Hata and Hirokazu Urabe}, title = {Rh-Catalyzed Isomerization and Intramolecular Redox Reaction of Alkynyl Ethers Affording Dihydropyrans and Ketoolefins}, journal = {Journal of the American Chemical Society}, year = 2009, } @article{CTT100567179, author = {Takeshi Hata and Naoki Hirone and Shiro Sujyaku and Kirihiro Nakano and Hirokazu Urabe}, title = {Iron-Mediated Intramolecular Metallative Cyclization of α,β-Unsaturated Esters and Amides. Versatile One-Pot Preparation of Bicyclic Ketoesters}, journal = {Organic Letters}, year = 2008, } @article{CTT100560644, author = {Satoshi Okada and Ryuji Murayama and Takumi Ishizuka and Keiichi Hara and Naoki Hirone and Takeshi Hata and Hirokazu Urabe}, title = {Iron Catalyst-Switched Selective Conjugate Addition of Grignard Reagents. α,β,γ,δ-Unsaturated Amides as Versatile Templates for Asymmetric Three-Component Coupling Process}, journal = {Angewandte Chemie International Edition}, year = 2008, } @article{CTT100554891, author = {Hiroyuki Naito and Takeshi Hata and Hirokazu Urabe}, title = {Facile Preparation of N-Protected 2-Alkylidene-1,3-imidazolidines}, journal = {Tetrahedron Letters}, year = 2008, } @article{CTT100554890, author = {Yasuhiro Fukudome and Hiroyuki Naito and Takeshi Hata and Hirokazu Urabe}, title = {Copper-Catalyzed 1,2-Double Amination of 1-Halo-alkynes. Concise Synthesis of Protected Tetrahydropyrazines and Related Heterocyclic Compounds}, journal = {Journal of the American Chemical Society}, year = 2008, } @article{CTT100560549, author = {R. Tanaka and H. Sanjiki and H. Urabe}, title = {Yttrium-Mediated Conversion of Vinyl Grignard Reagent to a 1,2-Dimetalated Ethane and Its Synthetic Application,}, journal = {J. Am. Chem. Soc.}, year = 2008, } @article{CTT100560539, author = {H. Urabe and D. Shikanai and K. Arayama and T. Sato and R. Tanaka}, title = {Electrophile-triggered Assembly of Metal Enamides and Allyl Grignard Reagent in One Pot. Novel Nucleophilic Double Allylation of Azadienes,}, journal = {Chem. Lett.}, year = 2007, } @article{CTT100560537, author = {S. Hirano, Y. Fukudome, R. Tanaka, F. Sato, H. Urabe}, title = {Practical Preparation of N-(1-Alkynyl)sulfonamides and Their Synthetic Utility in Titanium Alkoxide-Mediated Coupling Reactions}, journal = {Tetrahedron (Symposium-in-Print)}, year = 2006, } @article{CTT100397999, author = {K. Fukuhara and H. Urabe}, title = {Iron-Catalyzed 1,6-Addition of Aryl Grignard Reagents to 2,4-Dienoates and -Dienamides}, journal = {Tetrahedron Lett.}, year = 2005, } @article{CTT100560534, author = {Y. Nobe, K. Arayama, H. Urabe}, title = {Air-Assisted Addition of Grignard Reagents to Olefins. A Simple Protocol for Three-Component Coupling Process Yielding Alcohols}, journal = {J. Am. Chem. Soc.}, year = 2005, } @article{CTT100398003, author = {D. Suzuki and Y. Nobe and Y. Watai and R. Tanaka and Y. Takayama and F. Sato and H. Urabe}, title = {Facile Preparation of Various Heteroaromatic Compounds via Azatitanacyclopentadiene Intermediates}, journal = {J. Am. Chem. Soc.}, year = 2005, } @article{CTT100397996, author = {R. Tanaka and M. Sasaki and F. Sato and H. Urabe}, title = {A Novel Propargyltitanation of Acetylenes. Heteroatom Substituent-Dependent Manifold in Intermolecular Coupling of Allene and Acetylene}, journal = {Tetrahedron Lett.}, year = 2005, } @article{CTT100398006, author = {R. Tanaka and A. Yuza and Y. Watai and D. Suzuki and Y. Takayama and F. Sato and H. Urabe}, title = {One-Pot Synthesis of Metalated Pyridines from Two Acetylenes, a Nitrile, and a Titanium(II) Alkoxide}, journal = {J. Am. Chem. Soc.}, year = 2005, } @article{CTT100382986, author = {S. Hirano and R. Tanaka and H. Urabe and F. Sato}, title = {Practical Preparation of N-(1-Alkynyl)sulfonamides and Their Remote Diastereoselective Addition to Aldehydes via Titanation}, journal = {Org. Lett.}, year = 2004, } @article{CTT100382985, author = {K. Mitsui and T. Sato and H. Urabe and F. Sato}, title = {Stereoselective Construction of Acyclic Carbon Chains via One-pot Coupling Process Based on Alkenyloxazoline-Titanium Complexes}, journal = {Angew. Chem. Int. Ed.}, year = 2004, } @article{CTT100487061, author = {H. Urabe and D. Suzuki and F. Sato}, title = {Generation of an Acetylene-titanium Alkoxide Complex. Preparation of (Z)-1,2-Dideuterio-1-(trimethylsilyl)-1-hexene }, journal = {Org. Synth.}, year = 2003, } @article{CTT100487062, author = {R. Tanaka and S. Hirano and H. Urabe and F. Sato}, title = {Concise and Stereoselective Synthesis of Enamides and Dienamides by Titanium-Mediated Coupling Method}, journal = {Org. Lett.}, year = 2003, } @article{CTT100547016, author = {H. Urabe and D. Suzuki and M. Sasaki and F. Sato}, title = {Enol Ester as an Olefinic Partner in Enyne Cyclization. A Novel Tandem Cyclization to Stereo-defined Bicyclo[3.3.0]octenes}, journal = {J. Am. Chem. Soc.}, year = 2003, } @article{CTT100487055, author = {H. Urabe and K. Mitsui and S. Ohta and F. Sato}, title = {Titanium Alkoxide Complex of Functionalized Conjugated Dienes. A Versatile Bis-anionic Template for Stereoselective Construction of Carbon Frameworks}, journal = {J. Am. Chem. Soc}, year = 2003, } @article{CTT100470412, author = {R. Nakajima and H. Urabe and F. Sato}, title = {Intramolecular Coupling of Vinyl Ether and Olefins or Acetylenes with Ti(II) Reagent. Regio- and Stereoselective Vinyltitanation of Carbon-Carbon Multiple Bonds}, journal = {Chem. Lett.