論文

• Yuma Morimoto, Yuki Shimaoka, Kosuke Fukui, Shinobu Itoh. Selective Alkane Hydroxylation in a Fluorous Solvent System Catalyzed by a Fluorocarbon-Soluble Transition-Metal Catalyst, ACS Omega, May 2024.  公式リンク  
  
• Hideki Sugimoto, Megumu Sakaida, Yoshihito Shiota, Mayuko Miyanishi, Yuma Morimoto, Kazunari Yoshizawa, Shinobu Itoh. A rhodium(ii)/rhodium(iii) redox couple for C–H bond amination with alkylazides: a rhodium(iii)–nitrenoid intermediate with a tetradentate [14]-macrocyclic ligand, Dalton Transactions, 2024.  公式リンク  
  
• Yang Lan, Yuma Morimoto, Ikuma Shimizu, Hideki Sugimoto, Shinobu Itoh. Characterization and Reactivity Studies of Mononuclear Tetrahedral Copper(II)–Halide Complexes, Inorganic Chemistry, July 2023.  公式リンク  
  
• Kohei Yamaguchi, Yuya Uemura, Hideki Sugimoto, Rin Ito, Yuma Morimoto, Shinobu Itoh. Mechanistic studies on catalytic alkane oxidation by Murahashi's O2/copper(ii)/aldehyde system, Catalysis Science & Technology, 2023.  公式リンク  
  
• Yuma Morimoto, Makito Kawai, Aya Nakanishi, Hideki Sugimoto, Shinobu Itoh. Controlling the Reactivity of Copper(II) Acylperoxide Complexes, Inorganic Chemistry, Vol. 60, No. 12, pp. 8554-8565, June 2021.  公式リンク  
  
• Yuma Morimoto, Shinichi Hanada, Ryusuke Kamada, Arisa Fukatsu, Hideki Sugimoto, Shinobu Itoh. Hydroxylation of Unactivated C(sp3)–H Bonds with m-Chloroperbenzoic Acid Catalyzed by an Iron(III) Complex Supported by a Trianionic Planar Tetradentate Ligand, Inorganic Chemistry, Vol. 60, No. 11, pp. 7641-7649, June 2021.  公式リンク  
  
• Fujita, D., Kaga, A., Sugimoto, H., Morimoto, Y., Itoh, S., Yuma Morimoto. Controlling coordination number of rhodium(III) complex by ligand-based redox for catalytic CH amination, Bulletin of the Chemical Society of Japan, Vol. 93, No. 2, pp. 279-286, 2020.  公式リンク  
  
• Fukatsu, A., Morimoto, Y., Sugimoto, H., Itoh, S., Yuma Morimoto. Modelling a ‘histidine brace’ motif in mononuclear copper monooxygenases, Chemical Communications, Vol. 56, No. 38, pp. 5123-5126, 2020.  公式リンク  
  
• Yuma Morimoto, Yuki Shimaoka, Yuri Ishimizu, Hiroshi Fujii, Shinobu Itoh. Direct Observation of Primary C−H Bond Oxidation by an Oxido‐Iron(IV) Porphyrin π‐Radical Cation Complex in a Fluorinated Carbon Solvent, Angewandte Chemie, Vol. 131, No. 32, pp. 10979-10982, Aug. 2019.  公式リンク  
  
• Yuma Morimoto, Yuki Shimaoka, Yuri Ishimizu, Hiroshi Fujii, Shinobu Itoh. Direct Observation of Primary C−H Bond Oxidation by an Oxido‐Iron(IV) Porphyrin π‐Radical Cation Complex in a Fluorinated Carbon Solvent, Angewandte Chemie International Edition, Vol. 58, No. 32, pp. 10863-10866, Aug. 2019.  公式リンク  
  
• Shimizu, I., Morimoto, Y., Velmurugan, G., Gupta, T., Paria, S., Ohta, T., Sugimoto, H., Ogura, T., Comba, P., Itoh, S., Yuma Morimoto. Characterization and Reactivity of a Tetrahedral Copper(II) Alkylperoxido Complex, Chemistry - A European Journal, Vol. 25, No. 47, pp. 11157-11165, 2019.  公式リンク  
  
