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Title
Japanese:[{W(=O)(O2)2(H2O)}2(ﾎｼ-O)]2--catalyzed epoxidation of allylic alcohols in water with high selectivity and utilization of hydrogen peroxide. 
English:[{W(=O)(O2)2(H2O)}2(ﾎｼ-O)]2--catalyzed epoxidation of allylic alcohols in water with high selectivity and utilization of hydrogen peroxide. 
Author
Japanese: Keigo Kamata, Kazuya Yamaguchi, Shiro Hikichi, Noritaka. Mizuno.  
English: Keigo Kamata, Kazuya Yamaguchi, Shiro Hikichi, Noritaka. Mizuno.  
Language English 
Journal/Book name
Japanese:Advanced Synthesis & Catalysis 
English:Advanced Synthesis & Catalysis 
Volume, Number, Page Vol. 345    No. 11    pp. 1193-1196
Published date 2003 
Publisher
Japanese:Wiley-VCH Verlag GmbH & Co. KGaA 
English:Wiley-VCH Verlag GmbH & Co. KGaA 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1002/adsc.200303123
Abstract A dinuclear peroxotungstate, K2[{W(=O)(O2)2(H2O)}2(ﾎｼ-O)] ﾂｷ 2 H2O, exhibits high catalytic performance for the epoxidn. of various allylic alcs. with only one equiv. of hydrogen peroxide at 305 K in water solvent. The effectiveness of this system is evidenced by high chemo-, regio-, and diastereoselectivity, and stereospecificity for the epoxidn. of allylic alcs. Furthermore, products/catalyst sepn. can be easily carried out by simple extn. and the catalyst recovered can be reused with the maintenance of the catalytic performance. [on SciFinder(R)]

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