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タイトル
和文: 
英文:Photolytic Living Anionic Ring-Opening Polymerization (ROP) of Silicon-Bridged [1]Ferrocenophanes via an Iron-Cyclopentadienyl Bond Cleavage Mechanism. 
著者
和文: 田邊 真, Ian Manners:.  
英文: Makoto Tanabe, Ian Manners:.  
言語 English 
掲載誌/書名
和文: 
英文:Journal of the American Chemical Society 
巻, 号, ページ Vol. 126    No. 37    pp. 11434-11435
出版年月 2004年8月25日 
出版者
和文: 
英文:American Chemical Society 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1021/ja046657s
アブストラクト A new living anionic ring-opening polymerization (ROP) method for sila[1]ferrocenophane 1 was developed using UV irradiation in the presence of Na[C5H5] as a promoter to afford controlled molecular weight polymers (Mn = 9.3 × 103 to 7.0 × 104, PDI = 1.04−1.21). A ring-opened ferrocenylsilane with a dangling silyl-substituted cyclopentadienyl anion, which was obtained from a near-stoichiometric photoreaction of 1 with Li[C5H4Me], indicates an Fe−Cp bond cleavage mechanism for the photolytic ROP.

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