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タイトル
和文:Cationic gold(I) axially chiral biaryl bis[phosphine] complex-catalyzed atroposelective synthesis of heterobiaryls. 
英文:Cationic gold(I) axially chiral biaryl bis[phosphine] complex-catalyzed atroposelective synthesis of heterobiaryls. 
著者
和文: Tetsuro Shibuya, Kyosuke Nakamura, Ken. Tanaka.  
英文: Tetsuro Shibuya, Kyosuke Nakamura, Ken. Tanaka.  
言語 English 
掲載誌/書名
和文:Beilstein Journal of Organic Chemistry 
英文:Beilstein Journal of Organic Chemistry 
巻, 号, ページ Vol. 7        pp. 944-950, No. 105
出版年月 2011年 
出版者
和文:Beilstein-Institut zur Foerderung der Chemischen Wissenschaften 
英文:Beilstein-Institut zur Foerderung der Chemischen Wissenschaften 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
公式リンク http://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-7-105.pdf
 
DOI https://doi.org/10.3762/bjoc.7.105
アブストラクト It has been established that a cationic gold(I)/(R)-DTBM-Segphos or (R)-BINAP complex catalyzes an atroposelective intramol. hydroarylation of alkynes leading to enantioenriched axially chiral 4-aryl-2-quinolinones and 4-(aryl)coumarins and the synthesis of the target compds. was achieved with up to 61% ee. [on SciFinder(R)]

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