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Title
Japanese: 
English:Epitaxially Stabilized EuMoO3: A New Itinerant Ferromagnet 
Author
Japanese: 小塚 裕介, H. Seki, T. Fujita, Chakraverty Suvankar, 吉松 公平, 組頭 広志, 尾嶋 正治, M. S. Bahramy, R. Arita, 川崎 雅司.  
English: Y. Kozuka, H. Seki, T. Fujita, S. Chakraverty, K. Yoshimatsu, H. Kumigashira, M. Oshima, M. S. Bahramy, R. Arita, M. Kawasaki.  
Language English 
Journal/Book name
Japanese: 
English:Chemistry of Materials 
Volume, Number, Page Vol. 24        Page 3746
Published date Sept. 14, 2012 
Publisher
Japanese: 
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Conference name
Japanese: 
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Conference site
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DOI https://doi.org/10.1021/cm302231k
Abstract Synthesizing metastable phases often open new functions in materials, but it is a challenging topic. Thin film techniques have advantages to form materials which do not exist in nature since nonequilibrium processes are frequently utilized. In this study, we successfully synthesize an epitaxially stabilized new compound of perovskite Eu2+Mo4+O3 as a thin film form by a pulsed laser deposition. The analogous perovskite SrMoO3 is a highly conducting paramagnetic material, but Eu2+ and Mo4+ are not compatible in equilibrium, and a previous study found that the more stable pyrochlore Eu2 3+Mo2 4+O7 prefers to form. By using isostructural perovskite substrates, the gain of the interface energy between the film and the substrate stabilizes the matastable EuMoO3 phase. This compound exhibits high conductivity and large magnetic moment, originating from Mo 4d2 electrons and Eu 4f7 electrons, respectively. Our result indicates the epitaxial stabilization is effective not only to stabilize crystallographic structures but also to form a new compound which contains unstable combinations of ionic valences in bulk form.

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