• Abe, T., Hori, Y., Shiota, Y., Ohta, T., Morimoto, Y., Sugimoto, H., Ogura, T., Yoshizawa, K., Itoh, S., Yuma Morimoto. Cupric-superoxide complex that induces a catalytic aldol reaction-type C–C bond formation, Communications Chemistry, Vol. 2, No. 1, 2019.  公式リンク  
  
• Daiki Fujita, Hideki Sugimoto, Yuma Morimoto, Shinobu Itoh. Noninnocent Ligand in Rhodium(III)-Complex-Catalyzed C–H Bond Amination with Tosyl Azide, Inorganic Chemistry, Vol. 57, No. 16, pp. 9738-9747, Aug. 2018.  公式リンク  
  
• Yuma Morimoto, Yusaku Takagi, Toru Saito, Takehiro Ohta, Takashi Ogura, Norimitsu Tohnai, Motohiro Nakano, Shinobu Itoh. A Bis(μ‐oxido)dinickel(III) Complex with a Triplet Ground State, Angewandte Chemie International Edition, Vol. 57, No. 26, pp. 7640-7643, June 2018.  公式リンク  
  
• Yuma Morimoto, Yusaku Takagi, Toru Saito, Takehiro Ohta, Takashi Ogura, Norimitsu Tohnai, Motohiro Nakano, Shinobu Itoh. A Bis(μ‐oxido)dinickel(III) Complex with a Triplet Ground State, Angewandte Chemie, Vol. 130, No. 26, pp. 7766-7769, June 2018.  公式リンク  
  
• Sayantan Paria, Yuma Morimoto, Takehiro Ohta, Shinsuke Okabe, Hideki Sugimoto, Takashi Ogura, Shinobu Itoh. Copper(I)–Dioxygen Reactivity in the Isolated Cavity of a Nanoscale Molecular Architecture, European Journal of Inorganic Chemistry, Vol. 2018, No. 19, pp. 1976-1983, May 2018.  公式リンク  
  
• Sayantan Paria, Yuma Morimoto, Takehiro Ohta, Shinsuke Okabe, Hideki Sugimoto, Takashi Ogura, Shinobu Itoh. Cover Feature: Copper(I)–Dioxygen Reactivity in the Isolated Cavity of a Nanoscale Molecular Architecture (Eur. J. Inorg. Chem. 19/2018), European Journal of Inorganic Chemistry, Vol. 2018, No. 19, pp. 1955-1955, May 2018.  公式リンク  
  
• Itoh, S., Abe, T., Morimoto, Y., Sugimoto, H., Yuma Morimoto. 2-(2-Pyridyl)ethylamine (Pye) ligands in copper(I)-dioxygen chemistry, Inorganica Chimica Acta, Vol. 481, pp. 38-46, 2018.  公式リンク  
  
• Asahi, M., Yamazaki, S.-I., Morimoto, Y., Itoh, S., Ioroi, T., Yuma Morimoto. Crystal structure and oxygen reduction reaction (ORR) activity of copper(II) complexes of pyridylmethylamine ligands containing a carboxy group, Inorganica Chimica Acta, Vol. 471, pp. 91-98, 2018.  公式リンク  
  
• Paria, S., Ohta, T., Morimoto, Y., Sugimoto, H., Ogura, T., Itoh, S., Yuma Morimoto. Structure and Reactivity of Copper Complexes Supported by a Bulky Tripodal N<inf>4</inf> Ligand: Copper(I)/Dioxygen Reactivity and Formation of a Hydroperoxide Copper(II) Complex, Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 644, No. 14, pp. 780-789, 2018.  公式リンク  
  
• Krug, R., Schröder, D., Gebauer, J., Suljić, S., Morimoto, Y., Fujieda, N., Itoh, S., Pietruszka, J., Yuma Morimoto. Tyrosinases in Organic Chemistry: A Versatile Tool for the α-Arylation of β-Dicarbonyl Compounds, European Journal of Organic Chemistry, Vol. 2018, No. 15, pp. 1789-1796, 2018.  公式リンク  
  
