Home >

news Help

Publication Information


Title
Japanese:Hydrosilylation of various multiple bonds by a simple combined catalyst of a tungstate monomer and rhodium acetate. 
English:Hydrosilylation of various multiple bonds by a simple combined catalyst of a tungstate monomer and rhodium acetate. 
Author
Japanese: Shintaro Itagaki, Hanako Sunaba, Keigo Kamata, Kazuya Yamaguchi, Noritaka. Mizuno.  
English: Shintaro Itagaki, Hanako Sunaba, Keigo Kamata, Kazuya Yamaguchi, Noritaka. Mizuno.  
Language English 
Journal/Book name
Japanese:Chemistry Letters 
English:Chemistry Letters 
Volume, Number, Page Vol. 42    No. 9    pp. 980-982
Published date 2013 
Publisher
Japanese:Chemical Society of Japan 
English:Chemical Society of Japan 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1246/cl.130338
Abstract In the presence of a simple combined catalyst of a tungstate monomer (TBA2WO4, TBA: tetra-n-butylammonium) and Rh2(OAc)4 hydrosilylation of various types of substances including ketone, aldehyde, carbon dioxide, alkene, nitrile, and furan derivs. efficiently proceeded, affording the corresponding hydrosilylation products in moderate to high yields (竕・63% yields). In addn., the present system was also applicable to the one-pot redn. of benzamide to benzylamine (95% yield). [on SciFinder(R)]

©2007 Tokyo Institute of Technology All rights reserved.