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Title
Japanese:Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes. 
English:Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes. 
Author
Japanese: 柴田祐, Ken. Tanaka.  
English: Yu Shibata, Ken. Tanaka.  
Language English 
Journal/Book name
Japanese:Journal of the American Chemical Society 
English:Journal of the American Chemical Society 
Volume, Number, Page Vol. 131    No. 35    pp. 12552-12553
Published date 2009 
Publisher
Japanese:American Chemical Society 
English:American Chemical Society 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1021/ja905908z
Abstract We have established that a cationic rhodium(I)/(R,R)-QuinoxP* complex catalyzes the highly enantioselective direct intermol. hydroacylation of ﾎｱ-substituted acrylamides with unfunctionalized aliph. aldehydes to yield the corresponding ﾎｳ-ketoamides, e.g. (+)-PhCH2CH2COCH2CHMeCONPh2, in high yields with excellent ee values. [on SciFinder(R)]

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