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Title
Japanese:Spin Crossover by Encapsulation 
English:Spin Crossover by Encapsulation 
Author
Japanese: 小野 公輔, 吉沢 道人, 穐田 宗隆, Tatsuhisa Kato, Yoshihide Tsunobuchi, Shin-ichi Ohkoshi, Makoto Fujita.  
English: Kosuke Ono, Michito Yoshizawa, Munetaka Akita, Tatsuhisa Kato, Yoshihide Tsunobuchi, Shin-ichi Ohkoshi, Makoto Fujita.  
Language English 
Journal/Book name
Japanese:Journal of the American Chemical Society 
English:Journal of American Chemical Society 
Volume, Number, Page vol. 131    no. 8    pp. 2782–2783
Published date Jan. 2009 
Publisher
Japanese: 
English: 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
Official URL http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000264792300014&KeyUID=WOS:000264792300014
 
DOI https://doi.org/10.1021/ja8089894
Abstract Encapsulation by synthetic hosts can transform the spin states of square planar Ni(II)(acen) and Co(II)(tap) complexes. Upon encapsulation, the red Ni(II) diamagnetic state was converted into a green paramagnetic state, whereas the Co(II) low spin (S = 1/2) state was changed into a coupled (S = 1/2 and S = 3/2) state. The host cages are noninnocent and host−guest interactions within the confined cavity influence the resultant properties of the enclathrated metal complexes.

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