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Title
Japanese:Asymmetric Dearomatization of 1-Amino-naphthalene Derivatives through C-C Bond Formation with Electron-Rich Heterocycles as Nucleophiles. 
English:Asymmetric Dearomatization of 1-Amino-naphthalene Derivatives through C-C Bond Formation with Electron-Rich Heterocycles as Nucleophiles. 
Author
Japanese: Takafumi Baba, Junko Oka, Keiichi Noguchi, Ken. Tanaka.  
English: Takafumi Baba, Junko Oka, Keiichi Noguchi, Ken. Tanaka.  
Language English 
Journal/Book name
Japanese:European Journal of Organic Chemistry 
English:European Journal of Organic Chemistry 
Volume, Number, Page         pp. Ahead of Print
Published date 2015 
Publisher
Japanese:Wiley-VCH Verlag GmbH & Co. KGaA 
English:Wiley-VCH Verlag GmbH & Co. KGaA 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1002/ejoc.201500486
Abstract A cationic gold(I)/axially chiral biaryl bis(phosphine) complex has been employed to catalyze the asym. dearomatization reactions of 1-aminonaphthalene derivs. through a C-C bond-forming reaction with electron-rich heterocycles as the nucleophiles. These reactions afford pentacyclic heterocycles in good yields with moderate enantiomeric excess (ee) values. [on SciFinder(R)]

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