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Title
Japanese:Rhodium-catalyzed enantio- and diastereoselective intramolecular [2 + 2 + 2] cycloaddition of unsymmetrical dienynes. 
English:Rhodium-catalyzed enantio- and diastereoselective intramolecular [2 + 2 + 2] cycloaddition of unsymmetrical dienynes. 
Author
Japanese: Hiromi Sagae, Keiichi Noguchi, Masao Hirano, Ken. Tanaka.  
English: Hiromi Sagae, Keiichi Noguchi, Masao Hirano, Ken. Tanaka.  
Language English 
Journal/Book name
Japanese:Chemical Communications (Cambridge, United Kingdom) 
English:Chemical Communications (Cambridge, United Kingdom) 
Volume, Number, Page     No. 32    pp. 3804-3806
Published date 2008 
Publisher
Japanese:Royal Society of Chemistry 
English:Royal Society of Chemistry 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1039/b804294b
Abstract A cationic rhodium(I)/(R)-H8-BINAP or (R)-Segphos complex catalyzes an intramol. [2 + 2 + 2] cycloaddn. of unsym. dienynes, leading to fused tri- and tetracyclic cyclohexenes bearing two tertiary or quaternary carbon centers in high yields with high enantio- and diastereoselectivity. [on SciFinder(R)]

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