}, year = 2002, } @article{CTT100470411, author = {H. Urabe and K. Kusaka and D. Suzuki and F. Sato}, title = {Chiral 1,3-Butadiene-2-carboxylates for an Efficient Asymmetric Diels-Alder Reaction}, journal = {Tetrahedron Lett.}, year = 2002, } @article{CTT100470410, author = {C. Delas and H. Urabe and F. Sato}, title = {Site-selective Mono-titanation of Conjugated Diynes with a Ti(II) Alkoxide Reagent. Concise Preparation of Stereo-Defined Enynes and Dienynes}, journal = {Chem. Commun.}, year = 2002, } @article{CTT100470409, author = {C. Delas and H. Urabe and F. Sato}, title = {Stereoselective One-pot Preparation of 1,2,4,5-Tetraalkylidene- and 1,4-Dialkylidenecyclohexanes}, journal = {Chem. Commun.}, year = 2002, } @article{CTT100470408, author = {D. Suzuki and R. Tanaka and H. Urabe and F. Sato}, title = {Selective Syntheses of Metalated Pyridines from Two Different Unsymmetrical Acetylenes, a Nitrile, and a Titanium(II) Alkoxide}, journal = {J. Am. Chem. Soc.}, year = 2002, } @article{CTT100470407, author = {M. Narita and H. Urabe and F. Sato}, title = {Sulfur-Functionalized Olefins for Titanacycle Formation: Tandem Asymmetric Cyclization and the Pummerer Reaction Based on Sulfoxides Promoted by Titanium(II)-to-Titanium(IV) Relay}, journal = {Angew. Chem. Int. Ed.}, year = 2002, } @article{CTT100470406, author = {R. Tanaka and Y. Nakano and D. Suzuki and H. Urabe and F. Sato}, title = {Selective Preparation of Benzyltitanium Compounds by the Metalative Reppe Reaction. Its Application to the First Synthesis of Alcyopterosin A}, journal = {J. Am. Chem. Soc.}, year = 2002, } @article{CTT100457640, author = {Christophe Delas and Hirokazu Urabe and Fumie Sato}, title = {Titanium-Mediated Intramolecular Cyclization of Tethered Propargyl Alcohol Derivatives. Access to Exocyclic Bis-Allenes and Cyclobutene Derivatives}, journal = {Tetrahedron Lett.}, year = 2001, } @article{CTT100457639, author = {Daisuke Suzuki and Hirokazu Urabe and Fumie Sato}, title = {Metalative Reppe Reaction. Organized Assembly of Acetylene Molecules on Titanium Template Leading to a New Style of Acetylene Cyclotrimerization}, journal = {Journal of the American Chemical Society}, year = 2001, } @article{CTT100457641, author = {占部弘和}, title = {チタナサイクルによる有機合成の新しい幕開け}, journal = {有機合成化学協会誌}, year = 2001, } @article{CTT100457638, author = {Christophe Delas and Hirokazu Urabe and Fumie Sato}, title = {Remarkably Facile, Unidirectional Isomerization of Titanated Vinylallenes to Cyclobutenyltitanium Compounds. A Practical Construction of a Cyclobutene Framework}, journal = {Journal of the American Chemical Society}, year = 2001, } @article{CTT100460300, author = {占部弘和}, title = {有機合成を指向するチタナサイクルの開発と利用ー最近の動向ー}, journal = {化学工業}, year = 2001, } @article{CTT100438632, author = {Ryo Mizojiri and Hirokazu Urabe and Fumie Sato}, title = {Generation of a Silylethylene-Titanium Alkoxide Complex. A Versatile Reagent for Silylethylation and Silylethylidenation of Unsaturated Compounds}, journal = {The Journal of Organic Chemistry}, year = 2000, } @article{CTT100438631, author = {Hirokazu Urabe and Ryota Nakajima and Fumie Sato}, title = {A Facile Preparation of exo-Cyclic Conjugated Dienes Fused to Lactams or Lactones via Intramolecular Coupling of Acetylenes and Their Behavior in Diels-Alder Reactions}, journal = {Organic Letters}, year = 2000, } @article{CTT100426425, author = {Fumie Sato and Hirokazu Urabe and Sentaro Okamoto}, title = {Synthetic Reactions Mediated by a Ti(O-i-Pr)4 / 2 i-PrMgX Reagent}, journal = {Synlett}, year = 2000, } @article{CTT100438637, author = {Fumie Sato and Hirokazu Urabe and Sentaro Okamoto}, title = {Synthesis of Organotitanium Complexes from Alkenes and Alkynes, and Their Synthetic Application}, journal = {Chemical Reviews}, year = 2000, } @article{CTT100438636, author = {占部弘和}, title = {有機合成における華やかな金属試薬-チタン}, journal = {ファルマシア}, year = 2000, } @article{CTT100438635, author = {Hirokazu Urabe and Daigaku Hideura and Fumie Sato}, title = {Asymmetric Synthesis of Bicyclic Ketones Having an Angular Substituent via Ti(II) Alkoxide-Mediated Tandem Cyclization of Tri-substituted Olefinic Substrates}, journal = {Organic Letters}, year = 2000, } @article{CTT100438634, author = {Takashi Hamada and Ryo Mizojiri and Hirokazu Urabe and Fumie Sato}, title = {Expedient Construction of Multiple Stereogenic Centers in an Acyclic System via the Addition of Aldehydes, Ketones, and Chiral Imines to an Enyne-Titanium Alkoxide Complex}, journal = {Journal of the American Chemical Society}, year = 2000, } @article{CTT100438633, author = {Daisuke Suzuki and Hirokazu Urabe and Fumie Sato}, title = {Asymmetric Synthesis of Baylis-Hillman-Type Allyl Alcohols via a Chiral Acetylenic Ester-Titanium Alkoxide Complex}, journal = {Angewandte Chemie, International Edition}, year = 2000, } @article{CTT100426430, author = {HIROKAZU URABE}, title = {One-Pot, yet Two-Step, Hydrotitanation of 1-Silyl- or 1-Stannyl-1-alkynes, Showing the Opposite Regioselectivity to the Routine Hydrometalations}, journal = {Journal of the American Chemical Society}, year = 1999, } @article{CTT100426429, author = {HIROKAZU URABE}, title = {Titanium Alkoxide-Based Method for Stereoselective Synthesis of Functionalized Conjugated Dienes}, journal = {Journal of the American Chemical