Home >

news ヘルプ

論文・著書情報


タイトル
和文:Efficient, regioselective epoxidation of dienes with hydrogen peroxide catalyzed by [ﾎｳ-SiW10O34(H2O)2]4-. 
英文:Efficient, regioselective epoxidation of dienes with hydrogen peroxide catalyzed by [ﾎｳ-SiW10O34(H2O)2]4-. 
著者
和文: Keigo Kamata, Yoshinao Nakagawa, Kazuya Yamaguchi, Noritaka. Mizuno.  
英文: Keigo Kamata, Yoshinao Nakagawa, Kazuya Yamaguchi, Noritaka. Mizuno.  
言語 English 
掲載誌/書名
和文:Journal of Catalysis 
英文:Journal of Catalysis 
巻, 号, ページ Vol. 224    No. 1    pp. 224-228
出版年月 2004年 
出版者
和文:Elsevier Science 
英文:Elsevier Science 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1016/j.jcat.2004.02.027
アブストラクト A divacant, lacunary, Keggin-type silicotungstate, [ﾎｳ-SiW10O34(H2O)2]4-, exhibits high catalytic performance for the epoxidn. of various nonconjugated dienes using hydrogen peroxide under mild conditions, high regioselectivity to the more accessible double bonds, and high efficiency of hydrogen peroxide utilization. The high regioselectivity for the [ﾎｳ-SiW10O34(H2O)2]4--catalyzed epoxidn. would be caused by the steric hindrance of the active site. [on SciFinder(R)]

©2007 Institute of Science Tokyo All rights reserved.