Home >

news Help

Publication Information


Title
Japanese:P-43 メタノールを水素源としたPt 担持アルミナ触媒によるリグニンモデル含酸素官能基の水素化分解 
English: 
Author
Japanese: 藤墳 大裕, 田村真樹, 多湖輝興.  
English: Hiroyasu Fujitsuka, Masaki Tamura, Teruoki Tago.  
Language Japanese 
Journal/Book name
Japanese:バイオマス科学会議発表論文集 
English: 
Volume, Number, Page Vol. 12    No. 0    pp. 135-136
Published date Jan. 2017 
Publisher
Japanese:一般社団法人 日本エネルギー学会 
English: 
Conference name
Japanese:第12回バイオマス科学会議 
English: 
Conference site
Japanese:東京 
English: 
Abstract <p>Hydrogenolysis reaction is one of the important reactions to convert lignin into valuable aromatic chemicals. High-pressure hydrogen atmosphere is usually required for hydrogenolysis reaction, which causes high cost of hydrogen transportation and difficulty in handling. Thus we have focused on "in-situ hydrogenolysis" in which both hydrogen production by decomposition of alcohol solvent and hydrogenolysis of the reactant with the hydrogen produced in-situ occur simultaneously. We performed in-situ hydrogenolysis of benzofuran, which is a model compounds of decomposed lignin, in methanol solvent over Pt/Al2O3 catalyst. It was found that only furan moiety of benzofuran was hydrogenated and aromatic compounds like phenol were selectively obtained.</p>

©2007 Tokyo Institute of Technology All rights reserved.