• Arnaud Parrot, Yuma Morimoto, Sayantan Paria, Hideki Sugimoto, Nobutaka Fujieda, Shinobu Itoh. Generation and characterisation of a stable nickel(ii)-aminoxyl radical complex, Dalton Transactions, Vol. 46, No. 25, pp. 8013-8016, 2017.  公式リンク  
  
• Fujieda, Nobutaka, Nakano, Takumi, Taniguchi, Yuki, Ichihashi, Haruna, Sugimoto, Hideki, Morimoto, Yuma, Nishikawa, Yosuke, Kurisu, Genji, Itoh, Shinobu, Yuma Morimoto. A Well-Defined Osmium-Cupin Complex: Hyperstable Artificial Osmium Peroxygenase, Journal of the American Chemical Society, Vol. 139, No. 14, pp. 5149-5155, 2017.  公式リンク  
  
• Fujita, Daiki, Sugimoto, Hideki, Shiota, Yoshihito, Morimoto, Yuma, Yoshizawa, Kazunari, Itoh, Shinobu, Yuma Morimoto. Catalytic C-H amination driven by intramolecular ligand-to-nitrene one-electron transfer through a rhodium((III)) centre, Chemical Communications, Vol. 53, No. 35, pp. 4849-4852, 2017.  公式リンク  
  
• Parrot, Arnaud, Morimoto, Yuma, Paria, Sayantan, Sugimoto, Hideki, Fujieda, Nobutaka, Itoh, Shinobu, Yuma Morimoto. Generation and characterisation of a stable nickel(II)-aminoxyl radical complex, Dalton Transactions, Vol. 46, No. 25, pp. 8013-8016, 2017.  公式リンク  
  
• Abe, T., Morimoto, Y., Mieda, K., Sugimoto, H., Fujieda, N., Ogura, T., Itoh, S., Yuma Morimoto. Geometric effects on O–O bond scission of copper(II)-alkylperoxide complexes, Journal of Inorganic Biochemistry, Vol. 177, pp. 375-383, 2017.  公式リンク  
  
• Shimizu, Ikuma, Morimoto, Yuma, Faitermeier, Dieter, Kerscher, Marion, Paria, Sayantan, Abe, Tsukasa, Sugimoto, Hideki, Fujieda, Nobutaka, Asano, Kaori, Suzuki, Takeyuki, Comba, Peter, Itoh, Shinobu, Yuma Morimoto. Tetrahedral Copper(II) Complexes with a Labile Coordination Site Supported by a Tris-tetramethylguanidinato Ligand, Inorganic Chemistry, Vol. 56, No. 16, pp. 9634-9645, 2017.  公式リンク  
  
• Paul, Mitali, Shirase, Satoru, Morimoto, Yuma, Mathey, Laurent, Murugesapandian, Balasubramanian, Tanaka, Shinji, Itoh, Shinobu, Tsurugi, Hayato, Mashima, Kazushi, Yuma Morimoto. Cerium-Complex-Catalyzed Oxidation of Arylmethanols under Atmospheric Pressure of Dioxygen and Its Mechanism through a Side-On -Peroxo Dicerium(IV) Complex, Chemistry-a European Journal, Vol. 22, No. 12, pp. 4008-4014, 2016.  公式リンク  
  
• Morimoto, Yuma, Bunno, Shuji, Fujieda, Nobutaka, Sugimoto, Hideki, Itoh, Shinobu, Yuma Morimoto. Direct Hydroxylation of Benzene to Phenol Using Hydrogen Peroxide Catalyzed by Nickel Complexes Supported by Pyridylalkylamine Ligands, Journal of the American Chemical Society, Vol. 137, No. 18, pp. 5867-5870, 2015.  公式リンク  
  
