Home >

news ヘルプ

論文・著書情報


タイトル
和文:Chemo- and regioselective direct hydroxylation of arenes with hydrogen peroxide catalyzed by a divanadium-substituted phosphotungstate 
英文:Chemo- and regioselective direct hydroxylation of arenes with hydrogen peroxide catalyzed by a divanadium-substituted phosphotungstate 
著者
和文: Keigo Kamata, Taiyo Yamaura, Noritaka Mizuno.  
英文: Keigo Kamata, Taiyo Yamaura, Noritaka Mizuno.  
言語 English 
掲載誌/書名
和文:Angewandte Chemie (International ed. in English) 
英文:Angewandte Chemie (International ed. in English) 
巻, 号, ページ Vol. 51    No. 29    pp. 7275-8
出版年月 2012年 
出版者
和文:Wiley-VCH Verlag GmbH & Co. KGaA 
英文:Wiley-VCH Verlag GmbH & Co. KGaA 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1002/anie.201201605
アブストラクト Peroxide in, phenol out: The catalyst [ホウ-PW(10)O(38)V(2)(ホシ-OH)(2)](3-) showed high activity in the hydroxylation of various aromatic compounds with aqueous H(2)O(2). The system was regioselective, producing para-phenols from monosubstituted benzene derivatives. Furthermore, alkylarenes with reactive side-chain C sp 3-H bonds could be chemoselectively hydroxylated without significant formation of side-chain oxygenated products.[on SciFinder (R)]

©2007 Tokyo Institute of Technology All rights reserved.