Society}, year = 1999, } @article{CTT100426427, author = {占部弘和}, title = {オレフィン・アセチレン類と(h2-propene)Ti(O-i-Pr)2によるジアルコキシチタナサイクルの発生と新規合成反応}, journal = {有機合成化学協会誌}, year = 1999, } @article{CTT100426423, author = {HIROKAZU URABE}, title = {A Titanacycle-to-Carbocycle Relay Leading to an Expedient Synthesis of Cyclopentadienols}, journal = {Angewandte Chemie, International Edition}, year = 1999, } @article{CTT100426432, author = {HIROKAZU URABE}, title = {Aldehyde Addition and Copper-Mediated Allylation of Bicyclic Alkoxytitanacyclopentenes and -pentadienes: New Selectivities and an Unusual Reaction}, journal = {Journal of the American Chemical Society}, year = 1999, } @article{CTT100426431, author = {HIROKAZU URABE}, title = {New Synthesis of Silylcyclopropanols via Titanium(II)-Mediated Coupling of Vinylsilanes and Esters}, journal = {Tetrahedron Letters}, year = 1999, } @article{CTT100411934, author = {HIROKAZU URABE}, title = {Novel[1, N]-Carbon to Carbon Rearrangement of an Ester Group via Organotitanium Intermedates Wherein the N Varies from 2 to 5. Full Scope and Limitation Leading Predominantly to the Rearrangement}, journal = {Bulletin of the Chemical Society of Japan}, year = 1998, } @article{CTT100411938, author = {HIROKAZU URABE}, title = {Highly Enantio-and Diastereoselective Synthesis of 2-Substituted 1-Bicyclo[3.1.0]hexanols from Oppolzer's N-Acylcamphorsultams and (η┣D12┫D1-Propene)Ti(O-i-Pr)┣D22┫D2}, journal = {Angewandte Chemie, International Edition in English}, year = 1998, } @article{CTT100411937, author = {HIROKAZU URABE}, title = {(η┣D12┫D1-Propene)Ti(O-i-Pr)┣D22┫D2-Mediated Cyclization of Allenynol Derivatives Which Leads to a Stereoselective Preparation of Cyclic Cross-Conjugated Trienes(共著)}, journal = {Tetrahedron Letters}, year = 1998, } @article{CTT100411936, author = {HIROKAZU URABE}, title = {Stereocontrolled Cyclization of Enynols and Allenynols with (η┣D12┫D1-Propene)Ti(O-i-Pr)┣D22┫D2. Important Role of Unprotected Hydroxy Group at a Remote Position}, journal = {Tetrahedron Letters}, year = 1998, } @article{CTT100411935, author = {占部弘和}, title = {2価チタン錯体を用いる合成反応}, journal = {有機合成化学協会誌}, year = 1998, } @article{CTT100411933, author = {HIROKAZU URABE}, title = {Coupling Reaction of Terminal Allenes with Themselves or Acetylenes Mediated by (η┣D12┫D1-Propene)Ti(OPr┣D1i┫D1)┣D22┫D2 : Some New Selectivities and Synthetic Application}, journal = {Chemical Communications}, year = 1998, } @article{CTT100411930, author = {HIROKAZU URABE}, title = {Diastereoselective Addition of(η┣D12┫D1-Alkyne)Ti(O-i-Pr)┣D22┫D2Complexes to 2,3-O-Isopropylidene-glyceraldehyde}, journal = {Tetrahedron Letters}, year = 1997, } @article{CTT100411932, author = {HIROKAZU URABE}, title = {Ti(II)-Mediated Allenyne Cyclization as a New Tool for Generation of Chiral Organotitanium Compounds. Asymmetric Generation of Cyclic Allyltitanium Reagents with No Chiral Auxiliary}, journal = {Journal of the American Chemical Society}, year = 1997, } @article{CTT100411931, author = {HIROKAZU URABE}, title = {Intramolecular Cyclization of 2,7-or 2,8-Bis-Unsaturated Esters Mediated by (η┣D12┫D1-Propene)Ti(O-i-Pr)┣D22┫D2. Facile Construction of Mono-and Bicyclic Skeletons with Stereoselective Introduction of a Side Chain. A Synthesis of d-Sabinene}, journal = {Journal of the American Chemical Society}, year = 1997, } @article{CTT100411927, author = {HIROKAZU URABE}, title = {Intramolecular Cyclization of Conjugated Diene and Acetylene with(η┣D12┫D1-Propene)Ti(O-i-Pr)┣D22┫D2. Generation and Reaction of Titanabicycles Having an Allyltitanium Moiety}, journal = {Tetrahedron Letters}, year = 1996, } @article{CTT100411928, author = {HIROKAZU URABE}, title = {Selective Reaction of Aldehydes with Bicyclic Titanacyclopentadienes or Titanacyclopentenes Prepared in situ from 1,6-or1,7-Diynes or Enynes and(η┣D12┫D1-Propene)Ti(O-i-Pr)┣D22┫D2}, journal = {The Journal of Organic Chemistry}, year = 1996, } @article{CTT100411929, author = {HIROKAZU URABE}, title = {A Novel Tandem Cyclization of 2,7-or2,8-Bis-Unsaturated Esters Mediated by(η┣D12┫D1-Propene)TiX┣D22┫D2(X=Cl or O-i-Pr). A Facile Construction of Bicyclo[3.3.0]octane, -[4.3.0]nonane, and-[3.1.0]hexane Skeletons}, journal = {Journal of the American Chemical Society}, year = 1996, } @article{CTT100411924, author = {HIROKAZU URABE}, title = {Intramolecular Cyclization of Conjugated Dienl and Acetylene with (η┣D12┫D1-Propene)Ti(O-i-Pr)┣D22┫D2.Generation and Reaction of Titanabicycles Having an Allytitanium Moiety(共著)}, journal = {Tetrahedron Letters}, year = 1996, } @article{CTT100411918, author = {HIROKAZU URABE}, title = {Lewis Acid-Enhanced Reactivity of α, β-Unsaturated Ester and Amide towards Radical Addition}, journal = {The Journal of Organic Chemistry}, year = 1995, } @article{CTT100411916, author = {HIROKAZU URABE}, title = {Stereo-and Regio-selective Generation of Alkenylzinc Reagents via Titanium-Catalyzed Hydrozincation of Acetylenes}, journal = {The Journal of Organic Chemistry}, year = 1995, } @article{CTT100411922, author = {HIROKAZU URABE}, title = {Generation and Reactions of Low-Valent Titanium Alkoxide-Acetylene Complex. A Practical Preparation of Allyl Alcohol}, journal = {Tetrahedron Letters}, year = 1995, } @article{CTT100411919, author = {HIROKAZU URABE}, title = {Generation of Chiral (η┣D15┫D1-Indenyl)┣D22┫D2 (η┣D13┫D1-allyl) Ti Complex and