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Title
Japanese:The oxidative annulation of tertiary benzyl alcohols with internal alkynes using an (electron-deficient ﾎｷ5-cyclopentadienyl)rhodium(III) catalyst under ambient conditions. 
English:The oxidative annulation of tertiary benzyl alcohols with internal alkynes using an (electron-deficient ﾎｷ5-cyclopentadienyl)rhodium(III) catalyst under ambient conditions. 
Author
Japanese: Miho Fukui, Yuki Hoshino, Tetsuya Satoh, Masahiro Miura, Ken. Tanaka.  
English: Miho Fukui, Yuki Hoshino, Tetsuya Satoh, Masahiro Miura, Ken. Tanaka.  
Language English 
Journal/Book name
Japanese:Advanced Synthesis & Catalysis 
English:Advanced Synthesis & Catalysis 
Volume, Number, Page Vol. 356    No. 7    pp. 1638-1644
Published date 2014 
Publisher
Japanese:Wiley-VCH Verlag GmbH & Co. KGaA 
English:Wiley-VCH Verlag GmbH & Co. KGaA 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1002/adsc.201400084
Abstract It was established that a dinuclear (electron-deficient ﾎｷ5-cyclopentadienyl)rhodium(III) complex catalyzes the oxidative annulation of tertiary benzyl alcs. with internal alkynes via sp2 C-H/O-H functionalization under ambient conditions (at room temp. under air) to give substituted isochromenes in good yields. The preference for annulation across electron-rich substrates over electron-deficient substrates was obsd. using this electron-deficient rhodium(III) complex. [on SciFinder(R)]

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