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Title
Japanese:A potential gradient along the layer-by-layer architecture for electron transfer rectification 
English:A potential gradient along the layer-by-layer architecture for electron transfer rectification 
Author
Japanese: 山元公寿, 今岡享稔, 小林広紀, 桂山真.  
English: Kimihisa Yamamoto, Takane Imaoka, Hiroki Kobayashi, Makoto Katsurayama.  
Language Japanese 
Journal/Book name
Japanese:Dalton Trans. 
English:Dalton Trans. 
Volume, Number, Page        
Published date Apr. 2015 
Publisher
Japanese: 
English: 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1039/c5dt00788g
Abstract Electrochemical and photochemical measurements demonstrated that dendritic phenylazomethines, which can make complexes with SnCl2 by a stepwise process, only permit an outbound electron transfer. The unique dendrimer effect allows efficient production of photo-generated radical ion pairs by suppressing their charge recombination. In sharp contrast, the phenylenevinylene or benzylether dendrimers, which lack a heteroatom or π-conjugation, did not exhibit such non-symmetric characters.

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