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Title
Japanese:Chemo- and regioselective direct hydroxylation of arenes with hydrogen peroxide catalyzed by a divanadium-substituted phosphotungstate 
English:Chemo- and regioselective direct hydroxylation of arenes with hydrogen peroxide catalyzed by a divanadium-substituted phosphotungstate 
Author
Japanese: Keigo Kamata, Taiyo Yamaura, Noritaka Mizuno.  
English: Keigo Kamata, Taiyo Yamaura, Noritaka Mizuno.  
Language English 
Journal/Book name
Japanese:Angewandte Chemie (International ed. in English) 
English:Angewandte Chemie (International ed. in English) 
Volume, Number, Page Vol. 51    No. 29    pp. 7275-8
Published date 2012 
Publisher
Japanese:Wiley-VCH Verlag GmbH & Co. KGaA 
English:Wiley-VCH Verlag GmbH & Co. KGaA 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1002/anie.201201605
Abstract Peroxide in, phenol out: The catalyst [ﾎｳ-PW(10)O(38)V(2)(ﾎｼ-OH)(2)](3-) showed high activity in the hydroxylation of various aromatic compounds with aqueous H(2)O(2). The system was regioselective, producing para-phenols from monosubstituted benzene derivatives. Furthermore, alkylarenes with reactive side-chain C sp 3-H bonds could be chemoselectively hydroxylated without significant formation of side-chain oxygenated products.[on SciFinder (R)]

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