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Title
Japanese:Novel all-inorganic mononuclear chloro oxo diperoxotungstate. 
English:Novel all-inorganic mononuclear chloro oxo diperoxotungstate. 
Author
Japanese: Ryo Ishimoto, Keigo Kamata, Noritaka. Mizuno.  
English: Ryo Ishimoto, Keigo Kamata, Noritaka. Mizuno.  
Language English 
Journal/Book name
Japanese:Chemistry Letters 
English:Chemistry Letters 
Volume, Number, Page Vol. 42    No. 5    pp. 476-478
Published date 2013 
Publisher
Japanese:Chemical Society of Japan 
English:Chemical Society of Japan 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1246/cl.130029
Abstract Addn. of TPA.Cl (TPA = tetra-n-propylammonium) to a reaction mixt. of H2WO4, H2O2, and HCl gave a novel all-inorg. mononuclear chloro oxo diperoxotungstate, TPA[WOCl(O2)2(H2O)] (I), which was characterized by x-ray crystallog., elemental anal., and IR, Raman, UV-vis, 17O and 183W NMR spectroscopies, and CSI-MS. Compd. I acted as a good precursor for the high-yield synthesis of an active protonated tetranuclear peroxotungstate, TPA3[H{W2O2(O2)4(ﾎｼ-O)}2]. [on SciFinder(R)]

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