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Title
Japanese: 
English:Photocatalytic E → Z Isomerization of gem-Bromofluoroalkenes: Stereoselective Synthesis of β-Fluorostyrene Derivatives 
Author
Japanese: 加藤颯人, 榧木啓人, 小池 隆司.  
English: Hayato Kato, Yoshihito Kayaki, Takashi Koike.  
Language English 
Journal/Book name
Japanese: 
English:Org. Biomol. Chem. 
Volume, Number, Page Vol. 23    Issue 6    pp. 1342-1346
Published date Feb. 14, 2025 
Publisher
Japanese: 
English:Royal Chemical Society 
Conference name
Japanese: 
English: 
Conference site
Japanese: 
English: 
Official URL https://pubs.rsc.org/en/content/articlelanding/2025/ob/d4ob01658k
 
DOI https://doi.org/10.1039/D4OB01658K
Abstract Stereoselective synthesis of β-fluorostyrene derivatives has been achieved. Selective isomerization of gem-bromofluoroalkenyl benzenes bearing various ortho-substituents is enabled by using Ir photocatalysts with high triplet energy. Subsequent one-pot transition-metal (TM)-catalyzed reactions enable pot-economical synthesis of monofluoroalkenes in a stereoselective manner.

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