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Title
Japanese:Activation of hydrogen peroxide by polyoxometalates. 
English:Activation of hydrogen peroxide by polyoxometalates. 
Author
Japanese: Noritaka Mizuno, Kazuya Yamaguchi, Keigo Kamata, Yoshinao. Nakagawa.  
English: Noritaka Mizuno, Kazuya Yamaguchi, Keigo Kamata, Yoshinao. Nakagawa.  
Language English 
Journal/Book name
Japanese:Mech. Homogeneous Heterog. Epoxidation Catal. 
English:Mech. Homogeneous Heterog. Epoxidation Catal. 
Volume, Number, Page         pp. 155-176
Published date 2008 
Publisher
Japanese:Elsevier B.V. 
English:Elsevier B.V. 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1016/B978-0-444-53188-9.00004-3
Abstract A review. Numerous catalytic H2O2-based oxidn. reactions by polyoxometalates (POMs) were developed. POMs for H2O2-based oxidns. can be classified into three groups from the standpoints of their structures and H2O2 activation properties: (a) di- and tetranuclear small peroxotungstates, (b) lacunary polyoxotungstates, and (c) transition-metal-substituted POMs. This chapter focuses on the activation of H2O2 from groups (a)(c) including reaction mechanisms. Recent progress in the selective oxidn. with H2O2 catalyzed by POMs is comprehensively summarized. [on SciFinder(R)]

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