Its Highly Regio-, Diastereo-, and Enanitoselective Reaction with Carbonyl Compounds}, journal = {Tetrahedron Letters}, year = 1995, } @article{CTT100411917, author = {HIROKAZU URABE}, title = {Chelation-Controlled Addition of Dialkylzincs to┣DBtrans(/)-┫DB-α, β-Epoxy Aldehydes}, journal = {The Journal of Organic Chemistry}, year = 1995, } @article{CTT100411921, author = {HIROKAZU URABE}, title = {Synthetic Application of Titanabicycles generated from 1,6- or 1,7-Dienes, Enynes, and Diynes and (η┣D12┫D1-Propene) Ti (O-┣DBi(/)-┫DB-Pr)┣D22┫D2}, journal = {Tetrahedron Letters}, year = 1995, } @article{CTT100411920, author = {HIROKAZU URABE}, title = {Reagent-Controlled Stereoselection in Radical Addition to α-Methylenebutyrolactones}, journal = {Journal of the Chemical Society, Chemical Communications}, year = 1995, } @article{CTT100411923, author = {HIROKAZU URABE}, title = {First Practical Hydrozincation of Dienes Catalyzed by Cp┣D22┫D2TiCl┣D22┫D2. Generation of Allylzinc Reagent and Its Reaction with Carbonyl Compounds}, journal = {The Journal of Organic Chemistry}, year = 1994, } @article{CTT100411912, author = {HIROKAZU URABE}, title = {Carbon Dioxide Fixation by Cp┣D22┫D2(η┣D13┫D1-allyl)Ti Complexes Generated from Various Dienes}, journal = {Inorganica Chimica Acta}, year = 1994, } @article{CTT100411914, author = {HIROKAZU URABE}, title = {Regio-and Stereo-controlled Methylation of γ-Silyl Phosphates by π-Allylpalladium Methodology}, journal = {Journal of the Chemical Society, Chemical Communicatons.}, year = 1993, } @article{CTT100411915, author = {占部弘和}, title = {α.βエポキシ基により制御されたカルボニル化合物及びイミン類への求核試剤のジアステレオ選択的付加反応とその応用}, journal = {有機合成化学協会誌}, year = 1993, } @article{CTT100411913, author = {HIROKAZU URABE}, title = {A Regiochemical Control in the π-Allylalladium Substitution. Preparation of Optically Activeγ-Silyl allylamines}, journal = {Tetrahedron Letters}, year = 1993, } @inproceedings{CTT100911219, author = {田中啓翔 and 富田大貴 and 占部弘和 and 秦 猛志}, title = {テトラゾールの位置選択的アリール化とデグラデーション反応を利用するアゾ化合物の合成}, booktitle = {}, year = 2023, } @inproceedings{CTT100911216, author = {西 晃希 and 後藤大輝 and 辰巳湧太 and 重田雅之 and 占部弘和 and 秦 猛志}, title = {鉄触媒存在下ニトロ化合物と有機金属反応剤の還元的カップリング反応による第2級アミン合成}, booktitle = {}, year = 2023, } @inproceedings{CTT100911212, author = {後藤大輝 and 西 晃希 and 秦 猛志 and 占部弘和}, title = {鉄触媒存在下ニトロ化合物と有機亜鉛試薬の還元的カップリング反応による第二級アミン合成}, booktitle = {}, year = 2023, } @inproceedings{CTT100911211, author = {森地俊平 and 秦 猛志 and 占部弘和}, title = {鉄触媒による脂肪族グリニャール試薬のα,β,γ,δ-不飽和ホスフィンオキシドへの選択的付加反応の開発と利用}, booktitle = {}, year = 2022, } @inproceedings{CTT100911210, author = {飯坂拓也 and 秦 猛志 and 占部弘和}, title = {鉄触媒による脂肪族グリニャール試薬のα,β,γ,δ-不飽和スルホンへの位置かつ立体選択的付加反応}, booktitle = {}, year = 2022, } @inproceedings{CTT100868660, author = {小林一貴 and 笠倉望路 and 秦 猛志 and 重田雅之 and 占部弘和}, title = {1-(ω-アジドアルキル)-2-(2,2-ジハロビニル)アレーンを用いる多環性トリアゾール誘導体の合成}, booktitle = {}, year = 2022, } @inproceedings{CTT100868659, author = {中村南美 and 秦 猛志 and 重田雅之 and 占部弘和}, title = {ポリハロ(アリール)アレーンをテンプレートとする縮環芳香族化合物の合成}, booktitle = {}, year = 2022, } @inproceedings{CTT100868658, author = {富田大貴 and 伊藤 翔 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {銅触媒アリール化によるテトラゾールの位置選択的な四級化反応とその利用}, booktitle = {}, year = 2021, } @inproceedings{CTT100857403, author = {菖蒲池 魁士郎 and 嵯峨 康平 and 後藤 大輝 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {2位に四級炭素あるいはアルケニル側鎖をもつ5-アルキルテトラゾールの合成}, booktitle = {}, year = 2021, } @inproceedings{CTT100820038, author = {秦 猛志 and 小野田 聡志 and 重田雅之 and 占部弘和}, title = {塩化マンガン共存下ニトロ化合物と有機亜鉛試薬による官能性N,N-ジ置換ヒドロキシルアミン合成}, booktitle = {}, year = 2020, } @inproceedings{CTT100820041, author = {緒方 嵩隼 and 宮仲 健人 and 重田 雅之 and 秦 猛志 and 占部 弘和}, title = {Fe触媒とアリールグリニャール試薬による2,4-アルカジエナール アセタールの位置かつ立体選択的置換反応}, booktitle = {}, year = 2020, } @inproceedings{CTT100820040, author = {嵯峨 康平 and 重田 雅之 and 秦 猛志 and 占部 弘和}, title = {銅触媒とジアリールヨードニウム塩によるテトラゾール-5-アセトアミド類の1位選択的アリール化反応}, booktitle = {}, year = 2020, } @inproceedings{CTT100820039, author = {嵯峨 康平 and 伊藤 翔 and 重田 雅之 and 秦 猛志 and 占部 弘和}, title = {銅触媒とジアリールヨードニウム塩によるテトラゾール-5-アセトアミド類のデグラデーション反応}, booktitle = {}, year = 2020, } @inproceedings{CTT100820037, author = {秦 猛志 and 阿部鉄平 and 重田雅之 and 占部弘和}, title = {Rh触媒による1-アジド-2-[(2,2-ジハロビニル)(Boc)アミノ]アレーンからの2-ハロキノキサリンの位置選択的合成}, booktitle = {}, year = 2020, } @inproceedings{CTT100820033, author = {秦 猛志 and 小野田 聡志 and 重田雅之 and 占部弘和}, title = {Mn塩存在下ニトロ化合物とグリニャール試薬によるN,N-ジ置換ヒドロキシルアミン合成}, booktitle = {}, year = 2019, } @inproceedings{CTT100820036, author = {嵯峨康平 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {官能性および光学活性アルコールによるテトラゾールの高選択的2位アルキル化反応}, booktitle = {}, year = 2019, } @inproceedings{CTT100820035, author = {菅野剛志 and 海老原 太陽 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {鉄触媒による脂肪族グリニャール試薬のα,β,γ,δ-不飽和カルボニル化合物への位置かつ立体選択的付加反応}, booktitle = {}, year = 2019, } @inproceedings{CTT100820034, author = {秦 猛志 and 阿部鉄平 and 重田雅之 and 占部弘和}, title = {Rh触媒とo-(2,2-ジハロビニル)アリールアジドからの2,3-ジハロインドール合成}, booktitle = {}, year = 2019, } @inproceedings{CTT100783296, author = {菅野剛志 and 川田紘次郎 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {鉄触媒による脂肪族グリニャール試薬のα,β,γ,δ-不飽和カルボニル化合物への位置かつcis-選択的付加反応}, booktitle = {}, year = 2018, } @inproceedings{CTT100783295, author = {秦 猛志 and 戸谷英太郎 and 重田雅之 and 占部弘和}, title = {芳香族ニトロ化合物とアリールグリニャール試薬から合成された多環性ベンゾイミダゾールをテンプレートとする共役伸長}, booktitle = {}, year = 2018, } @inproceedings{CTT100761178, author = {大倉滉生 and 