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Title
Japanese: 
English:Reversible, Strain-Controlled Haptotropic Shifts of Cyclopentadienyl Ligands in [1]- and [2]Metallocenophanes 
Author
Japanese: 田邊 真, Sara C. Bourke, David E. Herbert, Alan J. Lough, Ian Manners.  
English: Makoto Tanabe, Sara C. Bourke, David E. Herbert, Alan J. Lough, Ian Manners.  
Language English 
Journal/Book name
Japanese: 
English:Angewandte Chemie International Edition 
Volume, Number, Page Vol. 44    No. 36    pp. 5886-5890
Published date Aug. 10, 2005 
Publisher
Japanese: 
English: 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1002/anie.200501155
Abstract Slipping rings: A reversible shift from η5-Cp to η1-Cp and back has been established for ring-strained metallocenophanes (see scheme) and the dependence of the reversibility on the degree of ring strain has been probed. The presence of phosphane ligands has allowed the isolation of novel η1-Cp ring-slipped Fe and Ru complexes.

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