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タイトル
和文: 
英文:Electronic Structure and Graphenization of Hexaphenylborazine 
著者
和文: Gaku Imamura, Cha Wen Chang, 難波江 裕太, 柿本 雅明, 宮田 清蔵, Koichiro Saiki.  
英文: Gaku Imamura, Cha Wen Chang, Yuta Nabae, Masa-aki Kakimoto, Seizo Miyata, Koichiro Saiki.  
言語 English 
掲載誌/書名
和文: 
英文:The Journal of Physical Chemistry C 
巻, 号, ページ Vol. 116    No. 30    pp. 16305-16310
出版年月 2012年10月 
出版者
和文: 
英文:American Chemical Society 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
公式リンク http://dx.doi.org/10.1021/jp304879s
 
DOI https://doi.org/10.1021/jp304879s
アブストラクト Synthesis of graphene that contains boron and nitrogen is still a big challenge. In this paper, we report the growth of boron (B)- and nitrogen (N)-doped graphene on a Pt(111) surface by graphenization of a novel molecule, hexaphenylborazine (HPB). We performed quantum chemical calculations for the molecule and compared the results with the photoelectron spectra. Deposition of HPB onto the heated Pt(111) substrate led to formation of the doped graphene. Incorporation of nitrogen and boron atoms to the graphene lattice was observed up to the substrate temperature of 600 ツーC and at 400 ツーC, respectively. On the basis of the experimental results and Mulliken population analysis, we discuss the possible atomic configuration of B,N-doped graphene.

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