Hydrosilylation of various multiple bonds by a simple combined catalyst of a tungstate monomer and rhodium acetate.

Shintaro Itagaki; Hanako Sunaba; Keigo Kamata; Kazuya Yamaguchi; Noritaka. Mizuno

doi:10.1246/cl.130338

論文・著書情報

タイトル

和文:	Hydrosilylation of various multiple bonds by a simple combined catalyst of a tungstate monomer and rhodium acetate.
英文:	Hydrosilylation of various multiple bonds by a simple combined catalyst of a tungstate monomer and rhodium acetate.

著者

和文:	Shintaro Itagaki, Hanako Sunaba, Keigo Kamata, Kazuya Yamaguchi, Noritaka. Mizuno.
英文:	Shintaro Itagaki, Hanako Sunaba, Keigo Kamata, Kazuya Yamaguchi, Noritaka. Mizuno.

言語

English

掲載誌/書名

和文:	Chemistry Letters
英文:	Chemistry Letters

巻, 号, ページ

Vol. 42 No. 9 pp. 980-982

出版年月

2013年

出版者

和文:	Chemical Society of Japan
英文:	Chemical Society of Japan

会議名称

和文:
英文:

開催地

和文:
英文:

DOI

https://doi.org/10.1246/cl.130338

アブストラクト

In the presence of a simple combined catalyst of a tungstate monomer (TBA2WO4, TBA: tetra-n-butylammonium) and Rh2(OAc)4 hydrosilylation of various types of substances including ketone, aldehyde, carbon dioxide, alkene, nitrile, and furan derivs. efficiently proceeded, affording the corresponding hydrosilylation products in moderate to high yields (竕･63% yields). In addn., the present system was also applicable to the one-pot redn. of benzamide to benzylamine (95% yield). [on SciFinder(R)]

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