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Title
Japanese:Aerobic Oxidative Olefination of Benzamides with Styrenes Catalyzed by a Moderately Electron-Deficient CpRh(III) Complex with a Pendant Amide. 
English:Aerobic Oxidative Olefination of Benzamides with Styrenes Catalyzed by a Moderately Electron-Deficient CpRh(III) Complex with a Pendant Amide. 
Author
Japanese: Ryo Yoshimura, Yu Shibata, Takayuki Yamada, Ken. Tanaka.  
English: Ryo Yoshimura, Yu Shibata, Takayuki Yamada, Ken. Tanaka.  
Language English 
Journal/Book name
Japanese:Journal of Organic Chemistry 
English:Journal of Organic Chemistry 
Volume, Number, Page         pp. Ahead of Print
Published date Jan. 21, 2019 
Publisher
Japanese:American Chemical Society 
English:American Chemical Society 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
DOI https://doi.org/10.1021/acs.joc.8b02875
Abstract It has been established that a newly developed moderately electron-deficient cyclopentadienyl (Cp)-Rh(III) complex, bearing ester and pendant amide moieties on the Cp ring [CpARh(III)], is able to catalyze the aerobic oxidative olefination of benzamides, bearing nonspecial carbamoyl groups, with styrenes including disubstituted ones at relatively low temp. (60-80 ﾂｰC). The presence of both the ester and pendant acidic N-phenylcarbamoyl moieties on the CpA ligand play important roles in facilitation of the catalysis without sacrificing thermal stability of the complex. [on SciFinder(R)]

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