嵯峨康平 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {Ag触媒によるニトロオレフィンへの1-テトラゾリル基の共役付加反応}, booktitle = {}, year = 2018, } @inproceedings{CTT100761184, author = {宮仲健人 and 原田朋奈 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {FeCl2とブチル-フリル混合グリニャール試薬による2,4-アルカジエニルカルボキシレートの位置かつ立体選択的デオキシ化反応}, booktitle = {}, year = 2018, } @inproceedings{CTT100761183, author = {田中克樹 and 篠原裕樹 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {1-ハロ-1-アルキンへのトリアルキルホスファイトの求核付加による(ハロビニル)ホスホネートの立体選択的合成と利用}, booktitle = {}, year = 2018, } @inproceedings{CTT100761182, author = {秦 猛志 and 林 叔毅 and 長谷川祐紀 and 石井あゆみ and 長谷川美貴 and 重田雅之 and 占部弘和}, title = {テトラゾールを含む縮環π共役化合物の合成と溶液中における蛍光挙動}, booktitle = {}, year = 2018, } @inproceedings{CTT100761181, author = {水本詩菜 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {TiCl4共存下N,N-ジビニルアミドと1,1-ジクロロまたはジメトキシアルカンによる新規エナミド合成}, booktitle = {}, year = 2018, } @inproceedings{CTT100761180, author = {藤澤和来 and 小坂恭平 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {リチオ(ブロモ)エナミドの立体化学反転のメカニズムとそれを利用する多置換エナミドの立体選択的合成}, booktitle = {}, year = 2018, } @inproceedings{CTT100761179, author = {高力駿介 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {フェナントロインドリジジンの合成研究-フェナントレン部分の合成と不斉化}, booktitle = {}, year = 2018, } @inproceedings{CTT100761177, author = {大倉滉生 and 嵯峨康平 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {光延反応を利用したアルコールによるテトラゾールの高選択的2位アルキル化反応}, booktitle = {}, year = 2018, } @inproceedings{CTT100761176, author = {増山愛理 and 渡部可於理 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるオキシムを側鎖にもつスルホニルトリアゾールの環化反応}, booktitle = {}, year = 2018, } @inproceedings{CTT100761175, author = {秦 猛志 and 金井優貴 and 阿部鉄平 and 重田雅之 and 占部弘和}, title = {Rh触媒とo-(2,2-ジハロビニル)アリールアジドによる2,3-ジハロインドールの合成}, booktitle = {}, year = 2018, } @inproceedings{CTT100761174, author = {池田 譲 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるN-[1-[o-(ブロモエチニル)フェニル]アルキル]イミドから光学活性を保持したインデニルアミン誘導体の合成}, booktitle = {}, year = 2018, } @inproceedings{CTT100753005, author = {宮仲健人 and 原田朋奈 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {Fe触媒とグリニャール試薬による2,4-アルカジエニルカルボキシレートの位置かつ立体選択的置換反応}, booktitle = {}, year = 2017, } @inproceedings{CTT100753008, author = {秦 猛志 and 後藤英之 and Kwek Cheah Ming and 瀬戸俊平 and 坂内理英 and 佐伯諒平 and 重田雅之 and 占部弘和}, title = {官能性ジエンモノエポキシドにおけるグリニャール試薬の鉄触媒置換反応を反復利用するポリプロピオネート類の合成研究}, booktitle = {}, year = 2017, } @inproceedings{CTT100753002, author = {重田雅之 and 坂口恵理子 and 小坂恭平 and 石井 梓 and 山岸優仁 and 秦 猛志 and 占部弘和}, title = {1-ハロ-1-アルキンへのカルボン酸アミドの付加反応とピロロキノリン合成への展開}, booktitle = {}, year = 2017, } @inproceedings{CTT100737551, author = {池田 譲 and 菅野剛志 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {Rh触媒による[1-[o-(ブロモエチニル)フェニル]アルキル]メチルエーテルの光学活性を保持した環化反応}, booktitle = {}, year = 2017, } @inproceedings{CTT100737550, author = {成相 智 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {官能性ω-ヨードアルケンの分子内環化反応によるシクロプロパン合成}, booktitle = {}, year = 2017, } @inproceedings{CTT100737549, author = {大倉滉生 and 小柳徹弥 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {Pd触媒とスルホニルアレンによるテトラゾールへの位置選択的炭素鎖導入}, booktitle = {}, year = 2017, } @inproceedings{CTT100737548, author = {水本詩菜 and 小川 晋 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {N, N-ジビニルアミドの新規合成法}, booktitle = {}, year = 2017, } @inproceedings{CTT100737547, author = {宮仲健人 and 三井崇裕 and 水森智也 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {ピリジン4位へのアリルまたはベンジル金属試薬付加の反応経路とその合成的利用}, booktitle = {}, year = 2017, } @inproceedings{CTT100737546, author = {秦 猛志 and 戸谷英太郎 and 高橋直人 and 重田雅之 and 占部弘和}, title = {芳香族ニトロ化合物とグリニャール試薬から発生したナイトレンを利用するベンゾイミダゾール合成}, booktitle = {}, year = 2017, } @inproceedings{CTT100737545, author = {小坂恭平 and 松本 翼 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {リチオ(ブロモ)エナミドの立体化学反転を利用する多置換エナミドの立体選択的合成}, booktitle = {}, year = 2017, } @inproceedings{CTT100737544, author = {松本 翼 and 小坂恭平 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {1-ブロモ-1-アルキンと(N)-アルキルトリフルアミドの付加体を利用する多置換エナミドの立体選択的合成}, booktitle = {}, year = 2017, } @inproceedings{CTT100737541, author = {秦 猛志 and 金井優貴 and 重田雅之 and 占部弘和}, title = {ハロアルキンへの求核付加とC-H活性化環化による含窒素π共役化合物の合成}, booktitle = {}, year = 2017, } @inproceedings{CTT100737553, author = {重田雅之 and 坂口恵理子 and 秦 猛志 and 占部弘和}, title = {キノリノンおよびヒドロキシピリジンのハロアルキンへのアンビデントな求核付加反応}, booktitle = {}, year = 2017, } @inproceedings{CTT100737552, author = {渡部可於理 and 増山愛理 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {Rh触媒とスルホニルトリアゾールによる立体選択的なピロリジン合成}, booktitle = {}, year = 2017, } @inproceedings{CTT100737540, author = {宮仲健人 and 原田朋奈 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {鉄触媒によるアリールグリニャール試薬の2,4-ジエニルカルボキシレートへの位置かつ立体選択的置換反応}, booktitle = {}, year = 2017, } @inproceedings{CTT100737543, author = {秦 猛志 and 高橋直人 and 重田雅之 and 占部弘和}, title = {Rh触媒分子内ヒドロアリール化を用いる縮合ヘテロ環化合物の合成}, booktitle = {}, year = 2017, } @inproceedings{CTT100737542, author = {秦 猛志 and 林 叔毅 and 重田雅之 and 占部弘和}, title = {ハロアルキンへの求核付加を利用する含アゾールπ共役化合物の合成}, booktitle = {}, year = 2017, } @inproceedings{CTT100737539, author = {重田雅之 and 大谷彗介 and 高力駿介 and 秦猛志 and 占部弘和}, title = {ファナントロインドリジジン類の合成研究}, booktitle = {}, year = 2016, } @inproceedings{CTT100712610, author = {Takeshi Hata and Naomi Tanaka and Masayuki Shigeta and Hirokazu Urabe}, title = {Preparation of Aminobiphenols and Benzimidazoles from Polyhalogenated Nitroarenes and Aryl Grignard Reagents via Magnesium-mediated Benzidine-type Rearrangement}, booktitle = {}, year = 2016, } @inproceedings{CTT100701880, author = {Takeshi Hata and Yuta Tatsumi and Naoto Takahashi and Masayuki Shigeta and Hirokazu Urabe}, title = {Facile Preparation of Polycyclic Difuran Compounds via Nucleophilic Addition to Haloalkynes Followed by Cyclization Involving C-H Activation}, booktitle = {}, year = 2016, } @inproceedings{CTT100701879, author = {秦 猛志 and 辰巳湧太 and 高橋直人 and 重田雅之 and 占部弘和}, title = {ハロアルキンへの求核付加とC-H活性化環化による多環状ジフラン化合物の簡便合成}, booktitle = {}, year = 2016, } @inproceedings{CTT100681892, author = {妹尾麻慧 and 古川礼奈 and 渡部可於理 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {Rh触媒とトリアゾールによるO隣接C‒H結合活性化を経るテトラヒドロフラン合成}, booktitle = {}, year = 2015, } @inproceedings{CTT100681891, author = {妹尾麻慧 and 古川礼奈 and 秦 猛志 and 占部弘和}, title = {Rh触媒とトリアゾールによるN隣接C‒H結合活性化を経た立体選択的環化反応}, booktitle = {}, year = 2015, } @inproceedings{CTT100681890, author = {小川 晋 and 坂口恵理子 and 秦 猛志 and 占部弘和}, title = {ハロアルキンへのN‒(シクロプロピルメチル)トリフルアミドの求核付加を利用するgem‒エタノピロリジン類の合成}, booktitle = {}, year = 2015, } @inproceedings{CTT100681889, author = {石井 梓 and 山岸優仁 and 小坂恭平 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {カルボン酸アミドのハロアルキンへの求核付加反応とその利用}, booktitle = {}, year = 2015, } @inproceedings{CTT100681888, author = {辰巳湧太 and 田中直美 and 秦 猛志 and 占部弘和}, title = {グリニャール/Ce/Cu三元試薬によるニトロ化合物からニトロンの合成}, booktitle = {}, year = 2015, } @inproceedings{CTT100681887, author = {クェク チャーミン and 重田雅之 and 秦 猛志 and 占部弘和}, title = {鉄触媒メチル化反応を反復利用する(+)‒ジンコフォリンの合成研究}, booktitle = {}, year = 2015, } @inproceedings{CTT100681886, author = {秦 猛志 and 勝見圭一朗 and 占部弘和}, title = {Rh触媒C‒H結合活性化反応を利用した光学活性アクアヤマイシンの形式的全合成}, booktitle = {}, year = 2015, } @inproceedings{CTT100681885, author = {山岸優仁 and 篠原裕樹 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {ジアミンのハロアルキンへのダブル付加と空気酸化を経るアセチレン結合のワンポット切断反応}, booktitle = {}, year = 2015, } @inproceedings{CTT100681884, author = {山岸優仁 and 篠原裕樹 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {ハロアルキンへの2‒アミノアルカノールのダブル付加を経るジヒドロオキサジン類の簡便合成}, booktitle = {}, year = 2015, } @inproceedings{CTT100681883, author = {成相 智 and 中川一茂 and 秦 猛志 and 占部弘和}, title = {Fe触媒によるグリニャール試薬とω‒ハロ‒α,β,γ,δ‒不飽和エステル・アミドの付加・環化を経たワンポット立体選択的シクロペンタンおよびヘキサン合成}, booktitle = {}, year = 2015, } @inproceedings{CTT100681882, author = {中川一茂 and 成相 智 and 秦 猛志 and 占部弘和}, title = {Fe触媒によるグリニャール試薬とω‒ハロ‒α,β,γ,δ‒不飽和エステル・アミドの付加・環化を経たワンポット立体選択的シクロヘキセン合成}, booktitle = {}, year = 2015, } @inproceedings{CTT100681880, author = {大谷彗介 and 岩田智史 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {Fe触媒によるグリニャール試薬のエンイノエート類への選択的な1,6‒付加反応とmeloscineの合成研究}, booktitle = {}, year = 2015, } @inproceedings{CTT100681881, author = {菅野剛志 and 水野 瞳 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {鉄触媒によるシクロプロピルグリニャール試薬の2,4‒アルカジエノエートまたはアミドへの立体選択的1,6‒付加反応}, booktitle = {}, year = 2015, } @inproceedings{CTT100681879, author = {山岸優仁 and 小柳徹弥 and 秦 猛志 and 占部弘和}, title = {ハロアルキンへのテトラゾール類の求核付加反応とその利用}, booktitle = {}, year = 2015, } @inproceedings{CTT100681893, author = {水森智也 and 三井崇裕 and 宮仲健人 and 重田雅之 and 秦 猛志 and 占部弘和}, title = {ピリジン4位へのベンジル亜鉛試薬の位置選択的付加反応}, booktitle = {}, year = 2015, } @inproceedings{CTT100687422, author = {秦 猛志 and 辰巳湧太 and 田中直美 and 重田雅之 and 占部弘和}, title = {ニトロ化合物とグリニャール試薬の還元的カップリング反応によるアミンおよびニトロンの選択的合成法の開発}, booktitle = {}, year = 2015, } @inproceedings{CTT100681754, author = {水森智也 and 秦 猛志 and 占部弘和}, title = {イットリウム試薬によるピリジン4位とスチレンの選択的カップリング反応}, booktitle = {}, year = 2014, } @inproceedings{CTT100681341, author = {水森智也 and 宮仲健人 and 三井崇裕 and 秦 猛志 and 占部弘和}, title = {スチレンとイットリウム試薬またはベンジルグリニャール試薬によるピリジンの4位選択的置換反応}, booktitle = {}, year = 2014, } @inproceedings{CTT100681755, author = {山岸優仁 and 石井 梓 and 嶋岡里香 and 西海 憲 and 秦 猛志 and 占部弘和}, title = {ハロアルキンへの求核付加反応とそれを利用するヘテロ環化合物合成}, booktitle = {}, year = 2013, } @inproceedings{CTT100681749, author = {Oh Yun Taek and 菅野剛志 and 秦 猛志 and 占部弘和}, title = {鉄触媒によるα,β,γ,δ-不飽和有機リン化合物へのグリニャール試薬の選択的δ-付加反応}, booktitle = {}, year = 2013, } @inproceedings{CTT100681750, author = {秦 猛志 and 勝見圭一朗 and 占部弘和}, title = {Rh触媒C-H結合活性化反応を利用した光学活性medermycinの形式的全合成}, booktitle = {}, year = 2013, } @inproceedings{CTT100681345, author = {Satoshi Iwata and Keisuke Ohtani and Takeshi Hata and Hirokazu Urabe}, title = {Copper- or Iron-Mediated Three-component Coupling of 2-Alken-4-ynoates, Grignard Reagents, and Organic Halides}, booktitle = {}, year = 2013, } @inproceedings{CTT100681344, author = {Kazushige Nakagawa and Yun Taek Oh and Takeshi Hata and Hirokazu Urabe}, title = {Iron-catalyzed Selective Addition of Aryl Grignard Reagents to Electron-Deficient Dienes}, booktitle = {}, year = 2013, } @inproceedings{CTT100681346, author = {西海 憲 and 小川 晋 and 秦 猛志 and 占部 弘和}, title = {ハロアセチレンへの求核付加とHeck反応によるダブル脱離を経たアルケニルベンゾフランの簡便合成}, booktitle = {}, year = 2013, } @inproceedings{CTT100681348, author = {妹尾麻慧 and 穂坂祐作 and 渡辺 友 and 嶋岡里香 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるアルキニルベンジル(またはアリル)エーテルのC–H結合活性化を経たジヒドロピラン類の合成}, booktitle = {}, year = 2013, } @inproceedings{CTT100681349, author = {秦 猛志 and 辰巳湧太 and 占部弘和}, title = {鉄触媒存在下ニトロ化合物とグリニャール試薬の還元的カップリング反応によるアミン合成}, booktitle = {}, year = 2013, } @inproceedings{CTT100681737, author = {坂内理英 and 瀬戸俊平 and 秦 猛志 and 占部弘和}, title = {グリニャール試薬の4,5-エポキシ-2-アルケノエートへの鉄触媒付加を反復利用する天然物の合成研究}, booktitle = {}, year = 2012, } @inproceedings{CTT100681739, author = {秦 猛志 and 坂内理英 and 占部弘和}, title = {FeCl2/4 t-BuMgClによる官能性ジエンモノエポキシドの還元的ホモカップリング反応−立体選択的シクロプロパン合成}, booktitle = {}, year = 2012, } @inproceedings{CTT100681740, author = {山岸優仁 and 石井 梓 and 秦 猛志 and 占部弘和}, title = {ハロアセチレンへの求核付加とC-H活性化環化による簡便なジヒドロイソキノリンの合成}, booktitle = {}, year = 2012, } @inproceedings{CTT100681741, author = {西海 憲 and 山岸優仁 and 秦 猛志 and 占部弘和}, title = {ハロアセチレンへの求核付加とC-H活性化環化による簡便な1,2-ベンゾチアジン1,1-ジオキシドの合成}, booktitle = {}, year = 2012, } @inproceedings{CTT100681742, author = {山岸優仁 and 石井 梓 and 秦 猛志 and 占部弘和}, title = {ハロアセチレンへの求核付加とC-H活性化環化による簡便なインドールの合成}, booktitle = {}, year = 2012, } @inproceedings{CTT100681744, author = {岩田智史 and 中川一茂 and 秦 猛志 and 占部弘和}, title = {鉄触媒によるヘテロ芳香族グリニャール試薬の2,4-アルカジエノエートへの立体選択的1,6-共役付加反応}, booktitle = {}, year = 2012, } @inproceedings{CTT100681745, author = {後藤英之 and 横溝智史 and 秦 猛志 and 占部弘和}, title = {cis-5-アリール-3-アルケン酸誘導体の環化と骨格転位を経る環状化合物の合成}, booktitle = {}, year = 2012, } @inproceedings{CTT100681746, author = {岩田智史 and 瀬戸俊平 and 秦 猛志 and 占部弘和}, title = {鉄試薬による2-アルケン-4-イノエート,tert-アルキルグリニャール試薬,および1-ブロモ-1-アルキンの3成分カップリング反応}, booktitle = {}, year = 2012, } @inproceedings{CTT100681748, author = {渡邉 友 and 嶋岡里香 and 秦 猛志 and 占部弘和}, title = {光学活性Rh触媒によるアルキニルベンジルエーテルのC-H活性化を経る不斉環化反応}, booktitle = {}, year = 2012, } @inproceedings{CTT100681736, author = {横溝智史 and 後藤英之 and 秦 猛志 and 占部弘和}, title = {cis-5-アリール-3-アルケン酸の環化と転位による多環状化合物の簡便合成}, booktitle = {}, year = 2011, } @inproceedings{CTT100681733, author = {秦 猛志 and 岩田智史 and 瀬戸俊平 and 占部弘和}, title = {鉄触媒による官能性共役エンインとグリニャール試薬からのアレンの選択的合成}, booktitle = {}, year = 2011, } @inproceedings{CTT100681735, author = {千田浩介 and 渡邉 友 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるハロエンインのハロシクロブテンへの不斉環化反応}, booktitle = {}, year = 2011, } @inproceedings{CTT100681732, author = {Satoshi Iwata and Takeshi Hata and Hirokazu Urabe}, title = {Iron-Catalyzed Selective Synthesis of Peroxyacetals from Unsaturated Ethers and tert-Butyl Hydroperoxide}, booktitle = {}, year = 2011, } @inproceedings{CTT100681731, author = {山岸優仁 and 西海 憲 and 岡崎 純 and 秦 猛志 and 占部弘和}, title = {1-ハロ-1-アルキンへの求核付加反応とその利用}, booktitle = {}, year = 2011, } @inproceedings{CTT100681708, author = {岩田智史 and 秦 猛志 and 占部弘和}, title = {鉄触媒存在下ベンジルエーテルとtert-ブチルヒドロぺルオキシドからペルオキシアセタールの選択的合成}, booktitle = {}, year = 2011, } @inproceedings{CTT100681701, author = {千田浩介 and 渡辺友 and 秦 猛志 and 占部弘和}, title = {光学活性Rh触媒によるハロエンインのハロシクロブテンへの不斉環化反応}, booktitle = {}, year = 2011, } @inproceedings{CTT100681702, author = {妹尾麻慧 and 千田浩介 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるハロアセチレンと芳香環の分子内環化反応とその利用}, booktitle = {}, year = 2011, } @inproceedings{CTT100681703, author = {山岸優仁 and 西海 憲 and 岡崎 純 and 秦 猛志 and 占部弘和}, title = {ハロアセチレンへのイミダゾール・イミダゾリンの立体選択的求核付加反応}, booktitle = {}, year = 2011, } @inproceedings{CTT100681704, author = {山岸優仁 and 岡崎 純 and 秦 猛志 and 占部弘和}, title = {ハロアセチレンへの求核付加反応を基軸とする環状アミンの合成}, booktitle = {}, year = 2011, } @inproceedings{CTT100681705, author = {山岸優仁 and 岡崎 純 and 秦 猛志 and 占部弘和}, title = {5−ハロ−4−アルキン−1−オールの求核的環化反応及び求核的環化スルホニル化反応}, booktitle = {}, year = 2011, } @inproceedings{CTT100681706, author = {横溝智史 and 後藤英之 and 秦 猛志 and 占部弘和}, title = {2,4-ジエノエートとアリールグリニャール試薬の鉄触媒カップリング生成物を利用するベンゾシクロヘプテノンの簡便合成}, booktitle = {}, year = 2011, } @inproceedings{CTT100681707, author = {秦 猛志 and 岩田智史 and 瀬戸俊平 and 占部弘和}, title = {鉄触媒による官能性共役エンインとグリニャール試薬からのアレンの選択的合成}, booktitle = {}, year = 2011, } @inproceedings{CTT100681690, author = {妹尾麻慧 and 千田浩介 and 村瀬裕彦 and 秦 猛志 and 占部弘和}, title = {ロジウム触媒によるハロアセチレンと含窒素官能基置換芳香環の分子内環化反応}, booktitle = {}, year = 2010, } @inproceedings{CTT100681692, author = {秦 猛志 and 中田拓也 and Oh Yun Taek and 広根直樹 and 占部弘和}, title = {鉄触媒によるアリールグリニャール試薬のα,β,γ,δ-不飽和スルホンへの選択的共役付加反応とその利用}, booktitle = {}, year = 2010, } @inproceedings{CTT100681694, author = {秦 猛志 and Dinh Hoang Yen and 日出島拓 and 占部弘和}, title = {ロジウム触媒C-H結合活性化を利用する(±)-diospongin Aおよび光学活性calyxin Lの合成}, booktitle = {}, year = 2010, } @inproceedings{CTT100681689, author = {広根直樹 and 横溝智史 and 秦 猛志 and 占部弘和}, title = {α,β,γ,δ-不飽和カルボニル化合物へのシリルリチウム試薬の選択的共役付加反応}, booktitle = {}, year = 2009, } @inproceedings{CTT100681688, author = {秦 猛志 and 坂内理英 and 大槻 葵 and 占部弘和}, title = {鉄触媒を用いたグリニャール試薬と官能性ジエンモノエポキシドおよびアリルスルホネートの位置および立体選択的カップリング反応}, booktitle = {}, year = 2009, } @inproceedings{CTT100681687, author = {岡崎純 and 千田浩介 and 村瀬裕彦 and 秦 猛志 and 占部弘和}, title = {1-ハロ-1-アルキンを利用する新規合成反応の開発}, booktitle = {}, year = 2009, } @inproceedings{CTT100681682, author = {秦 猛志 and 大槻葵 and 占部弘和}, title = {鉄触媒によるグリニャール試薬とγ,δ-エポキシ-α,β-不飽和カルボニル化合物のγ位選択的カップリング}, booktitle = {}, year = 2009, } @inproceedings{CTT100681679, author = {千田浩介 and 村瀬裕彦 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるハロアセチレンの分子内ヒドロアリール化反応}, booktitle = {}, year = 2009, } @inproceedings{CTT100681680, author = {村瀬裕彦 and 千田浩介 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるハロエンインの環化反応}, booktitle = {}, year = 2009, } @inproceedings{CTT100681681, author = {秦 猛志 and 今出葉月 and 占部弘和}, title = {鉄触媒存在下グリニャール試薬による官能性エンインのメタル化環化反応}, booktitle = {}, year = 2009, } @inproceedings{CTT100681683, author = {秦 猛志 and 占部弘和}, title = {グリニャール試薬2分子の付加を伴う官能性エンインのタンデム環化反応}, booktitle = {}, year = 2009, } @inproceedings{CTT100681684, author = {加藤雄三 and 秦 猛志 and 占部弘和}, title = {γ位に保護アミノ基を有するアルキル金属試薬の発生と利用}, booktitle = {}, year = 2009, } @inproceedings{CTT100681685, author = {広根直樹 and 秦 猛志 and 占部弘和}, title = {α,β,γ,δ-不飽和カルボニル化合物へのシリルリチウムの選択的1,4-共役付加反応}, booktitle = {}, year = 2009, } @inproceedings{CTT100681686, author = {日出島 拓 and 秦 猛志 and 占部弘和}, title = {2-アリール-5,6-ジヒドロ-2H-ピラン類と求電子あるいは求核試薬との反応}, booktitle = {}, year = 2009, } @inproceedings{CTT100681677, author = {秦 猛志 and 福留康弘 and 内藤寛之 and 占部弘和}, title = {スルホンアミドとハロアセチレンの反応を利用する含窒素ヘテロ環化合物の新規合成法}, booktitle = {}, year = 2008, } @inproceedings{CTT100681676, author = {村瀬裕彦 and 鹿内大輔 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるアルキニルエーテルの異性化反応と(±)-centrolobineの合成}, booktitle = {}, year = 2008, } @inproceedings{CTT100681675, author = {秦 猛志 and 広根 直樹 and 朱雀史朗 and 中野 貴理博 and 井本 淳介 and 占部 弘和}, title = {鉄試薬による官能性炭素−炭素多重結合の分子内環化反応}, booktitle = {}, year = 2008, } @inproceedings{CTT100681674, author = {村瀬裕彦 and 米原奈美 and 鹿内大輔 and 秦 猛志 and 占部弘和}, title = {ロジウム触媒によるアセチレンエーテル類の分子内環化反応の開発と利用}, booktitle = {}, year = 2008, } @inproceedings{CTT100681673, author = {秦 猛志 and 広根直樹 and 占部弘和}, title = {鉄試薬によるビスα,β-不飽和エステルの分子内タンデム環化反応}, booktitle = {}, year = 2008, } @inproceedings{CTT100681671, author = {荒山恭平 and 村山隆二 and 秦 猛志 and 占部弘和}, title = {鉄触媒の存否における光学活性α,β,γ,δ-飽和アミド上での3成分カップリング反応}, booktitle = {}, year = 2008, } @inproceedings{CTT100681672, author = {秦 猛志 and 井本淳介 and 占部弘和}, title = {鉄試薬による不飽和カルボニル化合物の還元的分子内アルキル化反応}, booktitle = {}, year = 2008, } @inproceedings{CTT100681670, author = {村瀬裕彦 and 米原奈美 and 鹿内大輔 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるアルキニルエーテル類の環化反応の立体化学とその利用}, booktitle = {}, year = 2008, } @inproceedings{CTT100681667, author = {加藤雄三 and Dinh Hoang Yen and 秦 猛志 and 占部弘和}, title = {アミノ基の脱離基への転換におけるアミノ修飾基の効果}, booktitle = {}, year = 2008, } @inproceedings{CTT100681668, author = {内藤寛之 and 秦 猛志 and 占部弘和}, title = {メタンスルホンアミドの新規な脱保護(脱メシル化)法の開発}, booktitle = {}, year = 2008, } @inproceedings{CTT100681669, author = {桟敷博明 and 田中亮一 and 秦 猛志 and 占部弘和}, title = {イットリウム塩共存下でのフェニルシランのアリールグリニャ−ル試薬による効率的置換反応}, booktitle = {}, year = 2008, } @inproceedings{CTT100681509, author = {加藤雄三 and Dihn Hoang Yen and 福留康弘 and 秦 猛志 and 占部弘和}, title = {保護されたアミノ基の脱離基への転換とその利用}, booktitle = {}, year = 2007, } @inproceedings{CTT100681508, author = {占部 弘和 and 秦 猛志 and 鹿内 大輔 and 村瀬 裕彦 and 米原 奈美}, title = {ロジウム触媒によるアセチレンエーテル類の新規異性化反応}, booktitle = {}, year = 2007, } @inproceedings{CTT100681507, author = {Hirokazu Urabe and Takeshi Hata and Daisuke Shikanai and Hirohiko Murase and Nami Yonehara}, title = {New Isomerization of Acetylenic Ether under Rh Catalyst}, booktitle = {}, year = 2007, } @inproceedings{CTT100681506, author = {Takeshi Hata and unknown unknown and Kirihiro Nakano and HIROKAZU URABE}, title = {Iron-Mediated Intramolecular Cyclization of Unsaturated Carbon-Carbon Bonds}, booktitle = {}, year = 2007, } @inproceedings{CTT100681505, author = {Kyohei Arayama and Satoshi Okada and Ryuji Murayama and Takumi Ishizuka and Takeshi Hata and Hirokazu Urabe}, title = {Iron-Catalyzed 1,6-Addition of Grignard Reagents to Chiral α,β,γ,δ-Unsaturated Amides. Its Application to Multi-Cmponent Coupling Process}, booktitle = {}, year = 2007, } @inproceedings{CTT100681504, author = {秦 猛志 and 荒山恭平 and 朱雀史朗 and 岡田悟史 and 中野貴理博 and 占部弘和}, title = {鉄塩とグリニャール試薬から調製した鉄試薬を用いる新規有機合成反応の開発}, booktitle = {}, year = 2007, } @inproceedings{CTT100681499, author = {秦 猛志 and 朱雀史朗 and 中野貴理博 and 占部弘和}, title = {FeCl2–t-BuMgClから調製した鉄試薬による官能性炭素—炭素不飽和結合の分子内環化反応}, booktitle = {}, year = 2007, } @inproceedings{CTT100681501, author = {内藤寛之 and 秦 猛志 and 占部弘和}, title = {ジアミン誘導体のブロモプロピオール酸アミドへの立体選択的二重付加反応によるイミダゾリジン類の合成}, booktitle = {}, year = 2007, } @inproceedings{CTT100681502, author = {鹿内大輔 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるアセチレンと環状エーテルの分子再構成反応}, booktitle = {}, year = 2007, } @inproceedings{CTT100681503, author = {村瀬裕彦 and 鹿内大輔 and 秦 猛志 and 占部弘和}, title = {Rh触媒によるベンジルエーテルとスルホニルアセチレンの分子内環化反応}, booktitle = {}, year = 2007, } @inproceedings{CTT100681500, author = {加藤雄三 and 秦猛志 and 占部弘和}, title = {アミノ基の修飾による直接求核置換反応の開発と利用}, booktitle = {}, year = 2007, } @inproceedings{CTT100681498, author = {占部 弘和 and 秦 猛志 and 田中 亮一 and 桟敷 博明}, title = {イットリウム試薬を用いる新規合成反応の開発}, booktitle = {}, year = 2006, } @inproceedings{CTT100681497, author = {Misa Sasaki and Hirotatsu Taura and Takeshi Hata and Fumie Sato and Hirokazu Urabe}, title = {A Novel Tandem Cyclization to 1,5-Bicyclo[3.3.0]octadienes and Its Application to the Synthesis of (±)-Hirsutene}, booktitle = {}, year = 2006, } @inproceedings{CTT100681496, author = {福留康弘 and 秦 猛志 and 占部弘和}, title = {イナミドを脱離基とする新規C-N結合切断反応}, booktitle = {}, year = 2006, } @misc{CTT100560574, author = {占部弘和}, title = {メタラサイクルをテンプレートとする多成分連結反応の開発}, year = 2006, } @misc{CTT100397985, author = {占部弘和}, title = {4族(Ti,Zr)メタラサイクルを経るヘテロ環化合物の合成法-アセチレン、オレフィン、およびヘテロ不飽和化合物の環化反応}, year = 2005, } @misc{CTT100397992, author = {西山 and 石原 and 村上 and 占部 and 中村 and 柴田 and 八谷}, title = {20年後に有機合成はどこに行くのか}, year = 2004, } @misc{CTT100560573, author = {占部弘和}, title = {共役ジ−、テトラ−、およびヘキサイン−チタン錯体の構造と反応}, year = 2000, } @misc{CTT100426426, author = {Fumie Sato and Hirokazu Urabe and Sentaro Okamoto}, title = {Bicyclization of Dienes, Enynes, and Diynes with Ti(II) Reagent. New Developments towards Asymmetric Synthesis}, year = 1999, } @misc{CTT100596582, author = {HIROKAZU URABE}, title = {New Methods for Selective Carbon-Carbon Bond Formation and Functionalization Based on Organosilicon Compounds}, year = 1985, } @phdthesis{CTT100596582, author = {HIROKAZU URABE}, title = {New Methods for Selective Carbon-Carbon Bond Formation and Functionalization Based on Organosilicon Compounds}, school = {東京工業大学}, year = 1985, }