• Paria, Sayantan, Ohta, Takehiro, Morimoto, Yuma, Ogura, Takashi, Sugimoto, Hideki, Fujieda, Nobutaka, Goto, Kei, Asano, Kaori, Suzuki, Takeyuki, Itoh, Shinobu, Yuma Morimoto. Generation, Characterization, and Reactivity of a Cu-II-Alkylperoxide/Anilino Radical Complex: Insight into the O-O Bond Cleavage Mechanism, Journal of the American Chemical Society, Vol. 137, No. 34, pp. 10870-10873, 2015.  公式リンク  
  
• Morimoto, Yuma, Takaichi, June, Hanada, Shinichi, Ohkubo, Kei, Sugimoto, Hideki, Fujieda, Nobutaka, Fukuzumi, Shunichi, Itoh, Shinobu, Yuma Morimoto. Redox behavior of novel nickel and palladium complexes supported by trianionic non-innocent ligand containing β-diketiminate and phenol groups, Journal of Porphyrins and Phthalocyanines, Vol. 19, No. 01-03, pp. 377-387, 2015.  公式リンク  
  
• Faraj, F.L., Khaledi, H., Morimoto, Y., Itoh, S., Olmstead, M.M., Ali, H.M., Yuma Morimoto. A tetradentate β-diiminato ligand containing phenolate substituents: Flexivalent coordination to Mn^III, Co^III, Ni^II, and Cu^II, European Journal of Inorganic Chemistry, Vol. 2014, No. 33, pp. 5752-5759, 2014.  公式リンク  
  
• Abe, Tsukasa, Morimoto, Yuma, Tano, Tetsuro, Mieda, Kaoru, Sugimoto, Hideki, Fujieda, Nobutaka, Ogura, Takashi, Itoh, Shinobu, Yuma Morimoto. Geometric Control of Nuclearity in Copper(I)/Dioxygen Chemistry, Inorganic Chemistry, Vol. 53, No. 16, pp. 8786-8794, 2014.  公式リンク  
  
• Takaichi, June, Morimoto, Yuma, Ohkubo, Kei, Shimokawa, Chizu, Hojo, Takayuki, Mori, Seiji, Asahara, Haruyasu, Sugimoto, Hideki, Fujieda, Nobutaka, Nishiwaki, Nagatoshi, Fukuzumi, Shunichi, Itoh, Shinobu, Yuma Morimoto. Redox Chemistry of Nickel(II) Complexes Supported by a Series of Noninnocent beta-Diketiminate Ligands, Inorganic Chemistry, Vol. 53, No. 12, pp. 6159-6169, 2014.  公式リンク  
  
• Park, Jiyun, Morimoto, Yuma, Lee, Yong-Min, Nam, Wonwoo, Fukuzumi, Shunichi, Yuma Morimoto. Unified View of Oxidative C-H Bond Cleavage and Sulfoxidation by a Nonheme Iron(IV)-Oxo Complex via Lewis Acid-Promoted Electron Transfer, Inorganic Chemistry, Vol. 53, No. 7, pp. 3618-3628, 2014.  公式リンク  
  
• Morimoto, Yuma, Lee, Yong-Min, Nam, Wonwoo, Fukuzumi, Shunichi, Yuma Morimoto. An autocatalytic radical chain pathway in formation of an iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol, Chemical Communications, Vol. 49, No. 25, pp. 2500-2502, 2013.  公式リンク  
  
• Nishida, Yusuke, Morimoto, Yuma, Lee, Yong-Min, Nam, Wonwoo, Fukuzumi, Shunichi, Yuma Morimoto. Effects of Proton Acceptors on Formation of a Non-Heme Iron(IV)-Oxo Complex via Proton-Coupled Electron Transfer, Inorganic Chemistry, Vol. 52, No. 6, pp. 3094-3101, 2013.  公式リンク  
  
• Yoon, H., Morimoto, Y., Lee, Y.-M., Nam, W., Fukuzumi, S., Yuma Morimoto. Electron-transfer properties of a nonheme manganese(IV)–oxo complex acting as a stronger one-electron oxidant than the iron(IV)–oxo analogue, Chemical Communications, Vol. 48, No. 91, pp. 11187-11189, 2012.  公式リンク  
  
