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タイトル
和文:Selective oxidation of hydrocarbons with molecular oxygen catalyzed by transition-metal-substituted silicotungstates. 
英文:Selective oxidation of hydrocarbons with molecular oxygen catalyzed by transition-metal-substituted silicotungstates. 
著者
和文: Noritaka Mizuno, Masaki Hashimoto, Yasutaka Sumida, Yoshinao Nakagawa, Keigo. Kamata.  
英文: Noritaka Mizuno, Masaki Hashimoto, Yasutaka Sumida, Yoshinao Nakagawa, Keigo. Kamata.  
言語 English 
掲載誌/書名
和文:Polyoxometalate Chem. Nano-Compos. Des., [Symp.] 
英文:Polyoxometalate Chem. Nano-Compos. Des., [Symp.] 
巻, 号, ページ         pp. 197-203
出版年月 2002年 
出版者
和文:Kluwer Academic/Plenum Publishers 
英文:Kluwer Academic/Plenum Publishers 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
アブストラクト A review on the synthesis and liq.-phase selective oxidn. catalysis by ﾎｳ-SiW10{Fe(OH2)}2O386- with O2. This Keggin-type di-Fe-substituted silicotungstate was prepd. by the reaction of the lacunary [ﾎｳ-SiW10O36]8- with Fe(NO3)3 in an acidic aq. soln. and isolated as the Bu4N salt. The synthesized compd. showed the highest turnover no. for the oxidn. of cyclohexane with 1 atm O among Fe- and tri-transition-metal-substituted silicotungstates tested. [on SciFinder(R)]

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