Home >

news Help

Publication Information


Title
Japanese:Use of acyl phosphonates as a coupling partner for rhodium-catalyzed [2+2+2] cycloaddition: unexpected dependence of the reactivity on structures of ﾎｱ,ﾏ�diynes. 
English:Use of acyl phosphonates as a coupling partner for rhodium-catalyzed [2+2+2] cycloaddition: unexpected dependence of the reactivity on structures of ﾎｱ,ﾏ�diynes. 
Author
Japanese: Ken Tanaka, Rie Tanaka, Goushi Nishida, Masao. Hirano.  
English: Ken Tanaka, Rie Tanaka, Goushi Nishida, Masao. Hirano.  
Language English 
Journal/Book name
Japanese:Synlett 
English:Synlett 
Volume, Number, Page     No. 13    pp. 2017-2022
Published date 2008 
Publisher
Japanese:Georg Thieme Verlag 
English:Georg Thieme Verlag 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1055/s-2008-1077968
Abstract A cationic rhodium(I)-H8-BINAP complex catalyzes a [2+2+2] cycloaddn. of 1,6- and 1,7-diynes with acyl phosphonates in high yields with high regioselectivity. Interestingly, the reactivity of ﾎｱ,ﾏ�diynes toward acyl phosphonates is highly dependent on their own structures. [on SciFinder(R)]

©2007 Tokyo Institute of Technology All rights reserved.