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Title
Japanese:Selective oxidation of hydrocarbons with molecular oxygen catalyzed by transition-metal-substituted silicotungstates. 
English:Selective oxidation of hydrocarbons with molecular oxygen catalyzed by transition-metal-substituted silicotungstates. 
Author
Japanese: Noritaka Mizuno, Masaki Hashimoto, Yasutaka Sumida, Yoshinao Nakagawa, Keigo. Kamata.  
English: Noritaka Mizuno, Masaki Hashimoto, Yasutaka Sumida, Yoshinao Nakagawa, Keigo. Kamata.  
Language English 
Journal/Book name
Japanese:Polyoxometalate Chem. Nano-Compos. Des., [Symp.] 
English:Polyoxometalate Chem. Nano-Compos. Des., [Symp.] 
Volume, Number, Page         pp. 197-203
Published date 2002 
Publisher
Japanese:Kluwer Academic/Plenum Publishers 
English:Kluwer Academic/Plenum Publishers 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
Abstract A review on the synthesis and liq.-phase selective oxidn. catalysis by ﾎｳ-SiW10{Fe(OH2)}2O386- with O2. This Keggin-type di-Fe-substituted silicotungstate was prepd. by the reaction of the lacunary [ﾎｳ-SiW10O36]8- with Fe(NO3)3 in an acidic aq. soln. and isolated as the Bu4N salt. The synthesized compd. showed the highest turnover no. for the oxidn. of cyclohexane with 1 atm O among Fe- and tri-transition-metal-substituted silicotungstates tested. [on SciFinder(R)]

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