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Title
Japanese:Synthesis and structural characterization of BINOL-modified chiral polyoxometalates. 
English:Synthesis and structural characterization of BINOL-modified chiral polyoxometalates. 
Author
Japanese: Ryo Ishimoto, Keigo Kamata, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka. Mizuno.  
English: Ryo Ishimoto, Keigo Kamata, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka. Mizuno.  
Language English 
Journal/Book name
Japanese:Dalton Transactions 
English:Dalton Transactions 
Volume, Number, Page Vol. 44    No. 24    pp. 10947-10951
Published date 2015 
Publisher
Japanese:Royal Society of Chemistry 
English:Royal Society of Chemistry 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1039/C5DT01338K
Abstract Chiral ligand-modified polyoxometalates (POMs), (Bu4N)4[ﾎｳ-SiTi2W10O36(ﾎｼ-OH)2(ﾎｼ-BINOLate)], were successfully synthesized by the introduction of (R)- or (S)-BINOL into the dititanium-substituted tungstosilicate POM in an org. medium and characterized by x-ray crystallog., spectroscopy, and elemental analyses. These BINOL-modified POMs were stable in the soln. state and showed catalytic activity for asym. oxidn. of thioanisole. [on SciFinder(R)]

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