Home >

news ヘルプ

論文・著書情報


タイトル
和文:Transition-Metal-Catalyzed Cyclization of Alkynals via Oxametallacycle Intermediates (Eur. J. Org. Chem. 20/2012). 
英文:Transition-Metal-Catalyzed Cyclization of Alkynals via Oxametallacycle Intermediates (Eur. J. Org. Chem. 20/2012). 
著者
和文: Ken Tanaka, Yuki. Tajima.  
英文: Ken Tanaka, Yuki. Tajima.  
言語 English 
掲載誌/書名
和文:European Journal of Organic Chemistry 
英文:European Journal of Organic Chemistry 
巻, 号, ページ Vol. 2012    No. 20    pp. n/a
出版年月 2012年 
出版者
和文:Wiley-VCH Verlag GmbH & Co. KGaA 
英文:Wiley-VCH Verlag GmbH & Co. KGaA 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1002/ejoc.201290051
アブストラクト The cover picture shows the Japanese famous inverted image of Mt. Fuji (reflected in the water). The scheme shows the general catalytic cycle of the transition-metal-catalyzed cyclization of alkynals via oxametallacycle intermediates. This cyclization is a highly efficient method for the stereoselective synthesis of carbocycles and heterocycles. This reaction is catalyzed by Ni, Rh, Ru, and Ti complexes and mediated by organometalloid reagents (X-Y = Si-H, B-C), organometallic reagents (X-Y = Zn-C), dihydrogen (X-Y = H-H), and org. reagents (X-Y = C-H, C-P). Details are presented in the Microreview by K. Tanaka and Y. Tajima on p. 3715 ff. [on SciFinder(R)]

©2007 Institute of Science Tokyo All rights reserved.