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Title
Japanese:Transition-Metal-Catalyzed Cyclization of Alkynals via Oxametallacycle Intermediates (Eur. J. Org. Chem. 20/2012). 
English:Transition-Metal-Catalyzed Cyclization of Alkynals via Oxametallacycle Intermediates (Eur. J. Org. Chem. 20/2012). 
Author
Japanese: Ken Tanaka, Yuki. Tajima.  
English: Ken Tanaka, Yuki. Tajima.  
Language English 
Journal/Book name
Japanese:European Journal of Organic Chemistry 
English:European Journal of Organic Chemistry 
Volume, Number, Page Vol. 2012    No. 20    pp. n/a
Published date 2012 
Publisher
Japanese:Wiley-VCH Verlag GmbH & Co. KGaA 
English:Wiley-VCH Verlag GmbH & Co. KGaA 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1002/ejoc.201290051
Abstract The cover picture shows the Japanese famous inverted image of Mt. Fuji (reflected in the water). The scheme shows the general catalytic cycle of the transition-metal-catalyzed cyclization of alkynals via oxametallacycle intermediates. This cyclization is a highly efficient method for the stereoselective synthesis of carbocycles and heterocycles. This reaction is catalyzed by Ni, Rh, Ru, and Ti complexes and mediated by organometalloid reagents (X-Y = Si-H, B-C), organometallic reagents (X-Y = Zn-C), dihydrogen (X-Y = H-H), and org. reagents (X-Y = C-H, C-P). Details are presented in the Microreview by K. Tanaka and Y. Tajima on p. 3715 ff. [on SciFinder(R)]

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