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Title
Japanese:Green Oxidation Reactions by Polyoxometalate-Based Catalysts: From Molecular to Solid Catalysts. 
English:Green Oxidation Reactions by Polyoxometalate-Based Catalysts: From Molecular to Solid Catalysts. 
Author
Japanese: Noritaka Mizuno, Keigo Kamata, Kazuya. Yamaguchi.  
English: Noritaka Mizuno, Keigo Kamata, Kazuya. Yamaguchi.  
Language English 
Journal/Book name
Japanese:Topics in Catalysis 
English:Topics in Catalysis 
Volume, Number, Page Vol. 53    No. 13-14    pp. 876-893
Published date 2010 
Publisher
Japanese:Springer 
English:Springer 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1007/s11244-010-9520-x
Abstract A review. This article summarizes our recent developments for H2O2- and O2-based green oxidn. reactions by polyoxometalates (POMs) and related compds. POM-based structurally controlled mol. catalysts exhibit high catalytic performance for epoxidn. and sulfoxidn. with H2O2. These mol. catalysts can be immobilized on the org.-inorg. hybrid support with covalently anchoring N-octyldihydroimidazolium cation fragments via the anion exchange. In addn., we have developed supported metal hydroxide catalysts such as Ru(OH)x/Al2O3 and Cu(OH)x/TiO2 on the basis of the information of the catalytically active sites with POMs. By using these supported metal hydroxide catalysts, novel aerobic oxidative synthesis of nitriles and amides, and efficient aerobic oxidative homocoupling of alkynes can be realized. [on SciFinder(R)]

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