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Title
Japanese: 
English:Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis 
Author
Japanese: 安祐輔, 小池隆司, 穐田宗隆.  
English: Yusuke Yasu, Takashi Koike, MUNETAKA AKITA.  
Language English 
Journal/Book name
Japanese: 
English:ORG. LETT. 
Volume, Number, Page Vol. 15        Page 2136–2139
Published date Apr. 19, 2013 
Publisher
Japanese: 
English:ACS publications 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1021/ol4006272
Abstract Intermolecular aminotrifluoromethylation of alkenes catalyzed by [Ru(bpy)3]2þ under visible light irradiation has been explored. The present photocatalytic protocol achieves highly efficient and regioselective difunctionalization of CdC bonds, leading to a variety of β-trifluoromethylamines. The reaction is applied to “late-stage aminotrifluoromethylation” of steroid and amino acid scaffolds.

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