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Title
Japanese:Efficient, regioselective epoxidation of dienes with hydrogen peroxide catalyzed by [ﾎｳ-SiW10O34(H2O)2]4-. 
English:Efficient, regioselective epoxidation of dienes with hydrogen peroxide catalyzed by [ﾎｳ-SiW10O34(H2O)2]4-. 
Author
Japanese: Keigo Kamata, Yoshinao Nakagawa, Kazuya Yamaguchi, Noritaka. Mizuno.  
English: Keigo Kamata, Yoshinao Nakagawa, Kazuya Yamaguchi, Noritaka. Mizuno.  
Language English 
Journal/Book name
Japanese:Journal of Catalysis 
English:Journal of Catalysis 
Volume, Number, Page Vol. 224    No. 1    pp. 224-228
Published date 2004 
Publisher
Japanese:Elsevier Science 
English:Elsevier Science 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1016/j.jcat.2004.02.027
Abstract A divacant, lacunary, Keggin-type silicotungstate, [ﾎｳ-SiW10O34(H2O)2]4-, exhibits high catalytic performance for the epoxidn. of various nonconjugated dienes using hydrogen peroxide under mild conditions, high regioselectivity to the more accessible double bonds, and high efficiency of hydrogen peroxide utilization. The high regioselectivity for the [ﾎｳ-SiW10O34(H2O)2]4--catalyzed epoxidn. would be caused by the steric hindrance of the active site. [on SciFinder(R)]

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