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Title
Japanese:Design and synthesis of a C2-symmetric chiral 1,2-bis(diphenylphosphino)benzene ligand via rhodium-catalyzed intramolecular [2 + 2 + 2] cycloaddition. 
English:Design and synthesis of a C2-symmetric chiral 1,2-bis(diphenylphosphino)benzene ligand via rhodium-catalyzed intramolecular [2 + 2 + 2] cycloaddition. 
Author
Japanese: Fumiya Mori, Keiichi Noguchi, Ken. Tanaka.  
English: Fumiya Mori, Keiichi Noguchi, Ken. Tanaka.  
Language English 
Journal/Book name
Japanese:Heterocycles 
English:Heterocycles 
Volume, Number, Page Vol. 86    No. 1    pp. 139-146
Published date 2012 
Publisher
Japanese:Japan Institute of Heterocyclic Chemistry 
English:Japan Institute of Heterocyclic Chemistry 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.3987/COM-12-S(N)30
Abstract The design and synthesis of a C2-sym. chiral 1,2-bis(diphenylphosphino)benzene ligand via the Rh-catalyzed intramol. [2 + 2 + 2] cycloaddn. followed by redn. are disclosed. This new chiral dppbz-type ligand could be employed for the Rh-catalyzed asym. alkene hydrogenation. [on SciFinder(R)]

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