• Fukuzumi, Shunichi, Ohkubo, Kei, Morimoto, Yuma, Yuma Morimoto. Mechanisms of metal ion-coupled electron transfer, Physical Chemistry Chemical Physics, Vol. 14, No. 24, pp. 8472-8484, 2012.  公式リンク  
  
• Morimoto, Yuma, Park, Jiyun, Suenobu, Tomoyoshi, Lee, Yong-Min, Nam, Wonwoo, Fukuzumi, Shunichi, Yuma Morimoto. Mechanistic Borderline of One-Step Hydrogen Atom Transfer versus Stepwise Sc3+-Coupled Electron Transfer from Benzyl Alcohol Derivatives to a Non-Heme Iron(IV)-Oxo Complex, Inorganic Chemistry, Vol. 51, No. 18, pp. 10025-10036, 2012.  公式リンク  
  
• Park, Jiyun, Morimoto, Yuma, Lee, Yong-Min, Nam, Wonwoo, Fukuzumi, Shunichi, Yuma Morimoto. Proton-Promoted Oxygen Atom Transfer vs Proton-Coupled Electron Transfer of a Non-Heme Iron(IV)-Oxo Complex, Journal of the American Chemical Society, Vol. 134, No. 8, pp. 3903-3911, 2012.  公式リンク  
  
• Park, J., Morimoto, Y., Lee, Y.-M., Nam, W., Fukuzumi, S., Yuma Morimoto. Proton-promoted oxygen atom transfer vs proton-coupled electron transfer of a non-heme iron(IV)-oxo complex, Journal of the American Chemical Society, Vol. 134, No. 8, pp. 3903-3911, 2012.  公式リンク  
  
• Park, J, Morimoto, Y, Lee, YM, Nam, W, Fukuzumi, S, Yuma Morimoto. Metal Ion Effect on the Switch of Mechanism from Direct Oxygen Transfer to Metal Ion-Coupled Electron Transfer in the Sulfoxidation of Thioanisoles by a Non-Heme Iron(IV)-Oxo Complex, Journal of the American Chemical Society, Vol. 133, No. 14, pp. 5236-5239, 2011.  公式リンク  
  
• Morimoto, Y, Kotani, H, Park, J, Lee, YM, Nam, W, Fukuzumri, S, Yuma Morimoto. Metal Ion-Coupled Electron, Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc3+, Journal of the American Chemical Society, Vol. 133, No. 3, pp. 403-405, 2011.  公式リンク  
  
• Park, Jiyun, Morimoto, Yuma, Lee, Yong-Min, You, Youngmin, Nam, Wonwoo, Fukuzumi, Shunichi, Yuma Morimoto. Scandium Ion-Enhanced Oxidative Dimerization and N-Demethylation of N,N-Dimethylanilines by a Non-Heme Iron(IV)-Oxo Complex, Inorganic Chemistry, Vol. 50, No. 22, pp. 11612-11622, 2011.  公式リンク  
  
• Fukuzumi, S, Morimoto, Y, Kotani, H, Naumov, P, Lee, YM, Nam, W, Yuma Morimoto. Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer, Nature Chemistry, Vol. 2, No. 9, pp. 756-759, 2010.  公式リンク  
  
• Lee, YM, Hong, S, Morimoto, Y, Shin, W, Fukuzumi, S, Nam, W, Yuma Morimoto. Dioxygen Activation by a Non-Heme Iron(II) Complex: Formation of an Iron(IV)-Oxo Complex via C-H Activation by a Putative Iron(III)-Superoxo Species, Journal of the American Chemical Society, Vol. 132, No. 31, pp. 10668-10670, 2010.  公式リンク  
  

著書

• Itoh Shinobu, Morimoto Yuma. β-Diketiminates as Redox Non-innocent Supporting Ligands in Coordination Chemistry, Chemical Science of Electron Systems, pp. 715-730, 2015.  公式リンク  

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