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Title
Japanese:Composites of [ﾎｳ-H2PV2W10O40]3- and [ﾎｱ-SiW12O40]4- supported on Fe2O3 as heterogeneous catalysts for selective oxidation with aqueous hydrogen peroxide. 
English:Composites of [ﾎｳ-H2PV2W10O40]3- and [ﾎｱ-SiW12O40]4- supported on Fe2O3 as heterogeneous catalysts for selective oxidation with aqueous hydrogen peroxide. 
Author
Japanese: Ye Wang, Keigo Kamata, Ryo Ishimoto, Yoshiyuki Ogasawara, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka. Mizuno.  
English: Ye Wang, Keigo Kamata, Ryo Ishimoto, Yoshiyuki Ogasawara, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka. Mizuno.  
Language English 
Journal/Book name
Japanese:Catalysis Science & Technology 
English:Catalysis Science & Technology 
Volume, Number, Page         pp. Ahead of Print
Published date 2015 
Publisher
Japanese:Royal Society of Chemistry 
English:Royal Society of Chemistry 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1039/C4CY01693A
Abstract Composites of [ﾎｳ-H2PV2W10O40]3- and [ﾎｱ-SiW12O40]4- supported on Fe2O3 (PV2-SiW12/Fe2O3, in particular, the molar ratio of PV2/SiW12 = 1/1) could act as effective and reusable heterogeneous catalysts for selective oxidn. with aq. hydrogen peroxide. In the presence of PV2-SiW12/Fe2O3, various kinds of org. substrates such as alkenes, sulfides, arenes, and alkanes could selectively be converted into the corresponding oxygenated products in moderate to high yields. The obsd. catalyzes for the present oxidns. were intrinsically heterogeneous, and PV2-SiW12/Fe2O3 could be reused at least three times for each oxidn. (epoxidn., sulfoxidn., and arene hydroxylation) without appreciable losses of the high catalytic performance. [on SciFinder(R)]

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