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タイトル
和文: 
英文:Synthesis and Characterization of a Dinuclear Platinum Complex with Silsesquioxanate Ligand 
著者
和文: •Neli Mintcheva, 田邊 真, 小坂田 耕太郎, Ivelina Georgieva, Tzvetan Mihailov, Natasha Trendafilova.  
英文: •Neli Mintcheva, Makoto Tanabe, Kohtaro Osakada, Ivelina Georgieva, Tzvetan Mihailov, Natasha Trendafilova.  
言語 English 
掲載誌/書名
和文: 
英文:Journal of Organometallic Chemistry 
巻, 号, ページ Vol. 695    No. 12-13    pp. 1738-1743
出版年月 2010年6月 
出版者
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英文: 
会議名称
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英文: 
開催地
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英文: 
DOI https://doi.org/10.1016/j.jorganchem.2010.03.033
アブストラクト The first dinuclear platinum complex with a silsesquioxanate ligand {[Pt(Ph)(PEt3)2]2O11Si7(c-C5H9)7(OH)} was synthesized by reaction of incompletely condensed silsesquioxane, (c-C5H9)7Si7O9(OH)3 with trans-PtI(Ph)(PEt3)2. Multinuclear (1H, 13C, 29Si, and 31P) NMR data clearly show two unequivalent platinum moieties (Pt(Ph)(PEt3)2) bridged by bulky silsesquioxanate ligand. DFT calculations were performed to analyse the molecular structure and NMR properties of the new platinum complex.

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